Dynamic adsorption behavior and mechanism of transition metal ions on silica gels functionalized with hydroxyl- or amino-terminated polyamines

Chemical Engineering Journal

Volumn 221, Issue , 2013, Pages 264-274

  Wang, Minghua ^a   Qu, Rongjun ^a   Sun, Changmei ^a   Yin, Ping ^a   Chen, Hou ^a  

^a LUDONG UNIVERSITY   (China)

Author keywords

Adsorption; Heavy metal removal; Organic inorganic hybrid; Silica gel

Indexed keywords

ADSORPTION BED; ADSORPTION CAPACITIES; ADSORPTION KINETICS; ADSORPTION MECHANISM; ADSORPTION PROCESS; AMINO GROUP; AMINO-TERMINATED; BREAK THROUGH CURVE; CHELATING ABILITY; DYNAMIC ADSORPTION; DYNAMIC ADSORPTION BEHAVIORS; FILM DIFFUSION; FUNCTIONALIZED; HEAVY METAL REMOVAL; MASS TRANSFER RESISTANCES; METAL ION ADSORPTION; ORGANIC-INORGANIC HYBRID; POLYAMINES; PSEUDO-FIRST-ORDER; PSEUDO-SECOND ORDER MODEL; STATIC AND DYNAMIC; STATIC EXPERIMENTS; SURFACE AREA; UTILIZATION RATIOS;

AMINES; DYNAMICS; EXPERIMENTS; FUNCTIONAL GROUPS; GOLD; HEAVY METALS; IONIC LIQUIDS; MASS TRANSFER; METAL IONS; RESINS; SILICA GEL; SILVER;

ADSORPTION;

EID: 84874572930     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2013.02.036     Document Type: Article

References (61)

1. Gubbuk I.H., Gup R., Kara H., Ersoz M. Adsorption of Cu(II) onto silica gel-immobilized Schiff base derivative. Desalination 2009, 249:1243-1248.
2. Li F., Du P., Chen W., Zhang S. Preparation of silica-supported porous sorbent for heavy metal ions removal in wastewater treatment by organic-inorganic hybridization combined with sucrose and polyethylene glycol imprinting. Anal. Chim. Acta 2007, 585:211-218.
3. Pramod Kumar G., Albino Kumar P. Saswati Chakraborty, Manabendra Ray, Uptake and desorption of copper ion using functionalized polymer coated silica gel in aqueous environment. Sep. Purif. Technol. 2007, 57:47-56.
4. Yin P., Xu Q., Qu R., Zhao G. Removal of transition metal ions from aqueous solutions by adsorption onto a novel silica gel matrix composite adsorbent. J. Hazard. Mater. 2009, 169:228-232.
5. Neubauer U., Nowack B., Furrer G., Schulin R. Heavy metal sorption on clay minerals affected by the siderophore desferrioxamine B. Environ. Sci. Technol. 2000, 34:2749-2755.
6. Ma N., Chen S., Li T., Zhang Q. Removal of mercury by an aminated fiber prepared by irradiation grafting copolymerization. Sep. Sci. Technol. 2012, 47:867-874.
7. Pérez-Quintanilla D., del Hierro I., Fajardo M., Sierra I. Mesoporous silica functionalized with 2-mercaptopyridine: Synthesis, characterization and employment for Hg(II) adsorption. Micropor. Mesopor. Mater. 2006, 89:58-68.
8. Gao B., Li Y., Chen Z. Adsorption behaviour of functional grafting particles based on polyethyleneimine for chromate anions. Chem. Eng. J. 2009, 150:337-343.
9. Walcarius A., Delacôte C. Mercury(II) binding to thiol-functionalized mesoporous silicas: critical effect of pH and sorbent properties on capacity and selectivity. Anal. Chim. Acta 2005, 547:3-13.
10. Kresge C.T., Leonowicz M.E., Roth W.J., VartuliJ J.C., Beck S. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 1992, 359:710-712.
11. Beck J.S., Vartuli J.C., Roth W.J., Leonowicz M.E., Kresge C.T., Schmitt K.D., Chu C.T.-W., Qlson D.H., Sheppard E.W., McCullen S.B., Higgins J.B., Schlenker J.L. A new family of mesoporous molecular sieves prepared with liquid crystal templates. J. Am. Chem. Soc. 1992, 114:10834-10843.
12. mercier L., Pinnavaia T.J. Heavy metal ion adsorbents formed by the grafting of a thiol-functionality to mesoporous silica molecular sieves: factors affecting Hg(II) uptake. Environ. Sci. Technol. 1998, 32:2749-2754.
13. Antochshuk V., Jaroniec M. Adsorption, thermogravimetric, and NMR studies of FSM-16 material functionalized with alkylmonochlorosilanes. J. Phys. Chem. B 1999, 103:6252-6261.
14. Kovalchuk T., Sfihi H., Kostenko L., Zaitsev V., Fraissard J. Preparation, structure and thermal stability of onium- and amino-functionalized silicas for the use as catalysts supports. J. Colloid Interface Sci. 2006, 302:214-229.
15. Jal P.K., Patel S., Mishra B.K. Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions. Talanta 2004, 62:1005-1028.
16. Stein A., Melde B.J., Schroden R.C. Hybrid inorganic-organic mesoporous silicates-nanoscopic reactors coming of age. Adv. Mater. 2000, 12:1403-1419.
17. Sayari A., Hamoudi S. Periodic mesoporous silica-based organic-inorganic nanocomposite materials. Chem. Mater. 2001, 13:3151-3168.
18. Brunel D., Blanc A.C., Galarneau A., Fajula F. New trends in the design of supported catalysts on mesoporous silicas and their applications in fine chemicals. Catal. Today 2002, 73:139-152.
19. Wang X., Cheng S. Solvent-free synthesis of flavanones over aminopropyl-functionalized SBA-15. Catal. Commun. 2006, 7:689-695.
20. Mureşeanu M., Pârvulescu V., Ene R., Cioaterâ N., Pasatoiu T.D., Andruh M. Cu(II) complexes imobilized on functionalized mesoporous silica as catalysts for biomimetic oxidations. J. Mater. Sci. 2009, 44:6795-6804.
21. Wu M., Chen Y., Wu R.a., Li R., Zou H., Chen B., Yao S. The synthesis of chloropropyl-functionalized silica hybrid monolithic column with modification of N,N-dimethyl-N-dodecylamine for capillary electrochromatography separation. J. Chromatogr. A 2010, 1217:4389-4394.
22. Xu Y., Wang C., Zhou G., Wu Y., Chen J. Improving the controlled release of water-insoluble emodin from amino-functionalized mesoporous silica. Appl. Surf. Sci. 2012, 258:6366-6372.
23. 2 core-shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal. J. Colloid Interface Sci. 2010, 349:293-299.
24. Da'na E., Silva N.D., Sayari A. Adsorption of copper on amine-functionalized SBA-15 prepared by co-condensation: kinetics properties. Chem. Eng. J. 2011, 166:454-459.
25. Anbia M., Lashgari M. Synthesis of amino-modified ordered mesoporous silica as a new nano sorbent for the removal of chlorophenols from aqueous media. Chem. Eng. J. 2009, 150:555-560.
26. Deng S., Zhang X., Wang J., Zhou H., Sun P., Chen T. Multi-amine-functionalized cubic Fd3̄m mesoporous silica by an anionic surfactant templating route. RSC Adv. 2012, 2:956-962.
27. Mahmoud M.E., El-Essawi M.M., Kholeif S.A., Fathalla E.M.I. Aspects of surface modification, structure characterization, thermal stability and metal selectivity properties of silica gel phases-immobilized-amine derivatives. Anal. Chim. Acta 2004, 525:123-132.
28. Aguado J., Arsuaga J.M., Arencibia A., Lindo M., Gascón V. Aqueous heavy metals removal by adsorption on amine-functionalized mesoporous silica. J. Hazard. Mater. 2009, 163:213-221.
29. Hamoudi S., El-Nemr A., Belkacemi K. Adsorptive removal of dihydrogenphosphate ion from aqueous solutions using mono, di- and tri-ammonium-functionalized SBA-15. J. Colloid Interface Sci. 2010, 343:615-621.
30. Bois L., Bonhommé A., Ribes A., Pais B., Raffin G., Tessier F. Functionalized silica for heavy metal ions adsorption. Colloid Surf. A: Physicochem. Eng. Aspects 2003, 221:221-230.
31. Yoshitake H., Yokoi T., Tatsumi T. Adsorption of chromate and arsenate by amino-functionalized MCM-41 and SBA-1. Chem. Mater. 2002, 14:4603-4610.
32. Yokoi T., Yoshitake H., Tatsumi T. Synthesis of amino-functionalized MCM-41 via direct co-condensation and post-synthesis grafting methods using mono-, di- and tri-amino-organoalkoxysilanes. J. Mater. Chem. 2004, 14:951-957.
33. Xia K., Ferguson R.Z., Losierb M., Tchoukanovab N., Brüningc R., Djaoued Y. Synthesis of hybrid silica materials with tunable pore structures and morphology and their application for heavy metal removal from drinking water. J. Hazard. Mater. 2010, 183:554-564.
34. Quang D.V., Kim J.K., Sarawade P.B., Tuan D.H., Kim H.T. Preparation of amino-functionalized silica for copper removal from an aqueous solution. J. Ind. Eng. Chem. 2012, 18:83-87.
35. Yoshitake H., Koiso E., Horie H., Yoshimura H. Polyamine-functionalized mesoporous silicas: preparation, structural analysis and oxyanion adsorption. Micropor. Mesopor. Mater. 2005, 85:183-194.
36. Yoshitake H., Koiso E., Tatsumi T., Horie H., Yoshimurayy H. Preparation and characterization of polyamine-functionalized mesoporous silica. Chem. Lett. 2004, 33:872-873.
37. Alothman Z.A., Apblett A.W. Metal ion adsorption using polyamine-functionalized mesoporous materials prepared from bromopropyl-functionalized mesoporous silica. J. Hazard. Mater. 2010, 182:581-590.
38. Zhang Y., Qu R., Sun C., Chen H., Wang C., Ji C., Yin P., Sun Y., Zhang H., Niu Y. Comparison of synthesis of chelating resin silica-gel-supported diethylenetriamine and its removal properties for transition metal ions. J. Hazard. Mater. 2009, 163:127-135.
39. Soliman E.M. Synthesis and metal collecting properties of mono, di, tri and tetramine based on silica gel matrix. Anal. Lett. 1997, 30:1739-1751.
40. Hamoudi S., EI-Nemr A., Bouguerra M., Belkacemi K. Adsorptive removal of nitrate and phosphate anions from aqueous solutions using functionalised SBA-15: effects of the organic functional group. Can. J. Chem. Eng. 2012, 90:34-40.
41. Zhang L., Yu C., Zhao W., Hua Z., Chen H., Li L., Shi J. Preparation of multi-amine-grafted mesoporous silicas and their application to heavy metal ions adsorption. J. Non-Cryst. Solids 2007, 353:4055-4061.
42. Chung J., Chun J., Lee J., Lee S.H., Lee Y.J., Hong S.W. Sorption of Pb(II) and Cu(II) onto multi-amine grafted mesoporous silica embedded with nano-magnetite: effects of steric factors. J. Hazard. Mater. 2012, 239-240:183-191.
43. 3+. Appl. Surf. Sci. 2008, 255:3361-3370.
44. Qu R., Wang M., Song R., Sun C., Zhang Y., Sun X., Ji C., Wang C., Yin P. Adsorption kinetics and isotherms of Ag(I) and Hg(II) onto silica gel with functional groups of hydroxyl- or amino-terminated polyamines. J. Chem. Eng. Data 2011, 56:1982-1990.
45. McKittrick M.W., Jones C.W. Toward single-site functional materials-preparation of amine-functionalized surfaces exhibiting site-isolated behavior. Chem. Mater. 2003, 15:1132-1139.
46. Da'na E., Sayari A. Optimization of copper removal efficiency by adsorption on amine-modified SBA-15: experimental design methodology. Chem. Eng. J. 2011, 167:91-98.
47. Wan Ngah W.S., Liang K.H. Adsorption of Gold(III) Ions onto Chitosan and N-Carboxymethyl Chitosan: equilibrium Studies. Ind. Eng. Chem. Res. 1999, 38:1411-1414.
48. 2+ from aqueous solution by adsorption onto a novel activated nylon-based membrane. Bioresource Technol. 2008, 99:7954-7958.
49. Moawed E.A., Zaid M.A.A., El-Shahat M.F. Preconcentration and determination of trace amounts of metal ions cast iron granite, and water using polyurethane foam functionalized with β-naphthol. Acta Chromatogr. 2005, 15:220-237.
50. Michard P., Guibal E., Vincent T., Cloirec P.L. Sorption and desorption of uranyl ions by silica gel: pH, particle size and porosity effects. Micropor. Mater. 1996, 5:309-324.
51. Chung T.-W., Yeh T.-S., Yang T.C.-K. Influence of manufacturing variables on surface properties and dynamic adsorption properties of silica gels. J. Non-Cryst. Solids 2001, 279:145-153.
52. S. Lagergren, Zur theorie der sogenannten adsorption geloster stoffe, Kungliga Svenska Vetenskapsakademiens, Handlingar, vol. 24, 1898, pp. 1-39.
53. Ho Y.S., McKay G. Pseudo-second order model for sorption processes. Process. Biochem. 1999, 34:451-465.
54. Qua R., Niu Y., Liu J., Sun Ch., Zhang Y., Chen H., Ji Ch. Adsorption and desorption behaviors of Pd(II) on silica-gel functionalized with ester- and amino-terminated dendrimer-like polyamidoamine polymers. React. Funct. Polym. 2008, 68:1272-1280.
55. Boyd G.E., Adamson A.W., Myers L.S. The exchange adsorption of ions from aqueous solutions by organic zeolites. II. Kinetics. J. Am. Chem. Soc. 1947, 69:2836-2848.
56. Reichenberg D. Properties of Ion-exchange resins in relation to their structure. III. Kinetics of exchange. J. Am. Chem. Soc. 1953, 75:589-597.
57. +. J. Colloid Interface Sci. 2000, 229:550-553.
58. Gao B., An F., Zhu Y. Novel surface ionic imprinting materials prepared via couple grafting of polymer and ionic imprinting on surfaces of silica gel particles. Polymer 2007, 48:2288-2297.
59. Yin P., Xu Q., Qu R., Zhao G., Sun Y. Adsorption of transition metal ions from aqueous solutions onto a novel silica gel matrix inorganic-organic composite material. J. Hazard. Mater. 2010, 173:710-716.
60. Gao B., An F., Liu K. Studies on chelating adsorption properties of novel composite material polyethyleneimine/silica gel for heavy-metal ions. Appl. Surf. Sci. 2006, 253:1946-1952.
61. Mureseanu M., Reiss A., Cioateraa N., Trandafir I., Hulea V. Mesoporous silica functionalized with 1-furoyl thiourea urea for Hg(II) adsorption from aqueous media. J. Hazard. Mater. 2010, 182:197-203.