NMR spectroscopic studies on the mechanism of cellulose dissolution in alkali solutions

Cellulose

Volumn 20, Issue 2, 2013, Pages 613-621

  Xiong, Bi ^a   Zhao, Pingping ^a   Cai, Ping ^a   Zhang, Lina ^a   Hu, Kai ^a   Cheng, Gongzhen ^a  

^a WUHAN UNIVERSITY   (China)

Author keywords

Alkali solutions; Cellobiose; Cellulose dissolution; Mechanism; NMR

Indexed keywords

CELLULOSE; DISSOLUTION; HYDRATION; HYDROGEN BONDS; MECHANISMS; NUCLEAR MAGNETIC RESONANCE; POSITIVE IONS; POTASSIUM HYDROXIDE; SODIUM HYDROXIDE; SPECTROSCOPIC ANALYSIS;

ALKALI SOLUTIONS; CELLOBIOSE; CELLULOSE DISSOLUTIONS; DISSOLUTION BEHAVIOR; FIRST HYDRATION SHELL; LONGITUDINAL RELAXATION; SPECTROSCOPIC STUDIES; STRUCTURE AND PROPERTIES;

LITHIUM COMPOUNDS;

EID: 84874532548     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10570-013-9869-7     Document Type: Article

References (27)

1. Cai J, Zhang L (2005) Rapid dissolution of cellulose in LiOH/Urea and NaOH/urea aqueous solutions. Macromol Biosci 5(6): 539-548. doi: 10. 1002/mabi. 200400222.
2. Cai J, Liu YT, Zhang LN (2006) Dilute solution properties of cellulose in LiOH/urea aqueous system. J Polym Sci Polym Phys 44(21): 3093-3101. doi: 10. 1002/polb. 20938.
3. Cai J, Zhang LN, Chang CY, Cheng GZ, Chen XM, Chu B (2007) Hydrogen-bond-induced inclusion complex in aqueous cellulose/LiOH/urea solution at low temperature. ChemPhysChem 8(10): 1572-1579. doi: 10. 1002/cphc. 200700229.
4. Collins KD, Neilson GW, Enderby JE (2007) Ions in water: characterizing the forces that control chemical processes and biological structure. Biophys Chem 128(2-3): 95-104.
5. Cuissinat C, Navard P (2006) Swelling and dissolution of cellulose Part 1: free floating cotton and wood fibres in N-methylmorpholine-N-oxide-water mixtures. Macromol Symp 244: 1-18. doi: 10. 1002/masy. 200651201.
6. Deshpande M, Scheicher RH, Ahuja R, Pandey R (2008) Binding strength of sodium ions in cellulose for different water contents. J Phys Chem B 112(30): 8985-8989.
7. Egal M, Budtova T, Navard P (2007) Structure of aqueous solutions of microcrystalline cellulose/sodium hydroxide below 0 degrees C and the limit of cellulose dissolution. Biomacromolecules 8(7): 2282-2287. doi: 10. 1021/bm0702399.
8. Egal M, Budtova T, Navard P (2008) The dissolution of microcrystalline cellulose in sodium hydroxide-urea aqueous solutions. Cellulose 15(3): 361-370. doi: 10. 1007/s10570-007-9185-1.
9. Frank HS, Wen WY (1957) Ion-solvent interaction. Structural aspects of ion-solvent interaction in aqueous solutions: a suggested picture of water structure. Discuss Faraday Soc 24: 133-140.
10. Isogai A (1997) NMR analysis of cellulose dissolved in aqueous NaOH solutions. Cellulose 4(2): 99-107.
11. Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Edit 44(22): 3358-3393.
12. Liebert T (2010) Cellulose solvents-remarkable history, bright future. Oxford University Press, Oxford, pp 3-54.
13. Liu WQ, Budtova T, Navard P (2011) Influence of ZnO on the properties of dilute and semi-dilute cellulose-NaOH-water solutions. Cellulose 18(4): 911-920. doi: 10. 1007/s10570-011-9552-9.
14. Marcus Y (1988) Ionic radii in aqueous solutions. Chem Rev 88(8): 1475-1498.
15. Porro F, Bedue O, Chanzy H, Heux L (2007) Solid-state C-13 NMR study of Na-cellulose complexes. Biomacromolecules 8(8): 2586-2593.
16. Remsing RC, Swatloski RP, Rogers RD, Moyna G (2006) Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a C-13 and Cl-35/37 NMR relaxation study on model systems. Chem Commun 12: 1271-1273.
17. Remsing RC, Hernandez G, Swatloski RP, Massefski WW, Rogers RD, Moyna G (2008) Solvation of carbohydrates in N, N′-dialkylimidazolium ionic liquids: a multinuclear NMR spectroscopy study. J Phys Chem B 112(35): 11071-11078.
18. Roshind MU, Tahtinen P, Niemitz M, Sjhohn R (2008) Complete assignments of the H-1 and C-13 chemical shifts and J(H, H) coupling constants in NMR spectra of D-glucopyranose and all D-glucopyranosyl-D-glucopyranosides. Carbohyd Res 343(1): 101-112. doi: 10. 1016/j. carres. 2007. 10. 008.
19. Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellose with ionic liquids. J Am Chem Soc 124(18): 4974-4975.
20. Symons MCR (1975) Water structure and hydration. Philos Trans R Soc Lond Ser B Biol Sci 272(915): 13-28. doi: 10. 1098/rstb. 1975. 0067.
21. Volkov A, Paula S, Deamer D (1997) Two mechanisms of permeation of small neutral molecules and hydrated ions across phospholipid bilayers. Bioelectrochem Bioenerg 42(2): 153-160.
22. Wang Y, Deng Y (2009) The kinetics of cellulose dissolution in sodium hydroxide solution at low temperatures. Biotechnol Bioeng 102(5): 1398-1405.
23. Yamashiki T, Kamide K, Okajima K, Kowsaka K, Matsui T, Fukase H (1988) Some characteristic features of dilute aqueous alkali solutions of specific alkali concentration (2. 5 mol I - 1) which possess maximum solubility power against cellulose. Polym J 20(6): 447-457.
24. Yang QL, Qi HS, Lue A, Hu K, Cheng GZ, Zhang LN (2011a) Role of sodium zincate on cellulose dissolution in NaOH/urea aqueous solution at low temperature. Carbohyd Polym 83(3): 1185-1191. doi: 10. 1016/j. carbpol. 2010. 09. 020.
25. Yang QL, Qin XZ, Zhang LN (2011b) Properties of cellulose films prepared from NaOH/urea/zincate aqueous solution at low temperature. Cellulose 18(3): 681-688. doi: 10. 1007/s10570-011-9514-2.
26. Zhang L, Ruan D, Gao S (2002) Dissolution and regeneration of cellulose in NaOH/thiourea aqueous solution. J Polym Sci Part B Polym Phys 40(14): 1521-1529.
27. Zhang JM, Zhang H, Wu J, Zhang J, He JS, Xiang JF (2010) NMR spectroscopic studies of cellobiose solvation in EmimAc aimed to understand the dissolution mechanism of cellulose in ionic liquids. Phys Chem Chem Phys 12(8): 1941-1947.