Evaluation of HOx sources and cycling using measurement- constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem

Atmospheric Chemistry and Physics

Volumn 13, Issue 4, 2013, Pages 2031-2044

  Kim, S ^a,g   Wolfe, G M ^b,h,i   Mauldin, L ^a,e,j   Cantrell, C ^a   Guenther, A ^a   Karl, T ^a   Turnipseed, A ^a   Greenberg, J ^a   Hall, S R ^a   Ullmann, K ^a   Apel, E ^a   Hornbrook, R ^a   Kajii, Y ^c,k   Nakashima, Y ^c,l   Keutsch, F N ^b   Digangi, J P ^b   Henry, S B ^b   Kaser, L ^d   Schnitzhofer, R ^d   Graus, M ^e,f   Hansel, A ^d   Zheng, W ^a   Flocke, F F ^a   more..

^a NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^b UNIVERSITY OF WISCONSIN MADISON   (United States)

^c TOKYO METROPOLITAN UNIVERSITY   (Japan)

^d UNIVERSITY OF INNSBRUCK   (Austria)

^e UNIVERSITY OF COLORADO   (United States)

^f NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^g UNIVERSITY OF CALIFORNIA   (United States)

^h NASA Goddard Space Flight Center   (United States)

ⁱ NASA GODDARD SPACE FLIGHT CENTER   (United States)

^j UNIVERSITY OF HELSINKI   (Finland)

^k KYOTO UNIVERSITY   (Japan)

^l TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

more..

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; CONCENTRATION (COMPOSITION); HYDROXIDE; ISOPRENE; MONOTERPENE; NITROGEN OXIDES; ORGANIC CARBON; OXIDATION; OZONE; PHOTOLYSIS;

EID: 84874377075     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-13-2031-2013     Document Type: Article

References (55)

1. Alaghmand, M., Shepson, P. B., Starn, T. K., Jobson, B. T., Wallace, H. W., Carroll, M. A., Bertman, S. B., Lamb, B., Ed-burg, S. L., Zhou, X., Apel, E., Riemer, D., Stevens, P., and Keutsch, F.: The morning NOx maximum in the forest atmosphere boudary layer, Atmos. Chem. Phys. Discuss., 11, 29251-29282, doi:10.5194/acpd-11-29251-2011, 2011.
2. Apel, E. C., Riemer, D. D., Hills, A., Baugh, W., Orlando, J., Faloona, I., Tan, D., Brune, W., Lamb, B., Westberg, H., Carroll, M. A., Thornberry, T., and Geron, C. D.: Measurement and interpretation of isoprene fluxes and isoprene, methacrolein, and methyl vinyl ketone mixing ratios at the PROPHET site during the 1998 intensive, J. Geophys. Res.-Atmos., 107, 4034 doi10.1029/2000jd000225, 2002.
3. Archibald, A. T., Jenkin, M. E., and Shallcross, D. E.: An isoprene mechanism intercomparison, Atmos. Environ., 44, 5356-5364, doi:10.1016/j. atmosenv.2009.09.016, 2010.
4. Atkinson, R.: Atmospheric chemistry of VOCs and NOx, Atmos. Environ., 34, 2063-2100, 2000.
5. Carslaw, N., Creasey, D. J., Harrison, D., Heard, D. E., Hunter, M. C., Jacobs, P. J., Jenkin, M. E., Lee, J. D., Lewis, A. C., Pilling, M. J., Saunders, S. M., and Seakins, P. W.: OH and HO2 radical chemistry in a forested region of north-western Greece, Atmos. Environ., 35, 4725-4737, doi:10.1016/s1352-2310(01)00089-9, 2001. (Pubitemid 32706375)
6. Chameides, W. L. and Cicerone, R. J.: Effects of nonmethane hydrocarbons in atmosphere, J. Geophys. Res.-Ocean. Atmos., 83, 947-952, doi:10.1029/ JC083iC02p00947, 1978.
7. Crounse, J. D., Paulot, F., Kjaergaard, H. G., and Wennberg, P. O.: Peroxy radical isomerization in the oxidation of isoprene, Phys. Chem. Chem. Phys., 13, 13607-13613, 2011.
8. Crutzen, P. J.: Photochemical reactions initiated by and influencing ozone in unpolluted tropospheric air, Tellus, 26, 47-57, 1974.
9. de Gouw, J. and Warneke, C.: Measurements of volatile organic compounds in the earths atmosphere using proton-transfer-reaction mass spectrometry, Mass Spectrom. Rev., 26, 223-257, 2007. (Pubitemid 46491712)
10. Di Gangi, J., Boyle, E. S., Karl, T., Turnipseed, A., Kim, S., Cantrell, C., Mauldin, R. L., Zheng, W., Flocke, F., Hall, S. R., Ullmann, K., Nakashima, Y., Paul, J. G., Wolfe, G. M., Desai, A. R., Kajii, Y., Guenther, A., and Keutsch, F.: First direct measurements of formaldehyde flux via eddy covariance: Implications for missing in-canopy formaldehyde sources, Atmos. Chem. Phys., 11, 10565-10578, doi:10.5194/acp-11-10565-2011, 2011.
11. DiGangi, J. P., Henry, S. B., Kammrath, A., Boyle, E. S., Kaser, L., Schnitzhofer, R., Graus, M., Turnipseed, A., Park, J.-H., Weber, R. J., Hornbrook, R., Cantrell, C., Maudlin, R. L., III, Kim, S., Nakashima, Y., Wolfe, G. M., Kajii, Y., Apel, E., Goldstein, A. H., Guenther, A., Karl, T., Hansel, A., and Keutsch, F. N.: Observations of glyoal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry, Atmos. Chem. Phys., 12, 9529-5943, doi:10.5194/acp-12-9529-2012, 2012.
12. Edwards, G. D., Cantrell, C. A., Stephens, S., Hill, B., Goyea, O., Shetter, R. E., Mauldin, R. L., Kosciuch, E., Tanner, D. J., and Eisele, F. L.: Chemical ionization mass spectrometer instrument for the measurement of tropospheric HO2 and RO2, Analyt. Chem., 75, 5317-5327, 2003. (Pubitemid 37280555)
13. Eisele, F. L. and Tanner, D. J.: Ion-assisted tropospheric OH measurements, J. Geophys. Res.-Atmos., 96, 9295-9308, doi:10.1029/91jd00198, 1991.
14. Fuchs, H., Bohn, B., Hofzumahaus, A., Holland, F., Lu, K., Nehr, S., Rohrer, F., and Wahner, A.: Detection of HO2 by laser-induced fluorescence: Calibration and interferences from RO2 radicals, Atmos. Meas. Tech., 4, 1209-1225, doi:10.5194/amt-4-1209-2011, 2011.
15. Fuchs, H., Dorn, H.-P., Bachner, M., Bohn, B., Brauers, T., Gomm, S., Hofzumahaus, A., Holland, F., Nehr, S., Rohrer, F., Tillmann, R., and Wahner, A.: Comparison of oh concentration measurements by DOAS and LIF during SAPHIR chamber experiments at high OH reactivity and low NO concentrations, Atmos. Meas. Tech., 5, 1611-1626, doi:10.5194/amt-5-1611-2012, 2012.
16. Graus, M., Muller, M., and Hansel, A.: High resolution PTR-TOF: Quantification and formula confirmation of VOC in real time, J. Am. Soc. Mass Spectrom., 21, 1037-1044, 2010.
17. Heard, D. E. and Pilling, M. J.: Measurement of OH and HO2 in the troposphere, Chem. Rev., 103, 5163-5198, doi:10.1021/cr020522s, 2003.
18. Hofzumahaus, A., Rohrer, F., Lu, K. D., Bohn, B., Brauers, T., Chang, C. C., Fuchs, H., Holland, F., Kita, K., Kondo, Y., Li, X., Lou, S. R., Shao, M., Zeng, L. M., Wahner, A., and Zhang, Y. H.: Amplified trace gas removal in the troposphere, Science, 324, 1702-1704, doi:10.1126/science.1164566, 2009.
19. Hornbrook, R. S., Crawford, J., Edwards, G. D., Goyea, O., Mauldin, R. L., Olson, J. S., and Cantrell, C. A.: Measurements of tropospheric HO2 and RO2 by oxygen dilution modulation and chemical ionization mass spectrometry, Atmos. Meas. Tech., 4, 735-756, doi:10.5194/amt-4-735-2011, 2011.
20. Huisman, A. J., Hottle, J. R., Coenes, K. L., Di Gangi, J. P., Galloway, M. M., Kammrath, A., and Keutsch, F. N.: Laser-induced phosphorescence for the in situ detection of glyoxal at part per trillion mixing ratios, Analyt. Chem., 80, 5584-5591, 2008.
21. Jenkin, M. E., Saunders, S. M., and Pilling, M. J.: The tropo-spheric degradation of volatile organic compounds: A protocol for mechanism development, Atmos. Environ. 31, 81-104, doi:10.1016/s1352-2310(96)00105-7, 1997. (Pubitemid 26345702)
22. Jenkin, M. E., Saunders, S. M., and Pilling, M. J.: The tropospheric degradation of volatile organic compounds: A protocol for mechanism development, Atmos. Environ., 31, 81-104, 1997.
23. Junkermann, F., Platt, U., and Volz-Thomas, A.: A photoelectric detector for the measurement of photolysis frequencies of ozone and other atmospheric molecules, J. Atmos. Chem., 8, 203-227, 1989.
24. Kaser, L., Karl, T., Schnitzhofer, R., Graus, M., Herdlinger-Blatt, I. S., DiGangi, J. P., Sive, B., Turnipseed, A., Hornbrook, R. S., Zheng, W., Flocke, F. M., Guenther, A., Keutsch, F. N., Apel, E., and Hansel, A.: Comparison of different real time VOC measurement techniques in a ponderosa pine forest, Atmos. Chem. Phys. Discuss., 12, 27955-27988, doi:10.5194/acpd-12- 27955-2012, 2012.
25. Kim, S., Karl, T., Guenther, A., Tyndall, G., Orlando, J., Harley, P., Rasmussen, R., and Apel, E.: Emissions and ambient distributions of biogenic volatile organic compounds (BVOCs) in a pon-derosa pine ecosystem: Interpretation of PTR-MS mass spectra, Atmos. Chem. Phys., 10, 1759-1771, doi:10.5194/acp-10-1759-2010, 2010.
26. Lelieveld, J., Butler, T. M., Crowley, J. N., Dillon, T. J., Fischer, H., Ganzeveld, L., Harder, H., Lawrence, M. G., Martinez, M., Taraborrelli, D., and Williams, J.: Atmospheric oxidation capacity sustained by a tropical forest, Nature, 452, 737-740, doi:10.1038/nature06870, 2008. (Pubitemid 351521085)
27. Levy, H.: Normal atmosphere-large radical and formaldehyde concentrations predicted, Science, 173, 141-143, doi:10.1126/science.173.3992.141, 1971.
28. Levy, H.: Photochemistry of lower troposphere, Planet Space Sci., 20, 919-935, doi:10.1016/0032-0633(72)90177-8, 1972.
29. Logan, J. A., Prather, M. J., Wofsy, S. C., and McElroy, M. B.: Tro-pospheric chemistry-a global perspective, J. Geophys. Res.-Ocean. Atmos., 86, 7210-7254, doi:10.1029/JC086iC08p07210, 1981.
30. Lou, S., Holland, F., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C. C., Fuchs, H., Haseler, R., Kita, K., Kondo, Y., Li, X., Shao, M., Zeng, L., Wahner, A., Zhang, Y., Wang, W., and Hofzumahaus, A.: Atmospheric OH reactivities in the Pearl River Delta-China in summer 2006: Measurement and model results, Atmos. Chem. Phys., 10, 11243-11260, doi:10.5194/acp-10-11243- 2010, 2010.
31. Lovelock, J. E.: Methyl chloroform in troposphere as an indicator of OH radical abundance, Nature, 267, 32-32, doi:10.1038/267032a0, 1977.
32. Lu, K. D., Rohrer, F., Holland, F., Fuchs, H., Bohn, B., Brauers, T., Chang, C. C., Haseler, R., Hu, M., Kita, K., Kondo, Y., Li, X., Lou, S. R., Nehr, S., Shao, M., Zeng, L. M., Wahner, A., Zhang, Y. H., and Hofzumahaus, A.: Observation and modelling of OH and HO2 concentrations in the Pearl River Delta 2006: A missing oh source in a voc rich atmosphere, Atmos. Chem. Phys., 12, 1541-1569, doi:10.5194/acp-12-1541-2012, 2012.
33. Mao, J., Ren, X., Zhang, L., Van Duin, D. M., Cohen, R. C., Park, J.-H., Goldstein, A. H., Paulot, F., Beaver, M. R., Crounse, J. D., Wennberg, P. O., DiGangi, J. P., Henry, S. B., Keutsch, F. N., Park, C., Schade, G. W., Wolfe, G. M., Thornton, J. A., and Brune, W. H.: Insights into hydroxyl measurements and atmospheric oxidation in a california forest, Atmos. Chem. Phys., 12, 8009-8020, doi:10.5194/acp-12-8009-2012, 2012.
34. Mauldin, R. L., Berndt, T., Sipila, M., Paasonen, P., Petaja, T., Kim, S., Kurten, T., Stratmann, F., Kerminen, V. M., and Kulmala, M.: A new atmospherically relevant oxidant of sulphur dioxide, Nature, 488, 193-196, doi:10.1038/nature11278, 2012.
35. Mauldin, R. L., Kosciuch, E., Eisele, F. L., Huey, L. G., Tanner, D. J., Sjostedt, S. J., Blake, D., Chen, G., Crawford, J., and Davis, D.: South pole Antarctica observations and modeling re-sults:New insights on HOx radical and sulfur chemistry, Atmos. Environ., 44, 572-581, 2010.
36. Nakashima, Y., Ida, A., Kajii, Y., Greenberg, J., Karl, T., Kim, S., Turnipseed, A., Guenther, A., Di Ganigi, J., Henry, J., Keutsch, F., Schnitzhofer, R., Kaser, L., and Hansel, A.: Total OH reactivity measurements at manitou experimental forest in summer season during beachon-rocs field campaign, American Geophysical Union Fall Meeting, San Francisco, CA USA, 2011.
37. Nakashima, Y., Ida, A., Kajii, Y. J., Greenberg, J., Karl, T., Kim, S., Turnipseed, A., Guenther, A. B., DiGangi, J. P., Henry, S. B., Keutsch, F. N., Schnitzhofer, R., Kaser, L., and Hansel, A.: Total OH reactivity measurements at the Manitou Experimental Forest in summer season during BEACHON-ROCS campaign, Atmos. Chem. Phys., in preparation, 2013.
38. Nolscher, A. C., Williams, J., Sinha, V., Custer, T., Song, W., Johnson, A. M., Axinte, R., Bozem, H., Fischer, H., Pouvesle, N., Phillips, G., Crowley, J. N., Rantala, P., Rinne, J., Kulmala, M., Gonzales, D., Valverde-Canossa, J., Vogel, A., Hoffmann, T., Ouwesloot, H. G., Vila-Guerau de Arellano, J., and Lelieveld, J.: Summertime total oh reactivity measurements from boreal forst during HUMPPA-COPEC 2010, Atmos. Chem. Phys., 12, 8257-8270, doi:10.5194/acp-12-8257-2012, 2012.
39. Peeters, J. and Müller, J. F.: HOx radical regeneration in isoprene oxidation via peroxy radical isomerisations. II: experimental evidence and global impact, Phys. Chem. Chem. Phys., 12, 14227-14235, 2010.
40. Peeters, J., Nguyen, T. L., and Vereecken, L.: HOx radical regeneration in the oxidation of isoprene, Phys. Chem. Chem. Phys., 11, 5935-5939, 2009.
41. Petaja, T., Mauldin, R. L., Kosciuch, E., McGrath, J., Nieminen, T., Paasonen, P., Boy, M., Adamov, A., Kotiaho, T., and Kul-mala, M.: Sulfuric acid and OH concentrations in a boreal forest site, Atmos. Chem. Phys., 9, 7435-7448, doi:10.5194/acp-9-7435-2009, 2009.
42. Ren, X., Mao, J., Brune, W., Cantrell, C., Maudlin, R. L., Horn-brook, R., Kosciuch, E., Olson, J. R., Crawford, J., Chen, G., and Singh, H. B.: Airbonre intercomparison of HOx measurements using laser-induced fuorescence and chemical ionization mass spectrometer during ARCTAS, Atmos. Meas. Tech., 5, 2025-2037, doi:10.5194/gmd-5-2025-2012, 2012.
43. Sadanaga, Y., Yoshino, A., Watanabe, K., Yoshioka, A., Wakazono, Y., Kanaya, Y., and Kajii, Y.: Development of a measurement system of OH reactivity in the atmosphere by using a laser-induced pump and probe tehcnqiue, Rev. Sci. Instr., 75, 2648-2655, 2004.
44. Saunders, S M., Jenkin, M. E., Derwent, R. G., and Pilling, M. J.: Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds, Atmos. Chem. Phys. 3, 161-180, doi:10.5194/acp-3-161-2003, 2003.
45. Sinha, V., Williams, J., Lelieveld, J., Ruuskanen, T. M., Kajos, M. J., Patokoski, J., Helllen, H., Hakola, H., Mogensen, D., Boy, M., Rinne, J., and Kulmala, M.: OH reactivity measurements within a Boreal Forest: Evidence for unknown reactive emissions, Environ. Sci. Technol., 44, 6614-6620, 2010.
46. Singh, H. B.: Atmospheric halocarbons-evidence in favor of reduced average hydroxyl radical concentration in troposphere, Geophys. Res. Lett., 4, 101-104, doi:10.1029/GL004i003p00101, 1977.
47. Sjostedt, S. J.: Investigation of photochemistry at high latitudes: Comparison of model predictions to measurements of short lived species, Ph. D., Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, USA, 174 pp., 2006.
48. Slusher, D. L., Huey, L. G., Tanner, D. J., Flocke, F., and Roberts, J. M.: A thermal dissociation-chemical ionization mass spectrom-etry (TD-CIMS) technique for the simultaneous measurement of peroxyacyl nitrates and dinitrogen pentoxide, J. Geophys. Res., 109, D19315, doi:10.1029/2004JD004670, 2004. (Pubitemid 39660694)
49. Stavrakou, T., Peeters, J., and Müller, J.-F.: Improved global modelling of HOx recycling in isoprene oxidation: evaluation against the GABRIEL and INTEX-A aircraft campaign measurements, Atmos. Chem. Phys., 10, 9863-9878, doi:10.5194/acp-10-9863-2010, 2010.
50. Tan, D., Faloona, I., Simpas, J. B., Brune, W., Shepson, P. B., Couch, T. L., Sumner, A. L., Carroll, M. A., Thornberry, T., Apel, E., Riemer, D., and Stockwell, W.: HOx budgets in a deciduous forest: Results from the PROPHET summer 1998 campaign, J. Geophys. Res.-Atmos., 106, 24407-24427, doi:10.1029/2001jd900016, 2001.
51. Tanner, D. J., Jefferson, A., and Eisele, F. L.: Selected ion chemical ionization mass spectrometric measurement of OH, J. Geophys. Res.-Atmos., 102, 6415-6425, doi:10.1029/96jd03919, 1997.
52. Whalley, L. K., Edwards, P. M., Furneaux, K. L., Goddard, A., In-gham, T., Evans, M. J., Stone, D., Hopkins, J. R., Jones, C. E., Karunaharan, A., Lee, J. D., Lewis, A. C., Monks, P. S., Moller, S. J., and Heard, D. E.: Quantifying the magnitude of a missing hydroxyl radical source in a tropical rainforest, Atmos. Chem. Phys., 11, 7223-7233, doi:10.5194/acp-11-7223-2011, 2011.
53. Wofsy, S. C., McConnel, J. C., and McElroy, M. B.: Atmospheric CH4, CO, and CO2, J. Geophys. Res., 77, 4477-4493, doi:10.1029/JC077i024p04477, 1972.
54. Wolfe, G. M. and Thornton, J. A.: The Chemistry of Atmosphere-Forest Exchange (CAFE) Model-Part 1: Model description and characterization, Atmos. Chem. Phys., 11, 77-101, doi:10.5194/acp-11-77-2011, 2011.
55. Wolfe, G. M., Crounse, J. D., Parrish, J. D., St. Clair, J. M., Beaver, M. R., Paulot, F., Yoon, T. P., Wennberg, P. O., and Keutsch, F. N.: Photolysis, OH reactivity and ozone reactivity of a proxy for isoprene-derived hydroperoxyenals (HPALDs), Phys. Chem. Chem. Phys., 14, 7276-7286, doi:10.1039/C2CP40388A, 2012.