Square-wave voltammetric determination of rutin in pharmaceutical formulations using a carbon composite electrode modified with copper (II) phosphate immobilized in polyester resin

Brazilian Journal of Pharmaceutical Sciences

Volumn 48, Issue 4, 2012, Pages 639-649

  Freitas, Kellen Heloizy Garcia ^a   Fatibello Filho, Orlando ^b   de Mattos, Ivanildo Luiz ^c  

^a FEDERAL UNIVERSITY OF PARÁ   (Brazil)

^b FEDERAL UNIVERSITY OF SÃO CARLOS   (Brazil)

^c UNIVERSITY OF CHILE   (Chile)

Author keywords

Modified carbon composite electrode application; Rutin determination in pharmaceuticals samples; Square wave voltammetry determination of rutin

Indexed keywords

COPPER COMPLEX; COPPER PHOSPHATE; POLYESTER; POTASSIUM CHLORIDE; RUTOSIDE; SILVER CHLORIDE; UNCLASSIFIED DRUG;

ACCURACY; ARTICLE; DRUG DETERMINATION; ELECTROCHEMISTRY; ELECTRODE; ENERGY DISPERSIVE X RAY SYSTEM; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; INTERMETHOD COMPARISON; LIMIT OF DETECTION; MODIFIED CARBON COMPOSITE ELECTRODE; PH; POTENTIOMETRY; ROENTGEN SPECTROSCOPY; SCANNING ELECTRON MICROSCOPY; SQUARE WAVE VOLTAMMETRY; SURFACE PROPERTY;

EID: 84874239282     PISSN: 19848250     EISSN: 21759790     Source Type: Journal    
DOI: 10.1590/S1984-82502012000400007     Document Type: Article

References (39)

1. BRETT, A.M.O.; BRETT, C.M.A. Electroquímica: princípios, métodos e aplicações. New York: Oxford University Press, 1993. 471 p.
2. BRETT, A.M.O.; GHICA, M.E. Electrochemical oxidation of quercetin. Electroanal., v.15, p.1745-1750, 2003.
3. CESPEDES, F.; MARTINEZ-FABREGAS, E.; ALEGRET, S. New materials for electrochemical sensing-rigid conducting composites. Trac-. Trends Anal. Chem., v.15, p.296-304, 1996.
4. CHEN, G.; ZHANG, H.; YE, J. Determination of rutin and quercetin in plants by capillary electrophoresis with electrochemical detection. Anal. Chim. Acta, v.423, p.69-76, 2000.
5. CHEN, X.; WANG, Z.; ZHANG, F.; ZHU, L.; LI, Y.; XIA, Y. Determination of rutin on the poly(p-aminobenzene sulfonic acid) modified glassy carbon electrode. Chem. Pharm. Bull., v.58, p.475-478, 2010.
6. DAPKEVICIOUS, A.; BEEK, T.A.V.; NIEDERLANDER, H.A.G.; GROOT, A.D. On-Line detection of antioxidative activity in High-Performance Liquid Chromatography eluates by chemiluminescence. Anal. Chem., v.71, p.736-740, 1999.
7. DOMENECH, A.; GARCIA-ESPANA, E.; LUIS, S.V.; MARCELINO, V.; MIRAVET, J.F. Electrochemistry of copper complexes with polyaza[n]paracyclophanes. Influence of ATP as an exogen ligand on the relative stability of the Cu(II) and Cu(I) oxidation states. Inorg. Chim. Acta, v.299, p.238-246, 2000.
8. ERLUND, I.; KOSONEN, T.; ALFTHAN, G.; MÄENPÄÄ, J.; PERTTUNEN, K.; KENRAALI, J.; PARANTAINEN, J.; ARO, A. Pharmacokinetics of quercetin from quercetin aglycone and rutin in healthy volunteers. Eur. J. Clin. Pharmacol., v.56, p.545-553, 2000.
9. FATIBELLO-FILHO, O.; VIEIRA, I.C. Construction and analytical application of a biosensor based on stearic acid-graphite powder modified with sweet potato tissue in organic solvents. Fresen. J. Anal. Chem., v.368, p.338-343, 2000.
10. FRANZOI, A.C.; MIGOWSKI, P.; DUPONT, J.; VIEIRA, I.C. Development of biosensors containing laccase and imidazolium bis(trifluoromethylsulfonyl)imide ionic liquid for the determination of rutin. Anal. Chim. Acta, v.639, p.90-95, 2009.
11. FRANZOI, A.C.; SPINELLI, A.; VIEIRA, L.C. Rutin determination in pharmaceutical formulations using a carbon paste electrode modified with poly (vinylpyrrolidone). J. Pharm. Biomed. Anal., v.47, p.973-977, 2008.
12. FREITAS, K.H.G.; FATIBELLO-FILHO, O. Carbon composite electrode modified with copper (II) phosphate immobilized in a polyester resin for voltammetric determination of catechin in teas. Anal. Lett., v.43, p.1-14, 2010.
13. 2immobilized in polyester resin. Talanta, v.81, p.1102-1108, 2010.
14. FREITAS, K.H.G.; MEDEIROS, R.A.; FATIBELLO-FILHO, O. Voltammetric determination of rutin using a carbon composite electrode modified with copper(II)-resin. Anal. Lett., v.42, p.881-897, 2009.
15. GENE, R.M.; CARTANA, C.; ADZET, T.; MARIN, E.; PANELLA, T.; CANIGUERAL, S. Anti-Inflammatory and analgesic activity of baccharis trimera: identification of its active constituents. Planta Med., v.62, p.232-235, 1996.
16. GHICA, M.E.; BRETT, A.M.O. Electrochemical oxidation of rutin. Electroanal., v.17, p.313-318, 2005.
17. HE, J.; WANG, Y.; DENG, N.; ZHAB, Z.; LIN, X. Cyclic voltammograms obtained from the optical signals: study of the successive electro-oxidations of rutin. Electrochim. Acta, v.52, p.6665-6672, 2007.
18. HE, J.; WANG, Y.; DENG, N.; LIN, X. Study of the adsorption and oxidation of antioxidant rutin by cyclic voltammetry-voltabsorptometry. Bioelectrochemistry, v.71, p.157-163, 2007.
19. JANEIRO, P.; BRETT, A.M.O. Catechin electrochemical oxidation mechanisms. Anal. Chim. Acta, v.518, p.109-115, 2004.
20. KRAUSE, M.S.; RAMALEY, L. Analytical application of square wave voltammetry. Anal. Chem., v.41, p.1365-1369, 1969.
21. LI, C.H.; CHEN, A.J.; CHEN, X.F.; CHEN, X.G.; ZU, Z.D. Separation and simultaneous determination of rutin, puerarin, daidzein, esculin and esculetin in medicinal preparations by non-aqueous capillary. J. Pharm. Biomed. Anal., v.39, p.125-131, 2005.
22. LIU, X.H.; LI, L.; ZHAO, X.P.; LU, X.Q. Electrochemical behavior of rutin on a multi-walled carbon nanotube and ionic liquid composite film modified electrode. Colloids Surf. B., v.81, p.344-349, 2010.
23. MIRCESKI, V.; KOMORSKY-LOVRIC, S.; LOVRIC, M. Square-wave voltammetry: theory and application. Berlin: Springer, 2007. 201 p.
24. NUENGCHAMNONG, N.; LOKKERBOL, A.H.; INGKANINAN, K. Separation and detection of the antioxidant flavonoids, rutin and quercetin, using hplc coupled on-line with colorimetric detection of antioxidant activity. Naresuan U. J., v.12, p.25-37, 2004.
25. OSTERYOUNG, J.G.; OSTERYOUNG, R.A. Square wave voltammetry. Anal. Chem., v.57, p.101A-110A, 1985.
26. PACKER, L. Handbook of antioxidants. Oxidative stress and disease. Los Angeles: CRC Press, 2001. 91 p.
27. PEREIRA, A.C.; SANTOS, A.S.; KUBOTA, L.T. Tendências em modificações de eletrodos amperométricos para aplicações analíticas. Quím. Nova, v.25, p.1012-1021, 2002.
28. PEREIRA, A.V.; FATIBELLO-FILHO, O. Flow injection spectrophotometric determination of L-ascorbic acid in pharmaceutical formulations with on-line solid-phase reactor containing copper (II) phosphate. Anal. Chim. Acta, v.366, p.55-62, 1998.
29. RAMALEY, L.; KRAUSE, M.S. Theory of square wave voltammetry. Anal. Chem., v.41, p.1362-1365, 1969.
30. SANTOS, S.X.D.; MAZO, L.H.; CAVALHEIRO, E.T.G. The use of a graphite-silicone rubber composite electrode in the determination of rutin in pharmaceutical formulation. J. Braz. Chem. Soc., v.19, p.1600-1606, 2008.
31. SCHOLZ, F. Electroanalytical methods: guide to experiments and applications. New York: Springer, 2002. 331 p.
32. SOMASUNDRUM, M.; KIRTIKARA, K.; TANTICHAROEN, M. Amperometric determination of hydrogen peroxide by direct and catalytic reduction at a copper electrode. Anal. Chim. Acta, v.319, p.59-70, 1996.
33. SUN, W.; YANG, M.; LI, Y.; JIANG, Q.; LIU, S.; JIAO, K. Electrochemical behavior and determination of rutin on a pyridiniumbased ionic liquid modified carbon paste electrode. J. Pharm. Biom. Anal., v.48, p.1326-1331, 2008.
34. VAZQUEZA, M.V.; SANCHEZA, S.R.; CALVOB, E.J.; SCHIFFRINC, D.J. The electrochemical reduction of oxygen on polycrystalline copper in borax buffer. J. Electroanal. Chem., v.374, p.189-197, 1994.
35. VOLIKAKIS, G.J.; EFSTATHIOU, C.E. Determination of rutin and other flavonoids by flow-injection/adsorptive stripping voltammetry using nujol-graphite and diphenylether-graphite paste electrodes. Talanta, v.51, p.775-785, 2000.
36. WANG, Q.J.; DING, F.; LI, H.; HE, P.G.; FANG, Y.Z. Determination of hydrochlorothiazide and rutin in Chinese herb medicines and human urine by capillary zone electrophoresis with amperometric detection. J. Pharm. Biomed. Anal., v.30, p.1507-1514, 2003.
37. XU, J.; ZHANG, H.; CHEN, G. Carbon nanotube/polystyrene composite electrode for microchip electrophoretic determination of rutin and quercetin in Flos Sophorae Immaturus. Talanta, v.73, p.932-937, 2007.
38. YANG, S.L.; QU, L.B.; LI, G.; YANG, R.; LIU, C.C. Gold nanoparticles/ ethylenediamine/carbon nanotube modified glassy carbon electrode as the voltammetric sensor for selective determination of rutin in the presence of ascorbic acid. J. Electroanal. Chem., v.645, p.115-122, 2010.
39. ZU, Y.; LI, C.; FU, Y.; ZHAO, C. Simultaneous determination of catechin, rutin, quercetin kaempferol and isorhamnetin in the extract of sea buckthorn (Hippophae rhamnoides L.) leaves by RP-HPLC with DAD. J. Pharm. Biomed. Anal., v.41, p.714-719, 2006.