Thermodynamic, equilibrium, and kinetic studies of adsorption of pillarized and organofunctionalized smectite clay for Th4+ removal

Journal of Ceramic Science and Technology

Volumn 3, Issue 1, 2012, Pages 17-28

  Guerra, D J L ^a   Menonca E S ^a   Silva, R A R ^a   Lara, W ^a  

^a FEDERAL UNIVERSITY OF MATO GROSSO   (Brazil)

Author keywords

Adsorption isotherms; Kinetic; Smectite; Thermodynamic; Thorium

Indexed keywords

3-MERCAPTOPROPYLTRIMETHOXYSILANE; ADSORBENT DOSAGE; ADSORPTION CAPACITIES; ADSORPTION PROCESS; AMAZON REGION; BATCH PROCESS; KINETIC MODELS; KINETIC STUDY; LIQUID/SOLID INTERFACE; MODIFIED CLAYS; ORGANOFUNCTIONALIZED; PILLARING PROCESS; ROOM TEMPERATURE; SMECTITE CLAYS; SMECTITES; SOLID-LIQUID INTERFACES;

ADSORPTION; ADSORPTION ISOTHERMS; BATCH DATA PROCESSING; EQUILIBRIUM CONSTANTS; KINETIC THEORY; KINETICS; THERMODYNAMICS; THORIUM; ZIRCONIUM;

CLAY MINERALS;

EID: 84873339897     PISSN: 21909385     EISSN: None     Source Type: Journal    
DOI: 10.4416/JCST2012-00040     Document Type: Article

References (57)

1. Guerra, D.L., Lemos, V.P., Airoldi, C., Angélica, R.S.: Influence of the acid activation of pillared smectites from amazon (Brazil) in adsorption process with butylamine, Polyhedron, 25, 2880-2890, (2006).
2. Liou, T.H.: Development of mesoporous structure and high adsorption capacity of biomass based activated carbon by phosphoric acid and zinc chloride activation, Chem. Eng. J., 158, 129-142, (2010).
3. Salinas-Castillo, A., Pastor, I., Mallavia, R., Mateo, C.R.: Immobilization of a trienzymatic system in a sol-gel Matrix: A new fluorescent biosensor for xanthine, Biosens. Bioelectron., 24, 1053-1056, (2008).
4. Caillou, S., Gerin, P.A., Nonckreman, C.J., Fleith, S., Dupont- Gillain, C.C., Landoulsi, J., Pancera, S.M., Genet, M.J., Rouxhet, P.G.: Enzymes at solid Surfaces: nature of the interface and physico-chemical process, Electrochim. Acta, 54, 116-122, (2008).
5. Sales, J.A.A., Airoldi, C.: Epoxide silylant agent ethylenediamine reaction product anchored on silica gel-thermodynamics of cation-nitrogen interaction at solid/liquid interface, J. Non-Cryst. Solids, 330, 142-149, (2003).
6. Türünç, O., Kahraman, M.V., Akdemir, Z.S., Kayaman-Apohan, N., Güngör, A.: Immobilization of a-amylase onto cyclic carbonate bearing hybrid material, Food Chem., 112, 992-997, (2009).
7. Guerra, D.L., Airoldi, C.: The performance of urea-intercalated and delaminated kaolinite-adsorption kinetics involving copper and lead, J. Brazil. Chem. Soc., 20, 19-30, (2009).
8. Tekin, N., Kadinci, E., Demirbas, Ö., Alkan, M., Kara, A.: Adsorption of polyvinylimidazole onto kaolinite, J. Colloid Interface Sci., 89, 472-479, (2006).
9. Zhao, D.L., Feng, S.J., Chen, C.L., Chen, S.H., Xu, D., Wang, X.K.: Adsorption of Thorium(IV) on MX-80 Bentonite: effect of pH, ionic strength and temperature, Appl. Clay Sci., 41, 17-23, (2008).
10. Degueldre, C., Kline, A.: Study of thorium association and surface precipitation on colloids, Earth Planet. Sci. Lett., 264, 104-113, (2007).
11. Manohar, D.M., Noeline, B.F., Anirudhan, T.S.: Adsorption performance of al-pillared bentonite clay for the removal of Cobalt(III) from aqueous phase, Appl. Clay Sci., 31, 194-206, (2006).
12. Karabulut, S., Karabulut, A., Denizli, A., Yürüm, Y.: Batch removal of Copper(II) and Zinc(II) from aqueous solutions with low-rank turkish coals, Sep. Purif. Technol., 18, 177-184, (2000).
13. Babel, S., Kurniawan, T.A.: Cr(VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan, Chemosphere, 54, 951-967, (2004).
14. Minamisawa, M., Minamisava, H., Yoshida, S., Takai, N.: Adsorption behavior of heavy metals on biomaterials, J. Agr. Food Chem., 52, 5606-5611, (2004).
15. Kanaan, N., Malar, S.J.S.: Removal of mercury (II) ions by adsorption onto dates nut and commercial activated Carbons: A comparative study, Indian J. Chem. Techn., 12, 522-527, (2005).
16. Almond, G.G., Harris, R.K., Franklin, K.R.: Sorption Behavior of U(VI) on Phyllite: Experiments and Modeling, J. Mater. Chem., 7, 681-687, (1997).
17. Leppert, D.: Heavy Metals Sorption with Clinoptilolite Zeolite: Alternatives for Treating Contaminated Soil and Water, Min. Engng., 42, 604-608, (1990).
18. Tang, X., Li, Z., Chen, Y.: Adsorption behavior of Zn(II) on calcinated chinese loess, J. Hazard. Mater., 161, 824-834, (2009).
19. Xu, S., Boyd, S.A.: Cationic surfactant adsorption by swelling and non-swelling layer silicates, Langmuir, 11, 2508-2514, (1995).
20. Penner, D., Lagaly, G.: Influence of Organic and Inorganic Salts on the Coagulation of Montmorillonite Dispersions, Clay Clay Miner., 48, 246-255, (2000).
21. Luptáková, V., Plesch, G.: Intercalated Cu(II) Benzimidazole Complexes in the Interlayer Space of Montmorillonite, Clay Miner., 40, 295-302, (2005).
22. Talip, Z., Eral, M., Hiçsönmez, Ü.: Adsorption of thorium from aqueous solutions by perlite, J. Environ. Radioactiv., 100, 139-143, (2009).
23. Guerra, D.L., Silva, E.M., Lara, W., Batista, A.C.: Removal of Hg(II) from aqueous medium by adsorption onto natural and alkyl-amine modified brazilian bentonite, Clay. Clay Miner., 59, 568-580, (2011).
24. Acharya, J., Sahu, J.N., Mohanty, C.R., Meikap, B.C.: Removal of Lead(II) from wastewater by activated carbon developed from tamarind wood by zinc chloride activation, Chem. Eng. J., 149, 249-262, (2009).
25. Langmuir, I.: The adsorption of gases on plane surfaces of glass, mica and platinum, J. Am. Chem., 57, 1361-1403, (1918).
26. Freundlich, H.M.F.: Über die adsorption in Lösungen (Adsoption in Solution), Z. Phys. Chem., 57, 385-470, (1906).
27. Sips, R.: On the structure of a catalyst surface, J. Chem. Phys., 16, 490-495, (1948).
28. Cestari, A.R., Vieira, E. F. S., Vieira, G.S., da Costa, L.P., Tavares, A.M.G., Loh, W., Airoldi, C.: The removal of reactive dyes from aqueous solutions using chemically modified mesoporous silica in the presence of anionic surfactant-the temperature dependence and a thermodynamic multivariate analysis, J. Hazard. Mater., 161, 307-316, (2009).
29. Zachara, J.M., McKinley, J.P.: Influence of Hydrolysis on the Sorption of Metal Cations by Smectites: Importance of Edge Coordination Reactions, Aquat. Sci., 55, 250-261, (1993).
30. Nunes, L.M., Airoldi, C.: Intercalation behaviour of some aromatic heterocyclic amines into a-titanium hydrogen phosphate, Mater. Res. Bull., 34, 2121-2130, (1999).
31. Nunes, L.M., Airoldi, C.: The intercalation of some heterocyclic amines into a-titanium Hydrogenphosphete-Structural and calorimetric data, J. Solid State Chem., 154, 557-563, (2000).
32. Prado, A.G.S., Airoldi, C.: Adsorption, preconcentration and separation of cations on silica gel chemically modified with herbicide 2,4- dichlorophenoxyacetic acid, Anal. Chim. Acta, 432, 201-211, (2001).
33. Prado, A.G.S., Arakaki, L.N.H., Airoldi, C.: Adsorption and separation of Cations on silica gel chemically modified by homogeneous and heterogeneous routes with the Ethylenimine anchored on Thiol modified silica gel, Green Chem., 4, 42-46, (2002).
34. Lima, I.S., Airoldi, C.: A Thermodynamic Investigation on Chitosan-Divalent Interactions, Thermochim. Acta, 421, 133-139, (2004).
35. Ruiz, V.S.O., Airoldi, C.: Thermochemical data for n-alkylmonoamine intercalation into crystalline lamellar zirconium phenylphosphonate, Thermochim. Acta, 420, 73-78, (2004).
36. Herrero, R., Lodeiro, P., Rey-Castro, C., Vilariño, T., Vicente, M.E.S.: Removal of inorganic mercury from aqueous solutions by biomass of the marine macroalga Cystoseira baccata, Water Res., 39, 3199-3210, (2005).
37. Ruiz, V.S.O., Petrucelli, G.C., Airoldi, C.: Inorganic-organic hybrids derived from lamellar acidic kenyiate immobilizations for cation removal at the Solid/Liquid interface, J. Mater. Chem., 16, 2338-2346, (2006).
38. Guerra, D.L., Viana, R.R., Airoldi, C.: Adsorption of mercury cation on chemical modified clay, Mater. Res. Bull., 44, 485-491, (2009).
39. Lazarin, A.M., Airoldi, C.: Thermodynamic of the nickel and cobalt removal from aqueous solution by layered crystalline organofunctionalized barium phosphate, J. Chem. Thermodyn., 41, 21-25, (2009).
40. Guerra, D.L., Viana, R.R., Airoldi, A.: Thermochemical data for n-alkylmonoamine functionalization into lamellar silicate al-kanemite, J. Chem. Thermodyn., 43, 69-74, (2011).
41. Burnham, A.K., Dinh, L.N.: A comparison of isoconversional and model-fitting approaches to kinetic parameter estimation and application predictions, J. Therm. Anal. Calorim., 89/2, 479-490, (2007).
42. Girgis, B.S., El-Barawy, K.A., Felix, N.S.: Dehydration kinetics of some Smectite: A thermogravimetric study, Thermochim. Acta, 111, 9-19, (1987).
43. Sales, J.A.A., Faria, F.P., Prado, A.G.S., Airoldi, C.: Attachment of 2-aminomethylpyridine molecule onto grafted silica gel surface and its ability in chelating cations, Polyhedron, 23, 719-725, (2004).
44. Ebrahimi-Kahrizsangi, R., Abbasi, M.H.: Evaluation of the teliability of coats-redfern methods for the kinetic analysis of non-isothermal TGA, T. Nonferr. Met. Soc., 18, 217-221, (2008).
45. Horovitz, H.H., Metzger, G.: A new analysis of thermogravimetric traces, Anal. Chem., 35, 1464-1468, (1963).
46. Guo, P., Duan, T., Song, X., Xu, J., Chen, H. : Effect of soil pH and organic matter on distribution of thorium fractions in soil contaminated by rare-earth industries, Talanta, 77, 624-627, (2008).
47. Bhainsa, K.C., D'Souza, S.F.: Thorium biosorption by Aspergillus Fumigatus, a filamentous fungal biomass, J. Hazard. Mater., 165, 670-676, (2009).
48. Crespo, M.T., Gascón, J.L., Acena, M.L.: Techniques and analytical methods in the determination of uranium, thorium, plutonium, americium and radium by adsorption on manganese dioxide, Sci. Total Environ., 130-131, 383-391, (1993).
49. Murphy, R.J., Lenhart, J.J., Honeyman, B.D.: The sorption of thorium (IV) and uranium (VI) to hematite in the presence of natural organic matter, Colloids Surf. A., 157, 47-62, (1999).
50. Pang, X., Tang, F.: Morphological control of mesoporous materials using inexpensive silica sources, Micropor. Mesopor. Mat., 85, 1-6, (2005).
51. Catalano, J.G., Brown Jr., G.E.: Uranyl Adsorption onto Montmorillonite: Evaluation of Binding Sites and Carbonate Complexation, Geochim. Cosmochim. Acta, 12, 2995-3005, (2005).
52. Yeddou, N., Bensmaili, A.: Kinetic models for the sorption of dye from aqueous solution by clay-wood sawdust mixture, Desalination, 185, 499-508, (2005).
53. Hongxia, Z., Yongxin, X., Zuyi, T.: Sorption of uranyl ions Gibbsite: effects of contact time, pH, ionic strength, concentration and anion of electrolyte, Colloids Surf. A., 252, 1-5, (2005).
54. Goel, J., Kadirvelu, K., Rajagopal, C., Gary, V.K.: Removal of lead (II) by adsorption using granular activated Carbon: batch and column studies, J. Hazard. Mater., 125, 211-220, (2005).
55. Han, R.P., Zhang, J.H., Zou, W.H., Xiao, H.J., Shi, J., Liu, H.M.: Biosorption of Copper(II) and Lead(II) from aqueous solution by chaff in a fixed-bed column, J. Hazard. Mater., 133, 262-268, (2006).
56. Han, R.P., Wang, Y., Zou, W.H., Wang, Y.F., Shi, J.: Comparison of linear and nonlinear analysis in estimating the thomas model parameters for methylene blue adsorption onto natural zeolite in fixed-bed column, J. Hazard. Mater., 145, 331-335, (2007).
57. Xu, X., Gao, B., Wang, W., Yue, Q., Wang, Y., Ni, S.: Adsorption of phosphate from aqueous solutions onto modified wheat Residue: characteristics, kinetics and column studies, Colloids Surf. B, 70, 46-52, (2009).