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Volumn 32, Issue 2, 2013, Pages 468-472

Entropies of organolithium aggregation based on measured microsolvation numbers

Author keywords

[No Author keywords available]

Indexed keywords

DONOR LIGANDS; MICROSOLVATION; MONODENTATES; NMR COUPLING; ORGANOLITHIUMS; TOLUENE SOLUTION;

EID: 84872959704     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om3009348     Document Type: Article
Times cited : (13)

References (26)
  • 2
    • 0000339985 scopus 로고    scopus 로고
    • For a short list of pioneering discoveries of discrete NMR signals for lithium-coordinated donor ligands, see: Reich, H. J.; Kulicke, K. J. J. Am. Chem. Soc. 1996, 118, 273-274
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 273-274
    • Reich, H.J.1    Kulicke, K.J.2
  • 7
    • 84985710798 scopus 로고
    • footnote 10 on p 1978 therein.
    • Bauer, W.; Seebach, D. Helv. Chim. Acta 1984, 67, 1972-1988, footnote 10 on p 1978 therein.
    • (1984) Helv. Chim. Acta , vol.67 , pp. 1972-1988
    • Bauer, W.1    Seebach, D.2
  • 9
  • 12
    • 0030698167 scopus 로고    scopus 로고
    • An impression of successively decreasing Li-ligand bond energies may be gained from calculations of the sequential microsolvation steps at the (hypothetical) monomeric methyllithium, as reported by: last paragraph on p 11257 therein.
    • An impression of successively decreasing Li-ligand bond energies may be gained from calculations of the sequential microsolvation steps at the (hypothetical) monomeric methyllithium, as reported by: Abbotto, A.; Streitwieser, A.; Schleyer, P.; von, R. J. Am. Chem. Soc. 1997, 119, 11255-11268, last paragraph on p 11257 therein.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 11255-11268
    • Abbotto, A.1    Streitwieser, A.2    Schleyer, P.3    Von, R.4
  • 13
    • 0034834622 scopus 로고    scopus 로고
    • The strong electric C-Li dipole moment of a monomer will be practically cancelled in the corresponding dimer (see Scheme 1 or 2); this was considered to be the major (thermodynamic) driving force promoting aggregation in a weakly polar ethereal solvent, as remarked by: on p 8077.
    • The strong electric C-Li dipole moment of a monomer will be practically cancelled in the corresponding dimer (see Scheme 1 or 2); this was considered to be the major (thermodynamic) driving force promoting aggregation in a weakly polar ethereal solvent, as remarked by: Reich, H. J.; Goldenberg, W. S.; Gudmundsson, B. Ö.; Sanders, A. W.; Kulicke, K. J.; Simon, K.; Guzei, I. A. J. Am. Chem. Soc. 2001, 123, 8067-8079, on p 8077.
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 8067-8079
    • Reich, H.J.1    Goldenberg, W.S.2    Gudmundsson, B.Ö.3    Sanders, A.W.4    Kulicke, K.J.5    Simon, K.6    Guzei, I.A.7
  • 21
    • 0030857132 scopus 로고    scopus 로고
    • 6Li) coupling. Because of their high ligand exchange rates, however, such monodentate nitrogen ligands are apparently unsuited(23) for an analysis of the role of free donors in aggregation equilibria. For an example and further references, see: Waldmüller, D.; Kotsatos, B. J.; Nichols, M. A.; Williard, P. G. J. Am. Chem. Soc. 1997, 119, 5479-5480
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 5479-5480
    • Waldmüller, D.1    Kotsatos, B.J.2    Nichols, M.A.3    Williard, P.G.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.