Removal of cations using ion-binding terpolymer involving 2-amino-6-nitro-benzothiazole and thiosemicarbazide with formaldehyde by batch equilibrium technique

Journal of Hazardous Materials

Volumn 248-249, Issue 1, 2013, Pages 59-68

  Ahamed, Mohamed A Riswan ^a   Jeyakumar, Duraisamy ^b   Burkanudeen, Abdul R ^c  

^a Oxford Engineering College   (India)

^b CENTRAL ELECTROCHEMICAL RESEARCH INSTITUTE   (India)

^c JAMAL MOHAMED COLLEGE   (India)

Author keywords

Ion exchangers; SEM; Terpolymer; TGA

Indexed keywords

BATCH EQUILIBRIUM; BATCH EQUILIBRIUM METHOD; CATION EXCHANGES; CONTACT TIME; EFFECT OF PH; ION-BINDING; PHYSICOCHEMICAL PARAMETERS; SPECTRAL STUDIES; TGA; THIOSEMICARBAZIDES;

FORMALDEHYDE; GEL PERMEATION CHROMATOGRAPHY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYCONDENSATION; POSITIVE IONS; RESINS; REUSABILITY; SCANNING ELECTRON MICROSCOPY; SPECTROSCOPIC ANALYSIS; SURFACE ANALYSIS; TERPOLYMERS; X RAY DIFFRACTION;

THERMOGRAVIMETRIC ANALYSIS;

2 AMINO 6 NITRO BENZOTHIAZOLE; BENZOTHIAZOLE DERIVATIVE; COBALT; COPPER; ELECTROLYTE; FORMALDEHYDE; IRON; LEAD; NICKEL; POLYMER; RESIN; THIOSEMICARBAZIDE; UNCLASSIFIED DRUG; ZINC;

CATION; CONDENSATION; ELECTROLYTE; EQUILIBRIUM; ION EXCHANGE; ORGANIC COMPOUND; PHYSICOCHEMICAL PROPERTY; POLYMER; RECYCLING; RESIN;

ABSORPTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; MOLECULAR WEIGHT; PH; PHYSICAL CHEMISTRY; POLYMERIZATION; POROSITY; PROTON NUCLEAR MAGNETIC RESONANCE; SCANNING ELECTRON MICROSCOPY; THERMOGRAVIMETRY; THERMOSTABILITY; X RAY DIFFRACTION;

BENZOTHIAZOLES; CATION EXCHANGE RESINS; CATIONS; FORMALDEHYDE; ION EXCHANGE; MAGNETIC RESONANCE SPECTROSCOPY; MICROSCOPY, ELECTRON, SCANNING; POLYMERS; SEMICARBAZIDES; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; THERMOGRAVIMETRY; X-RAY DIFFRACTION;

EID: 84872834752     PISSN: 03043894     EISSN: 18733336     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2012.12.047     Document Type: Article

References (33)

1. Hoai N.T., Yoo D.K., Kim D. Batch and column separation characteristics of copper-imprinted porous polymer micro-beads synthesized by a direct imprinting method. J. Hazard. Mater. 2010, 173:462-467.
2. Devi M., Fingermann M. Inhibition of acetylcholinesterase activity in the central nervous system of the red swamp crayfish, Procambarus clarkii, by mercury, cadmium, and lead. Bull. Environ. Contam. Toxicol. 1995, 55:746-750.
3. Rivas B.L., Pooley S.A., Maturana H.A., Villegas S. Metal ions uptake of acrylamide derivatives resins. Macromol. Chem. Phys. 2001, 202:443-447.
4. Kara A., Uzun L., Besirli N., Denizli A. Poly(ethylene glycol dimethacrylate-n-vinyl imidazole) beads for heavy metal removal. J. Hazard. Mater. 2004, 106:93-99.
5. Singru R.N., Gurnule W.B., Khati V.A., Zade A.B., Dontulwar J.R. Eco-friendly application of p-cresol-melamine-formaldehyde polymer resin as an ion-exchanger and its electrical and thermal study. Desalination 2010, 263:200-210.
6. Arasaretnam S., Karunanayake L. Synthesis, characterization, and metal adsorption properties of tannin-phenol-formaldehyde resins produced using tannin from dried fruit of Terminalia chebula (Aralu). J. Appl. Polym. Sci. 2010, 115:1081-1088.
7. Burkanudeen A., Karunakaran M. Chelation ion-exchange properties of ortho-nitrophenol-thiourea-paraformaldehyde terpolymer. Orient. J. Chem. 2002, 18:65-68.
8. Karunakaran M., Burkanudeen A. Synthesis and characterization of anthranilic acid-thiourea-paraformaldehyde copolymer. Orient. J. Chem. 2003, 19:225-228.
9. Da costa P.A., Teixiera V.G. Influence of the matrix porosity on the synthesis and adsorption behavior of dithiocarbamate styrenic resins toward zinc(II) and cadmium(II) ions. J. Appl. Polym. Sci. 2010, 116:3070-3078.
10. Azarudeen R.S., Ahamed M.A.R., Jeyakumar D., Burkanudeen A. An eco-friendly synthesis of a terpolymer resin: characterization and chelation ion-exchange property. Iran. Polym. J. 2009, 18:821-832.
11. Ahamed M.R., Azarudeen R., Karunakaran M., Karikalan T., Manikandan R., Burkanudeen A. Cation exchange properties of a terpolymer: synthesis and characterization. Int. J. Chem. Environ. Eng. 2010, 1:7-12.
12. Ahamed M.A.R., Azarudeen R., Karunakaran M., Burkanudeen A. Synthesis, characterization, metal ion binding capacities and applications of a terpolymer resin of anthranilic acid/salicylic acid/formaldehyde. Iran. Polym. J. 2010, 19:635-646.
13. Jadhao M.M., Kumar S., Paliwal L.J., Bhave N.S., Alam S. Resin-V: synthesis and physicochemical studies of a biphenol-guanidine-formaldehyde terpolymer resin. J. Appl. Polym. Sci. 2010, 118:1969-1978.
14. Azarudeen R.S., Ahamed M.A.R., Burkanudeen A.R. Chelating terpolymer resin: synthesis, characterization and its ion-exchange properties. Desalination 2011, 268:90-96.
15. Rahangdale S.S., Zade A.B., Gurnule W.B. Chelation ion exchange properties of 2,4-dihydroxyacetophenone-biuret-formaldehyde terpolymer resin. E-J. Chem. 2009, 6:835-843.
16. Shah P.M., Shah A.V., Shah B.A. Metal ions uptake by chelating resin derived from o-substituted benzoic acid and its synthesis, characterization and properties. Macromol. Symp. 2008, 274:81-90.
17. Shah B.A., Shah A.V., Patel N.B. A benign approach of microwave assisted synthesis of copolymeric resin with improved thermal, spectral and ion-exchange properties, Iran. Polym. J. 2008, 17:3-17.
18. Michael P.E.P., Lingala P.S., Juneja H.D., Paliwal L.J. Synthetic, structural, and thermal degradation of a tercopolymer derived from salicylic acid, guanidine, and formaldehyde. J. Appl. Polym. Sci. 2004, 92:2278-2283.
19. Singru R.N., Gurnule W.B. Thermogravimetric study of 8-hydroxyquinoline 5-sulfonic acidmelamine-formaldehyde terpolymer resins-II. J. Therm. Anal. Calorim. 2010, 100:1027-1036.
20. Parveen S., Ahamad T., Nishat N. New anti-bacterial polychelates: synthesis, characterization, and anti-bacterial activities of thiosemicarbazide-formaldehyde resin and its polymer-metal complexes. Appl. Organomet. Chem. 2008, 22:70-77.
21. Shah B.A., Shah A.V., Bhatt R.R. Studies of chelation ion-exchange properties of copolymer resin derived from salicylic acid and its analytical applications. Iran. Polym. J. 2007, 16:173-184.
22. Mahler J., Rafler G. Modified melamine resins for optical applications. Opt. Mater. 1999, 12:363-368.
23. Mane V.D., Wahane N.J., Gurnule W.B. Copolymer resin. VII. 8-Hydroxyquinoline-5-sulfonic acid-thiourea-formaldehyde copolymer resins and their ion-exchange properties. J. Appl. Polym. Sci. 2009, 111:3039-3049.
24. Parekh H.M., Panchal P.K., Patel M.N. Transition metal(II) ions with dinegative tetradentate Schiff base. J. Therm. Anal. Calorim. 2006, 86:803-807.
25. Azarudeen R.S., Ahamed M.A.R., Burkanudeen A.R. Kinetics of thermal decomposition and antimicrobial screening of terpolymer resins. Polym. Bull. 2011, 67:1553-1568.
26. Silverstein R.M., Bassler G.C. Spectrometric Identification of Organic Compounds 1967, John Wiley, New York. 2nd ed.
27. Peter A. Miray, A Practical Guide to Understanding the NMR of Polymer 2004, John Wiley and Sons, New York.
28. Ahamed M.A.R., Azarudeen R.S., Jeyakumar D., Burkanudeen A.R. Terpolymer chelates: synthesis, characterization, and biological applications. Int. J. Polym. Mater. 2011, 60:124-143.
29. Dutta S., Das A.K. Synthesis, characterization, and application of a new chelating resin functionalized with dithiooxamide. J. Appl. Polym. Sci. 2007, 103:2281-2285.
30. Singru R.N., Gurnule W.B. Chelation ion-exchange study of copolymer resin derived from 8-hydroxyquinoline 5-sulphonic acid, oxamide, and formaldehyde. J. Appl. Polym. Sci. 2010, 116:3356-3366.
31. Jadhao M.M., Paliwal L.J., Bhave N.S. Resin. III. Synthesis, characterization, and ion-exchange properties of a 2,2'-dihydroxybiphenyl-formaldehyde copolymer resin. J. Appl. Polym. Sci. 2008, 10:508-514.
32. Rath D.K., Lenka S., Nayak P.L. Synthetic resins. XVIII. Chelation ion exchange properties of 2,4-dinitrophenylhydrazone of 4-hydroxy acetophenone-formaldehyde resins. J. Appl. Polym. Sci. 1992, 46:2109-2114.
33. Bastia T.K., Lenka S., Nayak P.L. Biomedical polymers. IV. Bacteriocidal property of the resins derived from semicarbazone and 2,4-dinitrophenyl hydrazone of some hydroxy acetophenones. J. Appl. Polym. Sci. 1992, 46:1875-1877.