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Volumn 4, Issue 4, 2013, Pages 1095-1106

Macromolecular engineering via ring-opening polymerization (1): L-lactide/trimethylene carbonate block copolymers as thermoplastic elastomers

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM; BLOCK COPOLYMERS; MECHANICAL PROPERTIES; ORGANIC POLYMERS; ZINC;

EID: 84872716249     PISSN: 17599954     EISSN: 17599962     Source Type: Journal    
DOI: 10.1039/c2py20859h     Document Type: Article
Times cited : (64)

References (60)
  • 28
    • 84863091802 scopus 로고    scopus 로고
    • Whereas most of the earlier studies involved tin complexes, growing awareness of the possible toxicity of potential tin residues (even more relevant for polymeric materials to be in contact with the body or with food) has driven attention towards the use of more bio-friendly metal catalysts such as zinc, calcium, group 3 metals or bismuth. Besides, use of these latter type of metal catalysts rather than tin(ii) octoate avoids its significant drawbacks such as the poor control of the polymerization, the rather ill-defined mechanism and possible decarboxylation
    • S. M. Guillaume J.-F. Carpentier Catal. Sci. Technol. 2012 2 898 906
    • (2012) Catal. Sci. Technol. , vol.2 , pp. 898-906
    • Guillaume, S.M.1    Carpentier, J.-F.2
  • 42
    • 26944487628 scopus 로고    scopus 로고
    • To our knowledge, only Spassky and coworkers have reported the successful preparation of diblock PLLA-b-PTMC upon polymerizing l-LA prior to TMC, whereas the reverse order of monomer addition failed to give the desired copolymer (only a mixture of both homopolymers was obtained); see ref. 11a
    • H. R. Kricheldorf S. Rost Macromolecules 2005 38 8220 8226
    • (2005) Macromolecules , vol.38 , pp. 8220-8226
    • Kricheldorf, H.R.1    Rost, S.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.