Nanostructures of cellulose acetate phthalate obtained by electrospinning from 2-methoxyethanol-containing solvent systems: Morphological aspects, thermal behavior, and antimicrobial activity

Industrial and Engineering Chemistry Research

Volumn 52, Issue 2, 2013, Pages 696-705

  Olaru, Niculae ^a   Olaru, Liliana ^a   Tudorachi, Nita ^a   Dunca, Simona ^b   Pintilie, Manuela ^a  

^a PETRU PONI INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Romania)

^b ALEXANDRU IOAN CUZA UNIVERSITY OF IASI   (Romania)

Author keywords

[No Author keywords available]

Indexed keywords

2-METHOXYETHANOL; ANTI-MICROBIAL ACTIVITY; ANTIVIRAL PROPERTIES; CELLULOSE ACETATE PHTHALATE; DEGRADATION PRODUCTS; ENTERIC-COATING; FOURIER TRANSFORM INFRARED; GAS PRODUCT; HIGH POROSITY; HIGH SPECIFIC SURFACE AREA; INITIAL STAGES; MORPHOLOGICAL ASPECTS; NANO-STRUCTURED; NANOPRODUCTS; PHARMACEUTICAL EXCIPIENT; PHTHALIC ANHYDRIDES; RESIDUAL POLYMERS; SOLVENT MIXTURES; SOLVENT SYSTEM; STAPHYLOCOCCUS AUREUS; TECHNOLOGICAL APPLICATIONS; THERMAL BEHAVIORS; THERMOGRAVIMETRIC; TRANSMISSION ELECTRON MICROSCOPY TEM; WEIGHT LOSS;

BACTERIA; CELLULOSE; DEGRADATION; ESCHERICHIA COLI; ESTERS; MASS SPECTROMETRY; POWDERS; SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; VOLATILE FATTY ACIDS;

NANOSTRUCTURES;

EID: 84872698577     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie301299d     Document Type: Article

References (31)

1. Fang, J.; Niu, H. T.; Lin, T.; Wang, X. G. Applications of electrospun nanofibers Chin. Sci. Bull. 2008, 53, 2265
2. Subbiah, T.; Bhat, G. S.; Tock, R. W.; Parameswaran, S.; Ramkumar, S. S. Electrospinning of nanofibers J. Appl. Polym. Sci. 2005, 96, 557
3. Liu, H.; Hsieh, Y.-L. Ultrafine fibrous cellulose membranes from electrospinning of cellulose acetate J. Polym. Sci., Part B: Polym. Phys. 2002, 40, 2119
4. Liu, H.; Tang, C. Electrospinning of Cellulose Acetate in Solvent Mixture N,N-Dimethylacetamide (DMAc)/Acetone Polym. J. 2007, 39, 65
5. Han, D.; Gouma, P. I. Electrospun bioscaffolds that mimic the topology of extracellular matrix Nanomed.: NBM 2006, 2, 37
6. Chen, L.; Bromberg, L.; Alan Hatton, T.; Rutledge, G. C. Electrospun cellulose acetate fibers containing chlorhexidine as a bactericide Polymer 2008, 49, 1266
7. Son, W. K.; Youk, J. H.; Lee, T. S.; Park, W. H. Electrospinning of ultrafine cellulose acetate fibers: Studies of a new solvent system and acetylation of ultrafine cellulose acetate fibers J. Polym. Sci., Part B: Polym. Phys. 2004, 42, 5
8. Zuwei, M.; Kotaki, M.; Ramakrishna, S. Electrospun cellulose nanofiber as affinity membrane J. Membr. Sci. 2005, 265, 115
9. Wu, X.; Wang, L.; Yu, H.; Huang, Y. Effect of solvent on morphology of electrospinning ethyl cellulose fibers J. Appl. Polym. Sci. 2005, 97, 1292
10. Park, J. Y.; Han, S. W.; Lee, I. H. Preparation of Electrospun Porous Ethyl Cellulose Fiber by THF/DMAc Binary Solvent System J. Ind. Eng. Chem. 2007, 13, 1002
11. Jeun, J.-P.; Lim, Y.-M.; Choi, J.-H.; La, H.-S.; Kang, P.-H.; Nho, Y.-C. Preparation of Ethyl-Cellulose Nanofibers via An Electrospinning Solid State Phenom. 2007, 119, 255
12. Frenot, A.; Walenius Henriksson, M.; Walkenstrom, P. Electro-spinning of cellulose-based nanofibers J. Appl. Polym. Sci. 2007, 103, 1473
13. Sui, X.; Yuan, J.; Yuan, W.; Zhou, M. Preparation of Cellulose Nanofibers/Nanoparticles via Electrospray Chem. Lett. 2008, 37, 114
14. Kim, C.-W.; Frey, M. W.; Marquez, M.; Joo, Y. L. Preparation of submicron-scale, electrospun cellulose fibers via direct dissolution J. Polym. Sci., Part B: Polym. Phys. 2005, 43, 1673
15. Kulpinski, P. Cellulose nanofibers prepared by the N-methylmorpholine-N- oxide method J. Appl. Polym. Sci. 2005, 98, 1855
16. Gyotoku, T.; Aurelian, L.; Neurath, A. R. Cellulose acetate phthalate (CAP): an 'inactive' pharmaceutical excipient with antiviral activity in the mouse model of genital herpesvirus infection Antiviral. Chem. Chemother. 1999, 10, 327
17. Neurath, A. R.; Strick, N.; Li, Y. Y.; Debnath, A. K. Cellulose acetate phthalate, a common pharmaceutical excipient, inactivates HIV-1 and blocks the coreceptor binding site on the virus envelope glycoprotein gp 120 BMC Infect. Dis. 2001, 1, 17; http://www.biomedcentral.com/1471-2334/1/17
18. Duncan, R. The dawning era of polymer therapeutics Nat. Rev. Drug Discovery 2003, 2, 347
19. Neurath, A. R.; Strick, N.; Li, Y. Y. Water dispersible microbicidal cellulose acetate phthalate film BMC Infect. Dis. 2003, 3, 27; http://www.biomedcentral.com/1471-2334/3/27
20. Neurath, A. R.; Strick, N.; Jiang, S.; Li, Y. Y.; Debnath, A. K. Anti-HIV-1 activity of cellulose acetate phthalate: Synergy with soluble CD4 and induction of "dead-end" gp41 six-helix bundles BMC Infect. Dis. 2002, 2, 6; http://www.biomedcentral.com/1471-2334/2/6
21. Manson, K. H.; Wyand, M. S.; Miller, C.; Neurath, A. R. Effect of a Cellulose Acetate Phthalate Topical Cream on Vaginal Transmission of Simian Immunodeficiency Virus in Rhesus Monkeys Antimicrob. Agents Chemother. 2000, 44, 3199
22. Neurath, A. R.; Strick, N.; Li, Y. Y. Anti-HIV-1 activity of anionic polymers: a comparative study of candidate microbicides BMC Infect. Dis. 2002, 2, 27
23. Olaru, N.; Olaru, L. Electrospinning of cellulose acetate phthalate from different solvent systems Ind. Eng. Chem. Res. 2010, 49, 1953
24. Huang, C.; Soenen, S. J.; Van Gulck, E.; Vanham, G.; Rejman, J.; Van Calenbergh, S.; Vervaet, C.; Coenye, T.; Verstraelen, H.; Temmerman, M.; Demeester, J.; De Smedt, S. C. Electrospun cellulose acetate phthalate fibers for semen induced anti-HIV vaginal drug delivery Biomaterials 2012, 33, 962
25. Roxin, P.; Karlsson, A.; Singh, S. K. Characterization of Cellulose Acetate Phthalate (CAP) Drug Dev. Ind. Pharm. 1998, 24, 1025
26. Olaru, N.; Olaru, L.; Leanca, M. On Thermal Degradation of Cellulose Acetate Phthalate Cellul. Chem. Technol. 1995, 29, 253
27. Olaru, N.; Olaru, L.; Andriescu, A.; Tudorachi, N. Partial Hydrolysis of cellulose acetate in toluene/acetic acid/water system Angew. Makromol. Chem. 1996, 241, 67
28. Malm, C. J.; Genung, L. B.; Kuchmy, W. Analysis of Phthalic Acid Esters of Cellulose and of Polyvinyl Alcohol Anal. Chem. 1953, 25, 245
29. Tanghe, L. J.; Genung, L. B.; Mench, J. W.; Determination of Acetyl Content and Degree of Substitution of Cellulose Acetate. In Methods in Carbohydrate Chemistry; Whistler, R. L., Ed.; Academic Press: New York, London, 1963; Vol. 3, 201-203.
30. Wistreich, G. A. Microbiology Laboratory; Prentice Hall: Upper Saddle River, NJ, 2000.
31. Necula, A. M.; Dunca, S.; Stoica, I.; Olaru, N.; Olaru, L.; Ioan, S. Morphological properties and antibacterial activity of nano-silver containing cellulose acetate phthalate films Int. J. Polym. Anal. Charact. 2010, 15, 341