Silicate glass alteration enhanced by iron: Origin and long-term implications

Environmental Science and Technology

Volumn 47, Issue 2, 2013, Pages 750-756

  Michelin, A ^a,b   Burger, E ^a   Rebiscoul, D ^a   Neff, D ^b   Bruguier, F ^a   Drouet, E ^b   Dillmann, P ^b   Gin, S ^a  

^a DIF   (France)

^b CEA Saclay   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CLAYSTONES; DEEP GEOLOGICAL DISPOSAL; DISSOLUTION MECHANISM; GEL LAYERS; GEOSPHERES; GLASS ALTERATION; IMMEDIATE ENVIRONMENT; MULTISCALES; NUCLEAR SYSTEMS; OVERPACK; RADIONUCLIDE RELEASE; SILICATE GLASS;

IRON; RADIOACTIVE WASTES; SILICATES; SPENT FUELS;

GLASS;

FERRIC CARBONATE; FERRIC OXIDE; GLASS; GROUND WATER; IRON; MAGNETITE; METAL OXIDE; SILICATE; UNCLASSIFIED DRUG;

ARCHAEOLOGY; COMPARATIVE STUDY; DISSOLUTION; GLASS; IRON; LONG-TERM CHANGE; RADIOACTIVE WASTE; RADIONUCLIDE; SILICATE; WASTE DISPOSAL;

ARTICLE; CHEMICAL COMPOSITION; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; DIFFUSION COEFFICIENT; LEACHING; NUCLEAR WASTE; OXIDATION REDUCTION STATE; POROSITY; PRECIPITATION; RADIOACTIVE WASTE DISPOSAL; SYNCHROTRON RADIATION; THERMODYNAMICS;

GLASS; IRON; POROSITY; RADIOACTIVE WASTE; SILICATES; SOLUBILITY;

EID: 84872556181     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es304057y     Document Type: Article

References (36)

1. Miller, A. W.; Wang, Y. F. Radionuclide Interaction with Clays in Dilute and Heavily Compacted Systems: A Critical Review Environ. Sci. Technol. 2012, 46 (4) 1981-1994
2. Poinssot, C.; Gin, S. Long-term Behavior Science: The cornerstone approach for reliably assessing the long-term performance of nuclear waste J. Nucl. Mater. 2012, 420, 182-192
3. Ewing, R. C. Natural glasses: analogues for radioactive waste forms. In Scientific Basis for Nuclear Waste Management; McCarthy, G. J., Ed.; Plenum Press: New York, 1979; Vol. 1, pp 57-68.
4. Doremus, R. H. Interdiffusion of hydrogen and alkali ions in a glass surface J. Non-Cryst. Solids 1975, 19, 137-144
5. Hench, L. L.; Clark, D. E. Physical chemistry of glass surfaces J. Non-Cryst. Solids 1978, 28, 83-105
6. Bunker, B. C.; Tallant, D. R.; Headley, T. J.; Turner, G. L.; Kirkpatrick, R. J. The structure of leached sodium borosilicate glass Phys. Chem. Glasses 1988, 29, 106-120
7. Crovisier, J.-L.; Advocat, T.; Dussossoy, J.-L. Nature and role of natural alteration gels formed on the surface of ancient volcanic glasses (Natural analogs of waste containment glasses) J. Nucl. Mater. 2003, 321, 91-109
8. ANDRA. Dossier 2005 Argile: Phenomenological Evolution of a Geological Repository; Agence nationale pour la gestion des déchets radioactifs: Chatenay-Malabry, France, 2005.
9. H12: Project to Establish the Scientific and Technical Basis for HLW Disposal in Japan; JNC TN1410 2000; Japan Nuclear Cycle Development Institute: Tokyo, Japan, 2000.
10. McVay, G. L.; Buckwalter, C. Q. Effect of Iron on Waste-Glass Leaching J. Am. Ceram. Soc. 1983, 66, 170-174
11. De Combarieu, G.; Schlegel, M.; Neff, D.; Foy, E.; Vantelon, D.; Barboux, P.; Gin, S. Glass-iron-clay interactions in a radioactive waste geological disposal: An integrated laboratory scale experiment Appl. Geochem. 2011, 26, 65-79
12. Jollivet, P.; Minet, Y.; Nicolas, M.; Vernaz, E. Simulated alteration tests on non-radioactive SON68 nuclear glass in the presence of corrosion products and environmental materials J. Nucl. Mater. 2000, 281 (2-3) 231-243
13. Mitsui, S.; Aoki, R. Effect of a siliceous additive on aqueous alteration of waste glass with engineered barrier materials J. Nucl. Mater. 2001, 298, 184-191
14. Tournassat, C.; Blanc, P.; Gaucher, E. Estimation de la composition de l'eau porale du Callovo-oxfordien à 50, 70, 80 et 90 C; BRGM report/RP-56171-FR; Bureau de Recherches Géologiques et Minières: Orléans, France, 2008.
15. Libourel, G.; Verney-Carron, A.; AndreasMorlok, S.; Gin, J.; Sterpenich, A.; Michelin, D.; Neff, P. D. The use of natural and archeological analogues for understanding the long-term behavior of nuclear glasses C. R. Géosci. 2011, 343, 237-245
16. Arribet-Deroin, D. Fondre le fer en gueuses au XVIe siècle. Le haut fourneau de Glinet en pays de Bray (Normandie). Ph.D. Thesis. Université de Paris I, Panthéon-Sorbonne, Paris, 2001.
17. Saheb, M., M.; Descostes, M.; Neff, D.; Matthiesen, H.; Michelin, A.; Dillmann, P. Iron corrosion in an anoxic soil: Comparison between thermodynamic modelling and ferrous archaeological artefacts characterised along with the local in situ geochemical conditions Appl. Geochem. 2010, 25, 1937-1948
18. Benzerara, K.; Menguy, N.; Banerjee, N. R.; Tyliszczak, T.; Brown, G. E., Jr.; Guyot, F. Alteration of submarine basaltic glass from the Ontong Java Plateau: A STXM and TEM study Earth Planet. Sci. Lett. 2007, 260, 187-200
19. 2,3 threshold in iron oxides Phys. Rev. B 1995, 52, 3143-3150
20. Stöhr, J. NEXAFS Spectroscopy; Springer: Berlin, 1992.
21. Pourbaix, M. Atlas d'équilibres électrochimiques; Gauthiers-Villars & Cie.: Paris, 1963.
22. Ledieu, A.; Devreux, F.; Barboux, P.; Sicard, L.; Spalla, O. Leaching of borosilicate glasses. I. Experiments J. Non-Cryst. Solids. 2004, 343, 3-12
23. Hamilton, J. P.; Brantley, S. L.; Pantano, C. G.; Criscenti, L. J.; Kubicki, J. D. Dissolution of nepheline, jadeite and albite glasses: Toward better models for aluminosilicate dissolution Geochim. Cosmochim. Acta 2001, 65, 3683-3702
24. Cailleteau, C.; Angeli, F.; Devreux, F.; Gin, S.; Jestin, J.; Jollivet, P.; Spalla, O. Insight into silicate-glass corrosion mechanisms Nat. Mater. 2008, 7, 978-983
25. Gin, S.; Ribet, I.; Couillard, M. Role and properties of the gel formed during nuclear glass alteration: importance of gel formation conditions J. Nucl. Mater. 2001, 298, 1-10
26. Ribet, S.; Gin, S. Role of neoformed phases on the mechanisms controlling the resumption of SON68 glass alteration in alkaline media J. Nucl. Mater. 2004, 324, 152-164
27. Curti, E.; Crovisier, J. L.; Karpoff, A. M.; Morvan, G. Long-term corrosion of two nuclear waste reference glasses (MW and SON68): A kinetic and mineral alteration study Appl. Geochem. 2006, 21, 1152-1168
28. Jollivet, P.; Frugier, P.; Parisot, G.; Mestre, J. P.; Brackx, E.; Gin, S.; Schumacher, S. Effect of clayey groundwater on the dissolution rate of the simulated nuclear waste glass SON68 J. Nucl. Mater. 2012, 420, 508-518
29. Thien Bruno, M. J.; Godon, N.; Ballestero, A.; Gin, S.; Ayral, A. The dual effect of Mg on the long-term alteration rate of AVM nuclear waste glasses J. Nucl. Mater. 2012, 427, 297-310
30. Gin, S.; Guittonneau, C.; Godon, N.; Neff, D.; Rebiscoul, D.; Cabié, M.; Mostefaoui, S. Nuclear glass durability: New insight into alteration layer properties J. Phys. Chem. C 2011, 115, 18696-18706
31. Chave, T.; Frugier, P.; Gin, S.; Ayral, A. Glass-water interphase reactivity with calcium rich solutions Geochim. Cosmochim. Acta 2011, 75, 4125-4139
32. Pèlegrin, E.; Calas, G.; Ildefonse, P.; Jollivet, P.; Galoisy, L. Structural evolution of glass surface during alteration: Application to nuclear waste glasses J. Non-Cryst. Solids 2010, 356, 2497-2508
33. 27Al MAS NMR and aluminium X-ray absorption near edge structures study of natural imogolite and allophanes Clays Clay Miner. 1994, 42, 276-287
34. Schikorr, G. Uber Eisen (II)-hydroxyd und ein ferromagnetisches Eisen (III)-hydroxyd Z. Anorg. Allg. Chem. 1933, 212, 33-39
35. Odziemkowski, M.; Schuhmacher, T.; Gillham, R.; Reardon, E. Mechanism of oxide film formation on iron in simulating groundwater solutions: Raman spectroscopic studies Corros. Sci. 1998, 40, 371-389
36. Michelin, A. Altération pluriséculaire des systèmes verre/fer en milieu anoxique: apport des analogues archéologiques à la compréhension des mécanismes. Ph.D. Thesis. Université Pierre et Marie Curie, Paris, France, 2011.