Interplay between structure and relaxations in perfluorosulfonic acid proton conducting membranes

Journal of the American Chemical Society

Volumn 135, Issue 2, 2013, Pages 822-834

  Giffin, Guinevere A ^a   Haugen, Gregory M ^b   Hamrock, Steven J ^b   Di Noto, Vito ^a  

^a UNIVERSITY OF PADOVA   (Italy)

^b 3M COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE MIGRATION; CONDUCTION PROCESS; CRYSTALLINE DOMAINS; DEGREE OF CRYSTALLINITY; DELOCALIZATIONS; EQUIVALENT WEIGHT; HOST POLYMERS; HYDROPHOBIC AND HYDROPHILIC; HYDROPHOBIC DOMAINS; HYDROPHOBIC REGIONS; HYDROPHOBIC-HYDROPHILIC; IONOMER MEMBRANES; MEMBRANE WATER CONTENT; PERFLUOROSULFONIC ACID; PROTON CONDUCTING MEMBRANES; PROTON EXCHANGE PROCESS; PROTON MIGRATION; RATE-LIMITING STEPS; SPECTRAL CHANGE; SULFONIC ACID GROUPS; THERMALLY STABLE; WIDE-ANGLE X-RAY DIFFRACTION;

CHARGE TRANSFER; CRYSTALLINE MATERIALS; HYDROPHILICITY; HYDROPHOBICITY; POLYTETRAFLUOROETHYLENES; PROTONS; SOLVENTS; X RAY DIFFRACTION;

MEMBRANES;

PERFLUOROSULFONIC ACID; POLYMER; PROTON; SULFONIC ACID DERIVATIVE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CONDUCTANCE; CONFORMATION; DENSITY FUNCTIONAL THEORY; ELECTRICAL EQUIPMENT; INFRARED SPECTROSCOPY; MEMBRANE; PROTON EXCHANGE MEMBRANE FUEL CELL; PROTON TRANSPORT; THERMOGRAVIMETRY; X RAY DIFFRACTION;

EID: 84872505336     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3099799     Document Type: Article

References (48)

1. O'Hayre, R.; Cha, S. W.; Prinz, F. B. Fuel Cell Fundamentals; Wiley: Hoboken, NJ, 2006.
2. Laberty-Robert, C.; Valle, K.; Pereira, F.; Sanchez, C. Chem. Soc. Rev. 2011, 40, 961
3. Doyle, M.; Rajendran, G. In Handbook of Fuel Cells: Fundamentals Technology and Applications; Vielstich, W.; Lamm, A.; Gasteiger, H. A., Eds.; John Wiley & Sons: Chichester, 2003; Vol. 3, p 351.
4. Grot, W. Fluorinated ionomers; William Andrew: Norwich, NY, 2008.
5. Satyapal, S. In 5th International Conference on Polymer Batteries & Fuel Cells; US Department of Energy: Energy Efficiency & Renewable Energy: Argonne, IL, 2011.
6. Epping, M. K.; Kopasz, J. P. Fuel Cells 2009, 9, 356
7. Mauritz, K. A.; Moore, R. B. Chem. Rev. 2004, 104, 4535
8. Gierke, T. D.; Munn, G. E.; Wilson, F. C. J. Polym. Sci.: Polym. Phys. Ed. 1981, 19, 1687
9. Rubatat, L.; Rollet, A. L.; Gebel, G.; Diat, O. Macromolecules 2002, 35, 4050
10. Schmidt-Rohr, K.; Chen, Q. Nat. Mater. 2008, 7, 75
11. Di Noto, V.; Piga, M.; Giffin, G. A.; VezzuÌ, K.; Zawodzinski, T. A. J. Am. Chem. Soc. 2012, 134, 19099
12. Hamrock, S. J.; Yandrasits, M. A. Polym. Rev. 2006, 46, 219
13. Aieta, N. V.; Stanis, R. J.; Horan, J. L.; Yandrasits, M. A.; Cookson, D. J.; Ingham, B.; Toney, M. F.; Hamrock, S. J.; Herring, A. M. Macromolecules 2009, 42, 5774
14. Liu, Y.; Horan, J. L.; Schlichting, G. J.; Caire, B. R.; Hamrock, S. J.; Haugen, G. M.; Yandrasits, M. A.; Seifert, S.; Herring, A. M. Macromolecules 2012, 45, 7495
15. Delley, B. J. Chem. Phys. 1990, 92, 508
16. Delley, B. J. Chem. Phys. 2000, 113, 7756
17. Fujimura, M.; Hashimoto, T.; Kawai, H. Macromolecules 1981, 14, 1309
18. Gierke, T. D.; Munn, G. E.; Wilson, F. C. J. Polym. Sci., Polym. Phys. Ed. 1981, 19, 1687
19. Norgaard, C. F.; Nielsen, U. G.; Skou, E. M. Solid State Ionics 2012, 213, 76
20. Rollet, A.-L.; Diat, O.; Gebel, G. J. Phys. Chem. B 2002, 106, 3033
21. Masetti, G.; Cabassi, F.; Morelli, G.; Zerbi, G. Macromolecules 1973, 6, 700
22. Painter, P. C.; Coleman, M. M.; Koenig, J. L. The Theory of Vibrational Spectroscopy and its Application to Polymeric Materials; Wiley: New York, 1982.
23. Vainshtein, B. K. Diffraction of X-rays by Chain Molecules; Elsevier: Amsterdam, 1963.
24. Kreuer, K. D.; Schuster, M.; Obliers, B.; Diat, O.; Traub, U.; Fuchs, A.; Klock, U.; Paddison, S. J.; Maier, J. J. Power Sources 2008, 178, 499
25. Klug, H. P.; Alexander, L. E. X-Ray Diffraction Procedures For Polycrystalline and Amorphous Materials, 2 nd ed.; Wiley: New York, 1974.
26. Clark, E. S. Polymer 1999, 40, 4659
27. Elliott, J. A.; Paddison, S. J. Phys. Chem. Chem. Phys. 2007, 9, 2602
28. Paddison, S. J. J. New Mater. Electrochem. Syst. 2001, 4, 197
29. Petersen, M. K.; Voth, G. A. J. Phys. Chem. B 2006, 110, 18594
30. Di Noto, V.; Piga, M.; Lavina, S.; Negro, E.; Yoshida, K.; Ito, R.; Furukawa, T. Electrochim. Acta 2010, 55, 1431
31. Di Noto, V.; Piga, M.; Negro, E.; Giffin, G. A.; Polizzi, S.; Zawodzinski, T. A. Chem. Sci. 2012, in press.
32. Danilczuk, M.; Lin, L.; Schlick, S.; Hamrock, S. J.; Schaberg, M. S. J. Power Sources 2011, 196, 8216
33. Warren, D. S.; McQuillan, A. J. J. Phys. Chem. B 2008, 112, 10535
34. Lin-Vien, D.; Colthup, N. B.; Fately, W. G.; Grasselli, J. G. The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules; Academic Press: San Diego, 1991.
35. Zerbi, G.; Sacchi, M. Macromolecules 1973, 6, 692
36. Varetti, E. L. Spectrochim. Acta, Part A 1988, 44A, 733
37. Di Noto, V.; Boaretto, N.; Negro, E.; Giffin, G. A.; Lavina, S.; Polizzi, S. Int. J. Hydrogen Energy 2012, 37, 6199
38. Wu, D.; Paddison, S. J.; Elliott, J. A.; Hamrock, S. J. Langmuir 2010, 26, 14308
39. Brandrup, J.; Immergut, E. H.; Grulke, E. A. Polymer Handbook, 4 th ed.; Wiley: New York, 1999.
40. Giffin, G. A.; Piga, M.; Lavina, S.; Navarra, M. A.; D'Epifanio, A.; Scrosati, B.; Di Noto, V. J. Power Sources 2011, 198, 66
41. Di Noto, V.; Piga, M.; Pace, G.; Negro, E.; Lavina, S. ECS Transactions 2008, 16, 1183
42. Di Noto, V.; Giffin, G. A.; VezzuÌ, K.; Piga, M.; Lavina, S. In Solid State Proton Conductors: Properties and Applications in Fuel Cells; Knauth, P.; Di Vona, M. L., Eds.; Wiley: Chichester, 2012.
43. Fulcher, G. S. J. Am. Ceram. Soc. 1925, 8, 339
44. Tammann, G.; Hesse, W. Z. Anorg. Allg. Chem. 1926, 156, 245
45. Vogel, H. Phys. Z 1921, 22, 645
46. Ratner, M. In Polymer Electrolyte Reviews 1; MacCallum, J. R.; Vincent, C. A., Eds.; Elsevier: London, 1987.
47. Clark, J. K., II; Paddison, S. J. Solid State Ionics 2012, 213, 83
48. Clark, J. K., II; Paddison, S. J; Hamrock, S. J. Phys. Chem. Chem. Phys. 2012, 14, 16349