Interplay of electron hopping and bounded diffusion during charge transport in redox polymer electrodes

Journal of Physical Chemistry B

Volumn 117, Issue 1, 2013, Pages 333-342

  Akhoury, Abhinav ^a   Bromberg, Lev ^a   Hatton, T Alan ^a  

^a Massachusetts Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CROSSLINKING; CYCLIC VOLTAMMETRY; DIFFUSION; ELECTRODES; ELECTRON TRANSPORT PROPERTIES; GELS; POLYMER FILMS; SUBSTRATES;

APPARENT DIFFUSIVITY; APPLIED VOLTAGES; CARBON SUBSTRATES; CONCENTRATION LEVELS; CROSS-LINKED POLYMERS; DIFFUSIVE TRANSFER; DOMINANT MECHANISM; ELECTRON DIFFUSION; ELECTRON HOPPING; ELECTRON TRANSPORT; LINEAR DEPENDENCE; LOW CONCENTRATIONS; PEAK CURRENTS; POLYMER CHAINS; POROUS CARBONS; RANDOM COPOLYMER; RATE-CONTROLLING STEPS; REDOX POLYMERS; REDOX PROCESS; REDOX SPECIES; SCAN RATES; SQUARE ROOTS; SUBSTRATE SURFACE; VINYLFERROCENE;

POLYMERS;

EID: 84872336716     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp302157g     Document Type: Article

References (42)

1. Tamaki, T.; Yamaguchi, T. Ind. Eng. Chem. Res. 2006, 45, 3050-3058
2. Ackermann, Y.; Guschin, D. A.; Eckhard, K.; Shleev, S.; Schuhmann, W. Electrochem. Commun. 2010, 12, 640-643
3. Bunte, C.; Prucker, O.; Konig, T.; Ruhe, J. Langmuir 2010, 26, 6019-6027
4. Song, H. K.; Palmore, G. T. R. Adv. Mater. 2006, 18, 1764-1768
5. Feng, Z. F.; Zhou, J. Z.; Xi, Y. Y.; Lan, B. B.; Guo, H. H.; Chen, H. X.; Zhang, Q. B.; Lin, Z. H. J. Power Sources 2009, 194, 1142-1149
6. Tam, T. K.; Ornatska, M.; Pita, M.; Minko, S.; Katz, E. J. Phys. Chem. C 2008, 112, 8438-8445
7. Liu, X.; Neoh, K. G.; Kang, E. T. Macromolecules 2003, 36, 8361-8367
8. Mecheri, B.; Piras, L.; Ciotti, L.; Caminati, G. IEEE Sens. J. 2004, 4, 171-179
9. Tsiafoulis, C. G.; Florou, A. B.; Trikalitis, P. N.; Bakas, T.; Prodromidis, M. I. Electrochem. Commun. 2005, 7, 781-788
10. Heller, A. Redox hydrogel-based electrochemical biosensors. In Biosensors; Cooper, J. M.; Cass, A. E. G., Eds.; Oxford University Press: New York, 2004; pp 1-18.
11. Bu, H.-z.; Mikkelsen, S. R.; English, A. M. Anal. Chem. 1995, 67, 4071-4076
12. Gao, Q. A.; Guo, Y. Y.; Zhang, W. Y.; Qi, H. L.; Zhang, C. X. Sens. Actuators, B 2011, 153, 219-225
13. Guschin, D. A.; Castillo, J.; Dimcheva, N.; Schuhmann, W. Anal. Bioanal. Chem. 2010, 398, 1661-1673
14. Muresan, L.; Gaspar, S.; Turdean, G.; Popescu, I. C. Rev. Chim. (Bucharest, Rom.) 2010, 61, 126-129
15. Ikeda, S.; Oyama, N. Anal. Chem. 1993, 65, 1910-1915
16. Chen, C. J.; Liu, C. C.; Savinell, R. F. J. Electroanal. Chem. 1993, 348, 317-338
17. Nguyen, A. L.; Luong, J. H. T. Appl. Biochem. Biotechnol. 1993, 43, 117-132
18. Willner, I.; Katz, E. Angew. Chem., Int. Ed. 2000, 39, 1180-1218
19. Calvo, E. J.; Danilowicz, C.; Diaz, L. J. Chem. Soc., Faraday Trans. 1993, 89, 377-384
20. Calvo, E. J.; Danilowicz, C.; Diaz, L. J. Electroanal. Chem. 1994, 369, 279-282
21. Bu, H.-z.; English, A. M.; Mikkelsen, S. R. Anal. Chem. 1996, 68, 3951-3957
22. Akhoury, A.; Bromberg, L.; Hatton, T. A. ACS Appl. Mater. Interfaces 2011, 3, 1167-1174
23. Dahms, H. J. Phys. Chem. 1968, 72, 362-364
24. Ruff, I.; Friedrich, V. J. J. Phys. Chem. 1971, 75, 3297-3302
25. Laviron, E. J. Electroanal. Chem. 1980, 112, 1-9
26. Andrieux, C. P.; Saveant, J. M. J. Electroanal. Chem. 1980, 111, 377-381
27. Blauch, D. N.; Saveant, J.-M. J. Am. Chem. Soc. 1992, 114, 3323-3332
28. Bu, H.-z.; English, A. M.; Mikkelsen, S. R. J. Phys. Chem. B 1997, 101, 9593-9599
29. Fujiki, K.; Tsubokawa, N.; Sone, Y. Polym. J. 1990, 22, 661-670
30. Tsubokawa, N.; Abe, N.; Seida, Y.; Fujiki, K. Chem. Lett. 2000, 900-901
31. Tsubokawa, N.; Abe, N.; Wei, G.; Chen, J.; Saitoh, S.; Fujiki, K. J. Polym. Sci., Part A: Polym. Chem. 2002, 40, 1868-1875
32. Akhoury, A. Redox-Responsive Polymers for the Reversible Extraction of Butanol from Water. Ph.D. Thesis, Massachusetts Institute of Technology, June 2011.
33. O'Shaughnessy, W. S.; Mari-Buye, N.; Borros, S.; Gleason, K. K. Macromol. Rapid Commun. 2007, 28, 1877-1882
34. Baldwin, M. G.; Johnson, K. E. J. Polym. Sci., Part A: Polym. Chem. 1967, 5, 2091-2098
35. Sasaki, Y.; Walker, L. L.; Hurst, E. L.; Pittman, C. U., Jr. J. Polym. Sci. 1973, 11, 1213-1224
36. Kuramoto, N.; Shishido, Y.; Nagai, K. J. Polym. Sci., Part A: Polym. Chem. 1997, 35, 1967-1972
37. Datwani, S. S.; Truskett, V. N.; Rosslee, C. A.; Abbott, N. L.; Stebe, K. J. Langmuir 2003, 19, 8292-8301
38. Nagel, B.; Warsinke, A.; Katterle, M. Langmuir 2007, 23, 6807-6811
39. Nowak, R. J.; Schultz, F. A.; Umana, M.; Lam, R.; Murray, R. W. Anal. Chem. 1980, 52, 315-321
40. Oyama, N.; Tatsuma, T.; Takahashi, K. J. Chem. Phys. 1993, 97, 10504-10508
41. Zu, X.; Rusling, J. F. Langmuir 1997, 13, 3693-3699
42. Bard, A. J.; Faulkner, L. R. Electrochemical Methods. Fundamentals and Applications; John Wiley & Sons, Inc.: New York, 2001.