Investigation and enhancement of the stability and performance of water reduction systems based on cyclometalated iridium(III) complexes

ChemSusChem

Volumn 6, Issue 1, 2013, Pages 92-101

  Hansen, Sven ^a   Pohl, Marga Martina ^a   Klahn, Marcus ^a   Spannenberg, Anke ^a   Beweries, Torsten ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

cobalt; density functional calculations; hydrogen; iridium; palladium

Indexed keywords

ACTIVE SYSTEMS; ALKYL SUBSTITUTION; BIPYRIDINES; CO COMPLEXES; CYCLOMETALATING LIGAND; DFT CALCULATION; DICHLORO COMPLEXES; DINUCLEAR; INITIAL ACTIVITY; IRIDIUM COMPLEX; N LIGANDS; PD COMPLEX; PHOTO-CATALYTIC; PRODUCTION PERFORMANCE; PRODUCTION RATES; PRODUCTION YIELD; REDUCTION CATALYST; SACRIFICIAL ELECTRON DONORS; TRIETHYLAMINES; WATER REDUCTION;

COBALT; COBALT COMPOUNDS; DENSITY FUNCTIONAL THEORY; HYDROGEN; IRIDIUM; IRIDIUM COMPOUNDS; LIGANDS; PALLADIUM;

PALLADIUM COMPOUNDS;

COBALT; ETHYLAMINE; HYDROGEN; IRIDIUM; ORGANOMETALLIC COMPOUND; PALLADIUM; PYRIDINE DERIVATIVE; TRIETHYLAMINE; WATER;

ARTICLE; CHEMISTRY; OXIDATION REDUCTION REACTION; PHOTOCHEMISTRY;

COBALT; ETHYLAMINES; HYDROGEN; IRIDIUM; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PALLADIUM; PHOTOCHEMICAL PROCESSES; PYRIDINES; WATER;

MLCS; MLOWN;

EID: 84872314775     PISSN: 18645631     EISSN: 1864564X     Source Type: Journal    
DOI: 10.1002/cssc.201200617     Document Type: Article

References (47)

1. J. D. Holladay, J. Hu, D. L. King, Y. Wang, Catal. Today 2009, 139, 244-260.
2. A. J. Esswein, D. G. Nocera, Chem. Rev. 2007, 107, 4022-4047.
3. A. Fujishima, K. Honda, Nature 1972, 238, 37-38.
4. F. E. Osterloh, Chem. Mater. 2008, 20, 35-54.
5. J. M. Lehn, J. P. Sauvage, Nouv. J. Chim. 1977, 1, 449-451.
6. K. Sakai, Y. Kizaki, T. Tsubomura, K. Matsumoto, J. Mol. Catal. 1993, 79, 141-152.
7. J. R. Fisher, D. J. Cole-Hamilton, J. Chem. Soc. Dalton Trans. 1984, 809-813.
8. S. Rau, B. Schäfer, D. Gleich, E. Anders, M. Rudolph, M. Friedrich, H. Görls, W. Henry, J. G. Vos, Angew. Chem. 2006, 118, 6361-6364
9. Angew. Chem. Int. Ed. 2006, 45, 6215-6218.
10. P. Lei, M. Hedlund, M. Lomoth, H. Rensmo, O. Johansson, L. Hammarström, J. Am. Chem. Soc. 2008, 130, 26-27.
11. S. Hansen, M. Klahn, T. Beweries, U. Rosenthal, ChemSusChem 2012, 5, 656-660.
12. P. N. Curtin, L. L. Tinker, C. M. Burgess, E. D. Cline, S. Bernhard, Inorg. Chem. 2009, 48, 10498-10506.
13. Y.-J. Yuan, J.-Y. Zhang, Z.-T. Yu, J.-Y. Feng, W.-J. Luo, J.-H. Ye, Z.-G. Zou, Inorg. Chem. 2012, 51, 4123-4133.
14. T. Lazarides, T. M. McCormick, P. Du, G. Luo, B. Lindley, R. Eisenberg, J. Am. Chem. Soc. 2009, 131, 9192-9194
15. M. Wang, L. Chen, X. Li, L. Sun, Dalton Trans. 2011, 40, 12793-12800
16. J. Dong, M. Wang, P. Zhang, S. Yang, J. Liu, X. Li, L. Sun, J. Phys. Chem. C 2011, 115, 15089-15096.
17. W. T. Eckenhoff, R. Eisenberg, Dalton Trans. 2012, 41, 13004-13021.
18. V. Artero, M. Chavarot-Kerlidou, M. Fontecave, Angew. Chem. 2011, 123, 7376-7405
19. Angew. Chem. Int. Ed. 2011, 50, 7238-7266.
20. J. L. Dempsey, B. S. Brunschwig, J. R. Winkler, H. B. Gray, Acc. Chem. Res. 2009, 42, 1995-2004.
21. Z. Han, W. R. McNamara, M.-S. Eum, P. L. Holland, R. Eisenberg, Angew. Chem. 2012, 124, 1699-1702
22. Angew. Chem. Int. Ed. 2012, 51, 1667-1670.
23. F. Gärtner, A. Boddien, E. Barsch, K. Fumino, S. Losse, H. Junge, D. Hollmann, A. Brückner, R. Ludwig, M. Beller, Chem. Eur. J. 2011, 17, 6425-6436.
24. -). cf., A. Salzer, Pure Appl. Chem. 1999, 71, 1557-1585.
25. M. S. Lowry, W. R. Hudson, R. A. Pascal Jr., S. Bernhard, J. Am. Chem. Soc. 2004, 126, 14129-14135.
26. J. I. Goldsmith, W. R. Hudson, M. S. Lowry, T. H. Anderson, S. Bernhard, J. Am. Chem. Soc. 2005, 127, 7502-7510.
27. A comparison of the experimental bond lengths with the computed sum of covalent radii is a good measure for the nature of the bond. Covalent radii were taken from, P. Pyykkö, M. Atsumi, Chem. Eur. J. 2009, 15, 12770-12779.
28. P. J. Delaive, B. P. Sullivan, T. J. Meyer, D. G. Whitten, J. Am. Chem. Soc. 1979, 101, 4007-4008.
29. F. Gärtner, S. Losse, A. Boddien, M.-M. Pohl, S. Denurra, H. Junge, M. Beller, ChemSusChem 2012, 5, 530-533.
30. F. Gärtner, D. Cozzula, S. Losse, A. Boddien, G. Anilkumar, H. Junge, T. Schulz, N. Marquet, A. Spannenberg, S. Gladiali, M. Beller, Chem. Eur. J. 2011, 17, 6998-7006.
31. P. Zhang, P.-A. Jacques, M. Chavarot-Kerlidou, M. Wang, L. Sun, M. Fontecave, V. Artero, Inorg. Chem. 2012, 51, 2115-2120.
32. R. H. Crabtree, Chem. Rev. 2012, 112, 1536-1554.
33. P. Braunstein, I. Pruskil, G. Predieri, A. Tiripicchio, J. Organomet. Chem. 1983, 247, 227-237.
34. L. L. Tinker, N. D. McDaniel, P. N. Curtin, C. K. Smith, M. J. Ireland, S. Bernhard, Chem. Eur. J. 2007, 13, 8726-8732.
35. T. B. Rauchfuss, Inorg. Synth. 2010, 35, 168-173.
36. M. Noskowska, E. Sliwinska, W. Duczmal, Trans. Met. Chem. 2003, 28, 756-759.
37. S. Peitz, N. Peulecke, B. R. Aluri, S. Hansen, B. H. Müller, A. Spannenberg, U. Rosenthal, M. H. Al-Hazmi, F. M. Mosa, A. Wöhl, W. Müller, Eur. J. Inorg. Chem. 2010, 1167-1171.
38. H.-J. Drexler, A. Preetz, T. Schmidt, D. Heller, in The Handbook of Homogeneous Hydrogenation, Vol. 1 (Eds.:, J. G. De Vries, C. J. Elsevier,), Wiley-VCH, Weinheim, 2007, pp. 257-293
39. T. Beweries, J. Thomas, M. Klahn, D. Heller, A. Schulz, U. Rosenthal, ChemCatChem 2011, 3, 1865-1868.
40. For specifications of the light source (LOT-Oriel-300-W-Xe-lamp, LSB530) and cut-off filter (ITOS, GG420) see: http://www.lot-oriel.com.
41. Gaussian 09 Rev. A.02, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian, A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth, P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels, O. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski, D. J. Fox, Gaussian, Inc., Wallingford, CT, 2009.
42. C. Adamo, V. Barone, J. Chem. Phys. 1999, 110, 6158-6169.
43. F.-Q. Bai, J. Wang, B.-H. Xia, Q.-J. Pan, H.-X. Zhang, Dalton Trans. 2012, 41, 8441-8446.
44. P. J. Hay, W. R. Wadt, J. Chem. Phys. 1985, 82, 270-283
45. P. J. Hay, W. R. Wadt, J. Chem. Phys. 1985, 82, 299-310
46. W. R. Wadt, P. J. Hay, J. Chem. Phys. 1985, 82, 284-298.
47. J. Tomasi, B. Menucci, E. Cancès, THEOCHEM 1999, 464, 211-226.