Light-alkane oxidative dehydrogenation to light olefins over platinum-based sapo-34 zeolite-supported catalyst

Industrial and Engineering Chemistry Research

Volumn 52, Issue 1, 2013, Pages 346-352

  Nawaz, Zeeshan ^a,b   Wei, Fei ^a  

^a TSINGHUA UNIVERSITY   (China)

^b SAUDI BASIC INDUSTRIES CORPORATION   (Saudi Arabia)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST PERFORMANCE; CATALYST UTILIZATION; COKE ANALYSIS; COKE FORMATION; DEACTIVATION RATE; DIHYDROGEN; EXPERIMENTAL JUSTIFICATION; HYDROGEN-ABSTRACTION; INTERMEDIATE PRODUCT; LIGHT OLEFINS; OPTIMUM OPERATING CONDITIONS; OXIDATIVE DEHYDROGENATIONS; SAPO-34; SURFACE AREA; X RAY FLUORESCENCE;

BUTANE; BUTENES; CARBON DIOXIDE; CARBON MONOXIDE; CHEMISORPTION; DEHYDROGENATION; HYDROGEN; PLATINUM; PROPANE; PROPYLENE; REACTION INTERMEDIATES; TIN; TRANSMISSION ELECTRON MICROSCOPY;

CATALYST DEACTIVATION;

EID: 84872155946     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie301422n     Document Type: Article

References (43)

1. Beretta, A.; Forzatti, P.; Ranzi, E. Production of Olefins via Oxidative Dehydrogenation of Propane in Autothermal Conditions J. Catal. 1999, 184, 469
2. 3 Catalyst in the Oxidative Dehydrogenation of Propane in Annular Reactor J. Catal. 1999, 184, 455
3. Yokoyama, C.; Bharadwaj, S. S.; Schmidt, L. D. Platinum-tin and platinum-copper catalysts for autothermal oxidative dehydrogenation of ethane to ethylene Catal. Lett. 1996, 38, 181
4. 6) Alkanes Adv. Catal. 1994, 40, 1
5. Mamedov, E. A.; Corberan, V. C. Oxidative dehydrogenation of lower alkanes on vanadium oxide-based catalysts. The present state of the art and outlooks Appl. Catal., A 1995, 127, 1
6. Chaar, M. A.; Patel, D.; Kung, M. C.; Kung, H. H. Selective oxidative dehydrogenation of butane over V-Mg-O catalysts J. Catal. 1987, 105, 483
7. Chaar, M. A.; Patel, D.; Kung, H. H. Selective oxidative dehydrogenation of propane over V-Mg-O catalysts J. Catal. 1988, 109, 463
8. Corma, A.; Lopez-Nieto, J. M.; Paredes, N. Influence of the Preparation Methods of V-Mg-O Catalysts on Their Catalytic Properties for the Oxidative Dehydrogenation of Propane J. Catal. 1993, 144, 425
9. 3 Supported Vanadium Oxides J. Catal. 1994, 145, 318
10. 3-Supported Chromium Oxide-Based Catalysts Catal. Lett. 2003, 87, 121
11. 3 catalysts for the oxidative dehydrogenation of propane: Effect of Mo loading Appl. Catal., A 2001, 207, 421
12. Abello, M. C.; Gomez, M. F.; Rivarola, J. B.; Ferretti, O. 4th World Congress on Oxidation Catalysis, Potsdam, Germany, Sept 2001; Springer: Berlin, 2001; p 87.
13. Flick, D. W.; Huff, M. C. Oxidative dehydrogenation of ethane over supported chromium oxide and Pt modified chromium oxide Appl. Catal., A 1999, 187, 13
14. Grzybowska, B.; Sloczynki, J.; Grabowski, R.; Wcislo, K.; Kozlowska, A.; Stoch, J.; Zielinski, J. Chromium Oxide/Alumina Catalysts in Oxidative Dehydrogenation of Isobutane J. Catal. 1998, 178, 687
15. 3 in Oxidative Dehydrogenation of Isobutane to Isobutene Ind. Eng. Chem. Res. 2001, 40, 781
16. Grzybowska-Świerkosz, B. Thirty years in selective oxidation on oxides: what have we learned? Top. Catal. 2000, 11-12, 23
17. Hoang, M.; Mathews, J. F.; Pratt, K. C.; Xie, Z. A kinetic study of oxidative dehydrogenation of isobutane to isobutylene over chromium oxide supported on lanthanum carbonate Kinet. Catal. 2010, 51, 398
18. Al-Zahrani, S. M.; Jibril, B. Y.; Abaseed, A. E. Propane Oxidative Dehydrogenation over Alumina-Supported Metal Oxides Ind. Eng. Chem. Res. 2000, 39, 4070
19. 3 on Pd/Carbon Catalysts: Nature and Role of Pd Active Species J. Catal. 2001, 209, 279
20. Grasselli, R. K.; Stern, D. L.; Tsikoyannis, J. G. Catalytic Dehydrogenation (DH) of Light Paraffins Combined with Selective Hydrogen Combustion (SHC): I. DH-SHC-DH Catalysts in Series (Co-Fed Process Mode) Appl. Catal., A 1999, 189, 1
21. Grasselli, R. K.; Stern, D. L.; Tsikoyannis, J. G. Catalytic Dehydrogenation (DH) of Light Paraffins Combined with Selective Hydrogen Combustion (SHC): II. DH + SHC Catalysts Physically Mixed (Redox Process Mode) Appl. Catal., A 1999, 189, 9
22. 2 Removal J. Catal. 2004, 222, 480
23. Vajda, S.; Pellin, M. J.; Greeley, J. P.; Marshall, C. L.; Curtiss, L. A.; Ballentine, G. A.; Elam, J. W.; Catillon-Mucherie, S.; Redfern, P. C.; Mehmood, F.; Zapol, P. Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane Nat. Mater. 2009, 8, 213
24. Cavani, F.; Ballarini, N.; Cericola, A. Oxidative dehydrogenation of ethane and propane: How far from commercial implementation? Catal. Today 2007, 127, 113
25. Huff, M.; Schmidt, L. D. Ethylene formation by oxidative dehydrogenation of ethane over monoliths at very short contact times J. Phys. Chem. 1993, 97, 11815
26. Wolf, D.; Dropka, N.; Smejkal, Q.; Buyevskaya, O. Oxidative dehydrogenation of propane for propylene production-comparison of catalytic processes Chem. Eng. Sci. 2007, 56, 713
27. Nawaz, Z.; Tang, X. P.; Zhang, Q.; Dezheng, W.; Wei, F. A highly selective Pt-Sn/SAPO-34 catalyst for propane dehydrogenation to propylene Catal. Commun. 2009, 10, 1925
28. Nawaz, Z.; Shu, Q.; Jixian, G.; Tang, X. T.; Wei, F. Effect of Si/Al ratio on performance of Pt-Sn-based catalyst supported on ZSM-5 zeolite for n -butane conversion to light olefins J. Ind. Eng. Chem. 2010, 16, 57
29. 3-SAPO-34 as a support for propane dehydrogenation to propylene J. Ind. Eng. Chem. 2011, 17, 389
30. Nawaz, Z.; Chu, Y.; Yang, W.; Tang, X. P.; Wang, Y.; Wei, F. Study of Propane Dehydrogenation to Propylene in an Integrated Fluidized Bed Reactor Using Pt-Sn/Al-SAPO-34 Novel Catalyst Ind. Eng. Chem. Res. 2010, 49, 4614
31. Nawaz, Z.; Tang, X. P.; Zhu, J.; Wei, F.; Naveed, S. Catalytic cracking of 1-hexene to propylene using integrated SAPO-34 catalysts topologies Chin. J. Catal. 2009, 30, 1049
32. Nawaz, Z.; Tang, X. P.; Yu, C.; Wei, F. 1-Hexene catalytic cracking to propylene using shape selective molecular sieve SAPO-34 zeolite Arab. J. Sci. Eng. B 2010, 35, 15
33. Wei, F.; Nawaz, Z. (S.); Tang, X. P.; Chu, Y.; Wang, Y. Integrated Fluidized Bed Reactor Design for Alkane Dehydrogenation. CN 201010103170.4, 2010.
34. Nawaz, Z.; Wei, F.; Naveed, S. Highly stable Pt-Sn-based, SAPO-34 supported, Al-binded catalyst, and Integrated Fluidized Bed Reactor Design for Alkane Dehydrogenation. Pak. Patent 141413, 2009.
35. Wei, F.; Nawaz, Z. (S.); Tang, X. P. Light alkane dehydrogenation to olefins catalyst, their preparation method and applications. Patent CN 200910091226.6, 2009.
36. Nawaz, Z.; Wei, F.; Naveed, S. Pt-Sn-based catalyst for selective propane dehydrogenation to propylene: Higher propylene selectivity and yield. Pak Patent 140812, 2010.
37. Nawaz, Z.; Tang, X. P.; Chu, Y.; Wei, F. Influence of calcinations temperature and reaction atmosphere on catalytic properties of Pt-Sn/SAPO-34 novel catalyst for propane dehydrogenation to propylene Chin. J. Catal. 2010, 31, 552
38. Nawaz, Z.; Wei, F. Pt-Sn-Based SAPO-34 Supported Novel Catalyst for n -Butane Dehydrogenation Ind. Eng. Chem. Res. 2009, 48, 7442
39. Nawaz, Z.; Tang, X. P.; Wang, Y.; Wei, F. Parametric Characterization and Influence of Tin on the Performance of Pt-Sn/SAPO-34 Catalyst for Selective Propane Dehydrogenation to Propylene Ind. Eng. Chem. Res. 2010, 49, 1274
40. Kotanjac, Z. Development of packed bed membrane reactor for the oxidative dehydrogenation of propane. Ph.D. Thesis, University of Twente, Enschede, The Netherlands, 2009.
41. 4 for Propane Dehydrogenation J. Catal. 1986, 98, 235
42. Yarusov, I. B.; Zatolookina, E. V.; Shitova, N. V. Propane Dehydrogenation over Pt-Sn Catalysts Catal. Today 1992, 13, 655
43. Nawaz, Z.; Wei, F. Hydrothermal study of Pt-Sn-based SAPO-34 supported novel catalyst used for selective propane dehydrogenation to propylene J. Ind. Eng. Chem. 2010, 16, 774