Synthesis and properties of biodegradable polycaprolactone/polyurethanes by using 2,6-pyridinedimethanol as a chain extender

Polymer Degradation and Stability

Volumn 98, Issue 2, 2013, Pages 643-650

  Tsou, Chi Hui ^a,b   Lee, Hsun Tsing ^c   Tsai, Hui An ^d   Cheng, Hsiang Jung ^d   Suen, Maw Cherng ^d  

^a NATIONAL TAIWAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Taiwan)

^b ORIENTAL INSTITUTE OF TECHNOLOGY   (Taiwan)

^c VANUNG UNIVERSITY   (Taiwan)

^d TAOYUAN INNOVATION INSTITUTE OF TECHNOLOGY   (Taiwan)

Author keywords

Biodegradable; Hydrolytic degradation; Polycaprolactone diol; Polyurethanes

Indexed keywords

AMORPHOUS COMPOUNDS; AQUEOUS ETHANOL SOLUTIONS; BIODEGRADABLE; CAPROLACTONE; CHAIN EXTENDERS; DIPHENYLMETHANE DIISOCYANATE; ELONGATION AT BREAK; FTIR ANALYSIS; HYDROLYTIC DEGRADATION; POLYCAPROLACTONE DIOLS; POLYMER CHAINS; PREPOLYMERS; SEM IMAGE; SWELLING DEGREE; XRD PATTERNS; YOUNG'S MODULUS;

CRACKS; DEGRADATION; ETHANOL; POLYURETHANES; STRESS-STRAIN CURVES;

POLYCAPROLACTONE;

EID: 84872120056     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2012.11.010     Document Type: Article

References (24)

1. S.J. Huang Encyclopedia of polymer science and engineering vol. 2 1985 John Wiley and Sons pp.220-43
2. R. Chandra, and R. Rustgi Biodegradable polymers Program Polymer Science 23 1998 1273 1335
3. M. Okada Chemical syntheses of biodegradable polymers Program Polymer Science 27 2002 87 133
4. L.S. Nair, and C.T. Laurencin Biodegradable polymers as biomaterials Progress in Polymer Scince 32 2007 762 798
5. J. Pena, T. Corrales, I. Izquierdo-Barba, A.L. Doadrio, and M. Vallet-Regi Long term degradation of poly(ε-caprolactone) films in biologically related fluids Polymer Degradation and Stability 91 2006 1424 1432
6. O. Coulembier, P. Degee, J.L. Hedrick, and P. Dubois From controlled ring-opening polymerization to biodegradable aliphatic polyester: especially poly(beta-malic acid) derivatives Program Polymer Science 31 2006 723 747
7. F.G. Li, J.N. Hou, W. Zhu, X.A. Zhang, M. Xu, and X.L. Luo Crystallinity and morphology of segmented polyurethanes with different soft-segment length Journal of Applied Polymer Science 62 1996 631 638
8. S. Velankar, and S.L. Cooper Microphase separation and rheological properties of polyurethane melts. 1. Effect of block length Macromolecules 31 1998 9181 9192
9. H.M. Jeong, B.K. Ahn, and B.K. Kim Miscibility and shape memory effect of thermoplastic polyurethane blends with phenoxy resin European Polymer Journal 37 2001 2245 2252
10. M. Arcana, O. Giani-Beaune, R. Schue, F. Schue, W. Amass, and A. Amass Ring-opening copolymerization of racemic β-butyrolactone with ε-caprolactone and δ-valerolactone by distannoxane derivative catalysts: study of the enzymatic degradation in aerobic media of obtained copolymers Polymer Interation 51 10 2002 859 866
11. T. Hatakeyama, Y. Izuta, S. Hirose, and H. Hatakeyama Phase transitions of lignin-based polycaprolactones and their polyurethane derivatives Polymer 43 2002 1177 1182
12. T. Padmavathy, and K.S.V. Srinivasan Synthesis and properties of segmented main-chain liquid-crystalline polyurethanes with a high aspect ratio mesogenic diol as a chain extender Journal of Polymer Science Part A: Polymer Chemistry 40 2002 1527 1538
13. S. Dadbin, and M. Frounchi Effects of polyurethane soft segment and crosslink density on the morphology and mechanical properties of polyurethane/poly(allyl diglycol carbonate) simultaneous interpenetrating polymer networks Journal of Applied Polymer Science 89 2003 1583 1595
14. R.G.J.C. Heijkants, L.W. Schwab, R.V. van Calck, J.H. de Groot, A.J. Pennings, and A.J. Schouten Extruder synthesis of a new class of polyurethanes: polyacylurethanes based on poly(ε-caprolactone) oligomers Polymer 46 2005 8981 8989
15. S. Mondal, and J.L. Hu Structural characterization and mass transfer properties of polyurethane block copolymer: influence of mixed soft segment block and crystal melting temperature Polymer International 55 2006 1013 1020
16. E. Ayres, R.L. Oréfice, and M.I. Yoshida Phase morphology of hydrolysable polyurethanes derived from aqueous dispersions European Polymer Journal 43 2007 3510 3521
17. X. Jiang, J.H. Li, M.M. Ding, H. Tan, Q.Y. Ling, and Y.P. Zhong Synthesis and degradation of nontoxic biodegradable waterborne polyurethanes elastomer with poly(ε-caprolactone) and poly(ethylene glycol) as soft segment European Polymer Journal 43 2007 1838 1846
18. J.H. Hong, H.J. Jeon, J.H. Yoo, W.R. Yu, and J.H. Youk Synthesis and characterization of biodegradable poly(ε-caprolactone-co-β- butyrolactone)-based polyurethane Polymer Degradation and Stability 92 2007 1186 1192
19. F. Cao, and S.C. Jana Nanoclay-tethered shape memory polyurethane nanocomposites Polymer 48 2007 3790 3800
20. Z.G. Xie, C.H. Lu, X.S. Chen, L. Chen, X.L. Hu, and Q. Shi A facile approach to biodegradable poly(ε-caprolactone)-poly(ethylene glycol)-based polyurethanes containing pendant amino groups European Polymer Journal 43 2007 2080 2087
21. L. Tatai, T.G. Moore, R. Adhikari, F. Malherbe, R. Jayasekara, and I. Griffiths Thermoplastic biodegradable polyurethanes: the effect of chain extender structure on properties and in-vitro degradation Biomaterials 28 2007 5407 5417
22. J.M. Yeh, C.T. Yao, C.F. Hsieh, H.C. Yang, and C.P. Wu Preparation and properties of amino-terminated anionic waterborne-polyurethane-silica hybrid materials through a sol-gel process in the absence of an external catalyst European Polymer Journal 44 2008 2777 2783
23. L. Rueda-Larraz, B. Fernandez d'Arlas, A. Tercjak, A. Ribes, I. Mondragon, and A. Eceiza Synthesis and microstructure-mechanical property relationships of segmented polyurethanes based on a PCL-PTHF-PCL block copolymer as soft segment European Polymer Journal 45 2009 2096 2109
24. M. Amrollahi, G.M.M. Sadeghi, and Y. Kashcooli Investigation of novel polyurethane elastomeric networks based on polybutadieneol/polypropyleneoxide mixture and their structure-properties relationship Materials and Design 32 2011 3933 3941