Phosphorus- and nitrogen-doped silica coatings for enhancing the flame retardancy of cotton: Synergisms or additive effects?

Polymer Degradation and Stability

Volumn 98, Issue 2, 2013, Pages 579-589

  Alongi, Jenny ^a   Colleoni, Claudio ^b   Rosace, Giuseppe ^b   Malucelli, Giulio ^a  

^a POLITECNICO DI TORINO   (Italy)

^b UNIVERSITY OF BERGAMO   (Italy)

Author keywords

Cotton; Flame retardancy; Sol gel processes; Synergisms

Indexed keywords

ADDITIVE EFFECTS; BISPHOSPHONATES; BURNING TIME; CELLULOSIC SUBSTRATES; CONE CALORIMETRY; FLAME RETARDANCY; HEAT RELEASE RATE (HRR); NITROGEN-DOPED; OXIDE PHASIS; PHOSPHORUS-DOPED; SILICA COATINGS; SYNERGISMS;

ADDITIVES; COATINGS; COTTON; COTTON FABRICS; FIRE RESISTANCE; SILICA; SOL-GEL PROCESS; SOL-GELS; UREA;

PHOSPHORUS;

EID: 84872104515     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2012.11.017     Document Type: Article

References (20)

1. A.R. Horrocks Flame retardant challenges for textiles and fibres: new chemistry versus innovatory solutions Polym Degrad Stab 96 3 2011 377 392
2. E.D. Weil, and S.V. Levchik Flame retardants in commercial use or development for textiles J Fire Sci 26 3 2008 243 281
3. A.R. Horrocks An introduction to the burning behaviour of cellulosic fibres J Soc Dyes Col 99 7-8 1983 191 197
4. J. Alongi, G. Camino, and G. Malucelli Heating rate effect on char yield from cotton, poly(ethylene terephthalate) and blend fabrics Carbohydr Polym 92 2013 1327 1334
5. J.E. Hendrix, G.L. Drake, and R.H. Barker Pyrolysis and combustion of cellulose III. Mechanistic basis for the synergism involving organic phosphates and nitrogenous bases J Appl Polym Sci 16 2 1972 257 274
6. J.E. Hendrix, G.L. Drake, and R.H. Barker Pyrolysis and combustion of cellulose II. Thermal analysis of mixture of methyl alpha-D-glucopyranoside and levoglucosan with model phosphate flame retardants J Appl Polym Sci 16 1 1972 41 59
7. J.E. Hendrix, J.E. Bostic, E.S. Olson, and R.H. Barker Pyrolysis and combustion of cellulose I. Effects of thiphenyl phosphate in the presence of nitrogenous bases J Appl Polym Sci 14 7 1970 1701 1723
8. M. Lewin Synergism and catalysis in flame retardancy of polymers Polym Adv Technol 12 3-4 2001 215 222
9. A.R. Horrocks, G. Smart, S. Nazaré, B. Kandola, and D. Price Quantification of zinc hydroxystannate and stannate synergies in halogen-containing flame-retardant polymeric formulations J Fire Sci 28 3 2010 217 248
10. Alongi J, Frache A, Malucelli G, Camino G. In: Kilinc-Balci FS, editor. Handbook of fire resistant textiles: multi-component flame retardant coatings, USA, Woodhead Publishing, in press [ISBN: 0857091239].
11. J. Alongi, and G. Malucelli State of the art and perspectives on sol-gel derived hybrid architectures for flame retardancy of textiles J Mater Chem 22 41 2012 21805 21809
12. J. Alongi, M. Ciobanu, and G. Malucelli Novel flame retardant finishing systems for cotton fabrics based on phosphorus-containing compounds and silica derived from sol-gel processes Carbohydr Polym 85 3 2012 599 608
13. G. Brancatelli, C. Colleoni, M.R. Massafra, and G. Rosace Effect of hybrid phosphorus-doped silica thin films produced by sol-gel method on the thermal behaviour of cotton fabrics Polym Degrad Stab 96 4 2011 483 490
14. N. Yaman Preparation and flammability properties of hybrid materials containing phosphorous compounds via sol-gel process Fibers Polym 10 4 2009 413 418
15. 2 thin films on fabrics J Appl Polym Sci 105 6 2007 2085 2091
16. Alongi J, Colleoni C, Malucelli G, Rosace G. The role of pre-hydrolysis on multistep sol-gel processes for enhancing the flame retardancy of cotton. Cellulose, in press.
17. J. Tata, F. Carosio, J. Alongi, and A. Frache Optimization of the procedure to burn textile fabrics by cone calorimeter: part I. Combustion behavior of polyester Fire Mater 35 6 2010 397 409
18. G. Camino, L. Costa, and L. Trossarelli Study of the mechanism of intumescence in fire retardant polymers: part III. Effect of urea on the ammonium polyphosphate -pentaerythritol system Polym Degrad Stab 7 4 1984 221 229
19. J. Alongi, C. Colleoni, G. Malucelli, and G. Rosace Hybrid phosphorus-doped silica architectures derived from a multistep sol-gel process for improving thermal stability and flame retardancy of cotton fabrics Polym Degrad Stab 97 8 2012 1334 1344
20. E.L. Back Thermal auto-crosslinking in cellulose material Pulp Paper Magazine Can 8 4 1967 T165 T171