Structural transformation of a lithium-rich Li1.2Co 0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffraction

Journal of Power Sources

Volumn 229, Issue , 2013, Pages 239-248

  Mohanty, Debasish ^a   Kalnaus, Sergiy ^a   Meisner, Roberta A ^a   Rhodes, Kevin J ^b   Li, Jianlin ^a   Payzant, E Andrew ^a   Wood III, David L ^a   Daniel, Claus ^a,c  

^a OAK RIDGE NATIONAL LABORATORY   (United States)

^b FORD MOTOR COMPANY   (United States)

^c UNIVERSITY OF TENNESSEE   (United States)

Author keywords

High voltage cycling; In situ XRD; Li rich NMC; Phase transformation; Spinel

Indexed keywords

CAPACITY FADE; CATHODE MATERIALS; FIRST CYCLE; HIGH ENERGY DENSITIES; HIGH VOLTAGE; HIGH-VOLTAGE CYCLING; HIGH-VOLTAGES; IN-SITU XRD; IRREVERSIBLE CAPACITY; LAYERED OXIDES; LI-RICH NMC; LITHIUM EXTRACTION; LITHIUM-ION BATTERY; LOW-VOLTAGE DISCHARGES; MONOCLINIC PHASE; OXIDE CATHODE; OXYGEN LOSS; PLATEAU REGION; SITU X-RAY DIFFRACTION; SPINEL; STRUCTURAL INSTABILITY; STRUCTURAL TRANSFORMATION; TRANSITION METAL LAYERS;

CATHODES; ELECTRIC BATTERIES; ELECTRIC VEHICLES; ELECTRICITY; LATTICE CONSTANTS; LITHIUM COMPOUNDS; MANGANESE; MANGANESE OXIDE; PHASE TRANSITIONS; TRANSITION METALS; X RAY DIFFRACTION;

LITHIUM;

EID: 84872061277     PISSN: 03787753     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jpowsour.2012.11.144     Document Type: Article

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