Characterization of novel GdBa0.5Sr0.5Co 2-xFexO5+δ perovskites for application in IT-SOFC cells

International Journal of Hydrogen Energy

Volumn 38, Issue 2, 2013, Pages 1027-1038

  Kuroda, Chihiro ^a   Zheng, Kun ^b   Świerczek, Konrad ^b  

^a SHIBAURA INSTITUTE OF TECHNOLOGY   (Japan)

^b AGH UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Poland)

Author keywords

A site ordered perovskites; Cathode materials; GdBa0.5Sr0.5Co 2 xFexO5+ ; IT SOFC; Structural properties; Transport properties

Indexed keywords

CATHODE MATERIALS; CERIA ELECTROLYTE; CHEMICAL COMPOSITIONS; CHEMICAL DIFFUSION COEFFICIENTS; CHEMICAL EXPANSION; CO CONTENT; COMPOSITE CATHODE; DOUBLE PEROVSKITES; ELECTRICAL CONDUCTIVITY; ELECTROCHEMICAL MEASUREMENTS; ELECTROLYTE LAYERS; HIGH CONCENTRATION; IMPEDANCE SPECTROSCOPY; INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELL; IRON CONTENT; IT-SOFCS; ORDERED PEROVSKITE; OXYGEN CONTENT; OXYGEN STOICHIOMETRY; PEROVSKITE PHASE; POWER DENSITIES; SURFACE EXCHANGE REACTIONS; TEMPERATURE RANGE;

CARBON DIOXIDE; CATHODES; CERIUM COMPOUNDS; CHARACTERIZATION; DIFFUSION; ELECTRIC CONDUCTIVITY; ELECTROLYTES; ELECTRON TRANSPORT PROPERTIES; LANTHANUM COMPOUNDS; OXYGEN; PEROVSKITE; SOLID OXIDE FUEL CELLS (SOFC); STOICHIOMETRY; STRUCTURAL PROPERTIES; THERMAL EXPANSION; TRANSPORT PROPERTIES;

COBALT COMPOUNDS;

EID: 84872008056     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.10.085     Document Type: Article

References (58)

1. J.W. Fergus, R. Hui, X. Li, D.P. Wilkinson, and J. Zhang Solid oxide fuel cells materials properties and performance 2009 CRC Press
2. S.C. Singhal, and K. Kendall High temperature solid oxide fuel cells: fundamentals, design and applications 2003 Elsevier
3. N. Sammes Fuel cell technology: reaching towards commercialization 2006 Springer
4. E. Ivers-Tiffée, A. Weber, and D. Herbstritt Materials and technologies for SOFC-components J Eur Ceram Soc 21 2001 1805 1811
5. J. Molenda, K. Świerczek, and W. Zaja̧c Functional materials for the IT-SOFC J Power Sourc 173 2007 657 670
6. J. Richter, P. Holtappels, T. Graule, T. Nakamura, and L.J. Gauckler Materials design for perovskite SOFC cathodes Monatsh Chem 140 2009 985 999
7. N.Q. Minh Solid oxide fuel cell technology-features and applications Solid State Ionics 174 2004 271 277
8. E.V. Tsipis, and V.V. Kharton Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review I. Performance-determining factors J Solid State Electrochem 12 2008 1039 1060
9. E.V. Tsipis, and V.V. Kharton Electrode materials and reaction mechanisms in solid oxide fuel cells: a brief review J Solid State Electrochem 12 2008 1367 1391
10. 3-δ-based cathodes for intermediate-temperature solid-oxide fuel cells: a review J Power Sourc 192 2009 231 246
11. T. Ishihara Perovskite oxide for solid oxide fuel cells 2009 Springer
12. 3n+1 (n=1, 2, and 3), as intermediate-temperature solid oxide fuel cells J Am Ceram Soc 93 2010 2329 2333
13. 4 cathode materials for solid oxide fuel cells Sci China Chem 54 2011 898 910
14. 5+δ as materials of oxygen permeation membranes and cathode of SOFCs Acta Mater 56 2008 4876 4889
15. 5+x layered perovskite as an intermediate temperature solid oxide fuel cell cathode J Power Sourc 174 2007 255 263
16. 5+x for ITSOFC applications Solid State Ionics 177 2006 2009 2011
17. 5+δ cathode on samarium-doped ceria electrolyte J Power Sourc 188 2009 96 105
18. 5+δ cathode for intermediate-temperature solid oxide fuel cells under cathodic polarization Int J Hydrogen Energy 34 2009 2416 2420
19. 5+x double-perovskite structure cathode material for intermediate-temperature solid-oxide fuel cells J Power Sourc 185 2008 754 758
20. 5+δ as a potential cathode for intermediate temperature solid oxide fuel cells Int J Hydrogen Energy 36 2011 15715 15721
21. 5+d, a potential cathode material for intermediate-temperature solid oxide fuel cells J Power Sourc 194 2009 704 711
22. 5+δ oxide Solid State Ionics 192 2011 245 247
23. 5+δ(Ln= Lanthanide) J Electrochem Soc 156 2009 B1376 B1382
24. G. King, and P.M. Woodward Cation ordering in perovskites J Mater Chem 20 2010 5785 5796
25. 5+x (0.00≤x≤0.52) J Solid State Chem 156 2001 355 363
26. 5+w (RE=Nd, Sm) J Mater Chem 9 1999 789 797
27. 11 J Mater Chem 177 2004 2122 2128
28. 5+x with a perovskite related structure and ordered A cations J Mater Chem 17 2007 2500 2505
29. A.A. Taskin, A.N. Lavrov, and Y. Ando Achieving fast oxygen diffusion in perovskites by cation ordering Appl Phys Lett 86 2005 091910-1-091910-3
30. A. Tarancón, S.J. Skinner, R.J. Chater, F. Hernández- Ramírez, and J.A. Kilner Layered perovskites as promising cathodes for intermediate temperature solid oxide fuel cells J Mater Chem 17 2007 3175 3181
31. 5+δ Oxides as cathodes for intermediate-temperature solid oxide fuel cells J Electrochem Soc 155 2008 B385 B390
32. 5+δ(0≤x≤1.0) double perovskites as cathodes for solid oxide fuel cells J Electrochem Soc 155 2008 B1023 B1028
33. 1.9 composite cathodes for intermediate-temperature solid oxide fuel cells J Power Sourc 195 2010 2174 2181
34. 5+δ as a cathode for intermediate-temperature solid oxide fuel cells J Power Sourc 195 2010 1076 1078
35. 5+δ (Ln=Pr, Sm, and Gd) as cathode materials for IT-SOFC J Electrochem Soc 156 2009 B682 B689
36. 5+δ layered perovskite as promising cathode for proton conducting solid oxide fuel cell J Alloy Compd 496 2010 683 686
37. 5+δ (x=0, 0.5, 1) infiltrated into yttria-stabilized zirconia scaffold as cathodes for solid oxide fuel cells J Power Sourc 201 2012 10 17
38. 1.95 electrolyte for IT-SOFCs Electrochem Comm 11 2009 2085 2088
39. 5+δ-CGO composite cathodes for solid oxide fuel cell Ceram Int 38S 2012 S493 S496
40. 6-δ (M = Fe, Mn; x = 0, 0.2) Thermochim Acta 519 2011 12 15
41. A.C. Larson, and R.B. Von Dreele GSAS general structure analysis system Los Alamos Natl. Lab. Rep. - LAUR 86-748 2004
42. B.H. Toby EXPGUI, a graphical user interface for GSAS J Appl Cryst 34 2001 210 213
43. 4+δ by conductivity relaxation Solid State Ionics 206 2012 67 71
44. J. Crank The mathematics of diffusion 2nd ed. 1975 Oxford University Press New York
45. M.W. den Otter, H.J.M. Bouwmeester, B.A. Boukamp, and H. Verweij Reactor flush time correction in relaxation experiments J Electrochem Soc 148 2001 J1 J6
46. Q.L. Liu, K.A. Khor, and S.H. Chan High-performance low-temperature solid oxide fuel cell with novel BSCF cathode J Power Sourc 161 2006 123 128
47. C.J. Howard, and H.T. Stokes Octahedral tilting in cation-ordered perovskites- a group-theoretical analysis Acta Cryst B60 2004 674 684
48. M. Ram, and Y. Tsur Eliminating chemical effects from thermal expansion coefficient measurements J Electroceram 22 2009 120 124
49. 3 cathodes and rare earth doped ceria electrolytes J Power Sourc 173 2007 675 680
50. 5: square-planar Co(I) in an extended oxide J Am Chem Soc 132 2010 2802 2810
51. 5.0 cobaltite Phys Rev B 84 2011 104107-1-104107-9
52. 3-δLn: La, Sm; a: Sr, Ba) cathode materials and their performance in electrolyte-supported intermediate temperature solid oxide fuel cell J Power Sourc 196 2011 7110 7116
53. 3-δ (M = Sr, Ba, Ca) J Electrochem Soc 143 1996 2722 2729
54. 3 perovskite type oxides J Power Sourc 173 2007 695 699
55. 3-δ Solid State Ionics 121 1999 201 208
56. 3-d J Solid State Electrochem 8 2004 599 605
57. 3-δ Solid State Ionics 156 2003 201 208
58. 4+δ Solid State Ionics 158 2003 395 407