Synthesis of PMMA-b-PU-b-PMMA tri-block copolymers through ARGET ATRP in the presence of air

Express Polymer Letters

Volumn 7, Issue 3, 2012, Pages 249-260

  Krol P ^a   Chmielarz, P ^a  

^a RZESZOW UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

ARGET ATRP; ATRP; Brominated polyurethanes; Molecular engineering; Polymer synthesis

Indexed keywords

ACTIVATORS REGENERATED BY ELECTRON TRANSFERS; ARGET ATRP; ATOM TRANSFER; BIPYRIDINES; COMPLEXING AGENTS; COPPER CATALYST; GPC ANALYSIS; H NMR SPECTROSCOPY; MACROINITIATORS; METHYL METHACRYLATES; MOLE PERCENTAGES; MOLECULAR ENGINEERING; MONOMER CONVERSIONS; NUMBER-AVERAGE; POLYMER SYNTHESIS; POLYMERIZATION TIME; SPECTRAL METHODS;

ACRYLIC MONOMERS; BLOCK COPOLYMERS; BROMINE; CATALYSTS; CONFOCAL MICROSCOPY; COPPER COMPOUNDS; ESTERS; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; POLYURETHANES; SURFACE PROPERTIES;

ATOM TRANSFER RADICAL POLYMERIZATION;

EID: 84871974024     PISSN: 1788618X     EISSN: None     Source Type: Journal    
DOI: 10.3144/expresspolymlett.2013.23     Document Type: Article

References (20)

1. Matyjaszewski K., Dong H., Jakubowski W., Pietrasik J., Kusumo A.: Grafting from surfaces for 'Everyone': ARGET ATRP in the presence of air. Langmuir, 23, 4528-4531 (2007). DOI: 10.1021/la063402e.
2. Jakubowski W., Min K., Matyjaszewski K.: Activators regenerated by electron transfer for atom transfer radical polymerization of styrene. Macromolecules, 39, 39-45 (2006). DOI: 10.1021/ma0522716.
3. Dong H., Matyjaszewski K.: ARGET ATRP of 2-(dimethylamino)ethyl methacrylate as an intrinsic reducing agent. Macromolecules, 41, 6868-6870 (2008). DOI: 10.1021/ma8017553.
4. Tharanikkarasu K., Verma H., Jang W., Lee S. K., Seo J., Baek S., Han H.: Novel poly(methyl methacrylate)-block-polyurethane-block-poly(methyl methacrylate) tri-block copolymers through atom transfer radical polymerization. Journal of Applied Polymer Science, 108, 1538-1544 (2008). DOI: 10.1002/app.27642.
5. Tharanikkarasu K., Kim B. K.: Modification of aqueous polyurethane dispersions via tetraphenylethane iniferters. Journal of Applied Polymer Science, 73, 2993-3000 (1999). DOI: 10.1002/(SICI)1097-4628(19990929)73:14<2993::AID-APP24>3.0.CO;2-B.
6. Verma H., Kannan T.: Novel telechelic 2-methyl-2-bromopropionate terminated polyurethane macroinitiator for the synthesis of ABA type tri-block copolymers through atom transfer radical polymerization of methyl methacrylate. Polymer Journal, 40, 867-874 (2008). DOI: 10.1295/polymj.PJ2007236.
7. Nayak S., Verma H., Kannan T.: Synthesis and characterization of amphiphilic and hydrophobic ABA-type tri-block copolymers using telechelic polyurethane as atom transfer radical polymerization macroinitiator. Colloid and Polymer Science, 288, 181-188 (2010). DOI: 10.1007/s00396-009-2149-2.
8. Yin Z., Koulic C., Pagnoulle C., Jérôme R.: Reactive blending of functional PS and PMMA: Interfacial behavior of in situ formed graft copolymers. Macromolecules, 34, 5132-5139 (2001). DOI: 10.1021/ma001798+.
9. Viala S., Antonietti M., Tauer K., Bremser W.: Structural control in radical polymerization with 1,1 diphenylethylene: 2. Behavior of MMA-DPE copolymer in radical polymerization. Polymer, 44, 1339-1351 (2003). DOI: 10.1016/S0032-3861(03)00004-1.
10. Król B., Król P., Pikus S., Chmielarz P., Skrzypiec K.: Synthesis and characterisation of coating polyurethane cationomers containing fluorine built-in hard urethane segments. Colloid and Polymer Science, 288, 1255-1269 (2010). DOI: 10.1007/s00396-010-2244-4.
11. Sarbu T., Lin K-Y., Spanswick J., Gil R. R., Siegwart D. J., Matyjaszewski K.: Synthesis of hydroxyl-telechelic poly(methyl acrylate) and polystyrene by atom transfer radical coupling. Macromolecules, 34, 9694-9700 (2004). DOI: 10.1021/ma0484375.
12. Koulic C., Yin Z., Pagnoulle C., Gilbert B., Jérôme R.: Premade versus in situ formed compatibilizer at the PS/PMMA interface: Contribution of the Raman con-focal microscopy to the fracture analysis. Polymer, 42, 2947-2957 (2001). DOI: 10.1016/S0032-3861(00)00553-X.
13. Król P., Chmielarz P.: Controlled radical polymerization as the method for modification of polyurethanes by vinyl polymers. in 'Modern Polymeric Materials for Environmental Applications 4th International Seminar, Kraków, Poland' 169-174 (2010).
14. Lapprand A., Boisson F., Delolme F., Méchin F., Pascault J-P.: Reactivity of isocyanates with urethanes: Conditions for allophanate formation. Polymer Degradation and Stability, 90, 363-373 (2005). DOI: 10.1016/j.polymdegradstab.2005.01.045.
15. de la Fuente J. L., Fernández-Garcia M., Fernández-Sanz M., Madruga E. L.: Sequence distribution and stereoregularity of methyl methacrylate and butyl acrylate statistical copolymers synthesized by atom transfer radical polymerization. Macromolecules, 34, 5833-5837 (2001). DOI: 10.1021/ma010428y.
16. Verma H., Kannan T.: Synthesis of tri-block copolymers through reverse atom transfer radical polymerization of methyl methacrylate using polyurethane macroiniferter. Express Polymer Letters, 2, 579-588 (2008). DOI: 10.3144/expresspolymlett.2008.70.
17. di Lena F., Matyjaszewski K.: Transition metal catalysts for controlled radical polymerization. Progress in Polymer Science, 35, 959-1021 (2010). DOI: 10.1016/j.progpolymsci.2010.05.001.
18. Tsarevsky N. V., Matyjaszewski K.: 'Green' atom transfer radical polymerization:-From process design to preparation of well-defined environmentally friendly polymeric materials. Chemical Reviews, 107, 2270-2299 (2007). DOI: 10.1021/cr050947p.
19. Król P., Chmielarz P.: Controlled radical polymerization (CRP) methods in the synthesis of polyurethane copolymers (in Polish). Polimery, 56, 530-540 (2011).
20. Sharifpoor S., Labow R. S., Santerre J. P.: Synthesis and characterization of degradable polar hydrophobic ionic polyurethane scaffolds for vascular tissue engineering applications. Biomacromolecules, 10, 2729-2739 (2009). DOI: 10.1021/bm9004194