Vapour Phase Conversion of Glycerol to Acrolein over Supported Copper

Arabian Journal for Science and Engineering

Volumn 38, Issue 1, 2013, Pages 37-40

  Dar, Bashir A ^a   Dadhwal, Sumit ^a,b   Singh, Gurkirpal ^b   Garg, Pankaj ^b   Sharma, Pushpa ^b   Singh, Baldev ^a  

^a CSIR INDIAN INSTITUTE OF INTEGRATIVE MEDICINE   (India)

^b MAHARISHI MARKANDESHWAR DEEMED TO BE UNIVERSITY   (India)

Author keywords

Acrolein; Copper catalyst; Glycerol; Vapour phase

Indexed keywords

EID: 84871961666     PISSN: 2193567X     EISSN: 21914281     Source Type: Journal    
DOI: 10.1007/s13369-012-0395-y     Document Type: Article

References (30)

1. Ragauskas A. J., Williams C. K., Davison B. H., Britovsek G., Cairney J., Eckert C. A., Frederick W. J., Hallett J. P., Leak D. J., Liotta C. L., Miielenz J. R., Murphy R., Templer R., Tschaplinski T.: The path forward for biofuels and biomaterials. Science 311, 484-489 (2006).
2. Pargliaro M., Ciriminna R., Kimura H., Rossi M., Pina D.: From glycerol to value-added products. Angew. Chem. Int. Ed 46, 4434-40 (2007).
3. Behr A., Eilting J., Irawadi K., Leschinski J., Lindner F.: Improved utilization of renewable resources: new important derivatives of glycerol. Green Chem 10, 13-30 (2008).
4. Zhou C. H., Beltramini J. N., Fan Y. X., Lu G. Q.: "Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals". Chem. Soc. Rev 37, 527-549 (2008).
5. Eriko, T.; Satoshi, S.; Ryoji, T.; Toshiaki, S.: Production of acrolein from glycerol over silica-supported heteropolyacids. Catalysis commun. 1349-1353 (2007).
6. Suprun W., Lutecki M., Papp H.: TPD-TG-MS investigations of the catalytic conversion of glycerol over MOx-Al2O3-PO4. Catalysts Chem. Eng. Technol. 34(1), 134-139 (2011) doi: 10. 1002/ceat. 201000316.
7. Cavani F., Guidetti S., Marinelli L., Piccinini M., Ghedini E., Signoretto M.: The control of selectivity in gas-phase glycerol dehydration to acrolein catalysed by sulfated zirconia. Appl. Catal. B: Env. 100(1-2), 197-204 (2010).
8. Alhanash A., Elena F. K., Ivan V. K.: Gas-phase dehydration of glycerol to acrolein catalysed by caesium heteropoly salt. Appl. Catal. A: General 378, 11-18 (2010).
9. Jia C., Liu Y., Schmidt W., Lu A., Schüth F.: Small-sized HZSM-5 zeolite as highly active catalyst for gas phase dehydration of glycerol to acrolein. J. Catal. 269, 71-79 (2010).
10. Miyazawa T., Koso S., Kunimori K., Tomishige K.: Glycerol hydrolysis to 1, 2-propanediol catalyzed by a heat-resistant ion-exchange resin combined with Ru/C. Appl. Catal. A 329, 30-35 (2007).
11. 2 in glycerol reaction under hydrogen. Green Chem 9, 582-588 (2007).
12. Alhanash A., Kozhevnikova E. F., Kozhevnikov I. V.: Hydrolysis of glycerol to propanediol overru: polyoxometalate bifunctional catalyst. Catal. Lett. 120, 307-311 (2008).
13. Wang S., Liu H.: Selective hydrolysis of glycerol to propylene glycol on Cu-ZnO catalysts. Catal. Lett. 117, 62-67 (2007).
14. Maris E. P., Davis R. J.: Hydrolysis of glycerol over carbon-supported Ru and Pt catalysts. J. Catal. 249, 328-337 (2007).
15. Maris E. P., Ketchie W. C., Murayam M., Davis R. J.: Glycerol hydrolysis on carbon-supported PtRu and AuRu bimetallic catalysts. J. Catal. 251, 281-294 (2007).
16. Montassier C., Menezo J. C., Hoang L. C., Renaud C., Barbier J.: Aqueous polyol conversions on ruthenium and on sulfur-modified ruthenium. J. Mol. Catal. 70, 99-110 (1991).
17. Feng J., Fu H. Y., Wang J. B., Li R. X., Chen H., Li X. J.: Hydrolysis of glycerol to glycols over ruthenium catalysts: Effect of support and catalyst reduction temperature. Catal. Commun. 9, 1458-1464 (2008).
18. 2. Catal. Chem. Lett. 36, 1274 (2007).
19. Perosa A., Tundo P.: Selective hydrolysis of glycerol with Raney nickel. Ind. Eng. Chem. Res. 44, 8535-8537 (2005).
20. Debanjan G., Babita B., Sunkara V. M.: Pd on amine-terminated ferrite nanoparticles: A complete magnetically recoverable facile catalyst hydrogenation reactions. Org. Lett. 9, 1419-1421 (2007).
21. Zheng Y., Chen X., Shen Y.: Commodity chemicals derived fromglycerol, an important biorefinary feedstock. Chem. Rev. 110, 1807 (2010).
22. Avelino C., George W. H., Laurent S., Paul O. C.: Biomass to chemicals: catalytic conversion of glycerol/water mixtures into acrolein, reaction network. J. Catal. 257, 163-171 (2008).
23. Kapil P., Mohan K. R., Bakhshi N. N., Dalai A. K.: Catalytic conversion of glycerol to value added liquid products. Appl. Catal. A 372, 224-238 (2010).
24. Tsukuda E., Sato S., Takahashi R., Sodesawa T.: Production of acrolein from glycerol over silica-supported heteropoly acids. Catal. Commun. 8, 1349-1353 (2007).
25. Chai S., Wang H., Liang Y., Xu B.: Sustainable production of acrolein: investigation of solid acid-base catalysts for gas phase dehydrationof glycerol. Green Chem. 9, 1130-1136 (2007).
26. Atia H., Ambruster U., Martin A.: Dehydration of glycerol in gas phase using hetropoly acid catalysts as active compounds. J. Catal. 258, 71-82 (2008).
27. Antal M. J., Mok W. S. L., Roy J. C., Raissi A. T.: Pyrolytic sources of hydrocarbons from biomass. J. Anal. Appl. Pyrol. 8, 291-303 (1985).
28. Chaminand J., Djakovitch L., Gallezot P., Marion P., Pinel C., Rosier C.: Glycerol hydrolysis on heterogeneous catalysts. Green Chem. 6, 359-361 (2004).
29. Perosa A., Tundo P.: Selective hydrolysis of glycerol with Raney nickel. Ind. Eng. Chem. Res. 44, 8535-8537 (2005).
30. 5 catalyst. J. Catal. 250, 342-349 (2007).