Oxidation mechanisms of CF2Br2 and CH 2Br2 induced by air nonthermal plasma

Environmental Science and Technology

Volumn 47, Issue 1, 2013, Pages 542-548

  Schiorlin, Milko ^a   Marotta, Ester ^a   Dal Molin, Marta ^a   Paradisi, Cristina ^a  

^a UNIVERSITY OF PADOVA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

APCI MASS SPECTROMETRY; BROMOMETHANES; CHARGE EXCHANGES; FTIR ANALYSIS; MECHANISTIC PROBES; NONTHERMAL PLASMA; OH RADICAL; OXIDATION MECHANISMS; POST-DISCHARGE; PROCESSED GAS; PULSED HIGH VOLTAGE; ROOM TEMPERATURE;

ATMOSPHERIC HUMIDITY; ATMOSPHERIC PRESSURE; CARBON DIOXIDE; CHARGE TRANSFER; ELECTRIC DISCHARGES; FREE RADICALS; MASS SPECTROMETRY; OXIDATION; OZONE;

REACTION INTERMEDIATES;

CARBON DIOXIDE; CARBON MONOXIDE; DIBROMODIFLUOROMETHANE; DIBROMOMETHANE; HYDROXYL RADICAL; NITRIC ACID; NITROUS OXIDE; ORGANOBROMINE DERIVATIVE; OZONE; UNCLASSIFIED DRUG; BROMINATED HYDROCARBON; CHLOROFLUOROCARBON; POTASSIUM PEROXYMONOSULFURIC ACID; SULFURIC ACID;

AIR TEMPERATURE; ATMOSPHERIC PRESSURE; FTIR SPECTROSCOPY; HUMIDITY; HYDROXYL RADICAL; ION EXCHANGE; MASS SPECTROMETRY; ORGANIC POLLUTANT; OXIDATION; PLASMA;

AIR; AIR NONTHERMAL PLASMA; AIR POLLUTANT; ARTICLE; ATMOSPHERIC PRESSURE; CATALYSIS; CONTROLLED STUDY; HUMIDITY; HYDROLYSIS; INFRARED SPECTROSCOPY; MASS SPECTROMETRY; ORGANIC POLLUTION; OXIDATION; REACTOR; ROOM TEMPERATURE; CHEMISTRY; OXIDATION REDUCTION REACTION;

AIR; AIR POLLUTANTS; CARBON DIOXIDE; CARBON MONOXIDE; CHLOROFLUOROCARBONS, METHANE; HYDROCARBONS, BROMINATED; NITROUS OXIDE; OXIDATION-REDUCTION; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; SULFURIC ACIDS;

MLCS; MLOWN;

EID: 84871794239     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es303561n     Document Type: Article

References (47)

1. United States Environmental Protection Agency Superfund Cleanup Process, 2011. http://www.epa.gov/superfund/cleanup/index.htm (accessed Nov. 26, 2012).
2. Atkinson, R.; Arey, J. Atmospheric degradation of volatile organic compounds Chem. Rev. 2003, 103, 4605-4638
3. Van Veldhuizen, E. M., Ed. Electrical Discharges for Environmental Purposes: Fundamentals and Applications; Nova Science Publishers: New York, U.S.A., 2000.
4. Fridman, A. Plasma Chemistry; Cambridge University Press: Cambridge, U.K., 2008.
5. Vandenbroucke, A. M.; Morent, R.; De Geyter, N.; Leys, C. Non-thermal plasmas for non-catalytic and catalytic VOC abatement J. Hazard. Mater. 2011, 195, 30-54
6. Zaniol, B.; Schiorlin, M.; Gazza, E.; Marotta, E.; Puiatti, M. E.; Rea, M.; Sonato, P.; Paradisi, C. An emission spectroscopy study of atmospheric plasmas formed by DC and pulsed corona discharges in hydrocarbon contaminated air Int. J. Plasma Environ. Sci. Technol. 2008, 2, 65-71
7. Marotta, E.; Schiorlin, M.; Rea, M.; Paradisi, C. Products and mechanisms of the oxidation of organic compounds in atmospheric air plasmas J. Phys. D: Appl. Phys. 2010, 43, 124011
8. DonoÌ, A.; Paradisi, C.; Scorrano, G. Abatement of volatile organic compounds by corona discharge. a study of the reactivity of trichloroethylene under atmospheric conditions Rapid Commun. Mass Spectrom. 1997, 11, 1687-1694
9. Marotta, E.; Paradisi, C. A mass spectrometry study of alkanes in air plasma at atmospheric pressure J. Am. Soc. Mass Spectrom. 2009, 20, 697-707
10. Marotta, E.; Scorrano, G.; Paradisi, C. Ionic reactions of chlorinated volatile organic compounds in air plasma at atmospheric pressure Plasma Process. Polym. 2005, 2, 209-217
11. Marotta, E.; Callea, A.; Rea, M.; Paradisi, C. DC corona electric discharges for air pollution control. Part 1. Efficiency and products of hydrocarbon processing Environ. Sci. Technol. 2007, 41, 5862-5868
12. Schiorlin, M.; Marotta, E.; Rea, M.; Paradisi, C. Comparison of toluene removal in air at atmospheric conditions by different corona discharges Environ. Sci. Technol. 2009, 43, 9386-9392
13. Magne, L.; Pasquiers, S. LIF spectroscopy applied to the study of non-thermal plasmas for atmospheric pollutant abatement C. R. Phys. 2005, 6, 908-917
14. Nakagawa, Y.; Ono, R.; Oda, T. Density and temperature measurement of OH radicals in atmospheric-pressure pulsed corona discharge in humid air. J. Appl. Phys. 2011, 110, art. no. 073304.
15. Su, Z.-Z.; Ito, K.; Takashima, K.; Katsura, S.; Onda, K.; Mizuno, A. OH radical generation by atmospheric pressure pulsed discharge plasma and its quantitative analysis by monitoring CO oxidation J. Phys. D: Appl. Phys. 2002, 35, 3192-3198
16. Marotta, E.; Callea, A.; Ren, X.; Rea, M.; Paradisi, C. DC corona electric discharges for air pollution control. Part 2. Ionic intermediates and mechanisms of hydrocarbon processing Plasma Process. Polym. 2008, 5, 146-154
17. Marotta, E.; Callea, A.; Ren, X.; Rea, M.; Paradisi, C. A mechanistic study of pulsed corona processing of hydrocarbons in air at ambient temperature and pressure Int. J. Plasma Environ. Sci. Technol. 2007, 1, 39-45
18. Nicoletti, A.; Paradisi, C.; Scorrano, G. Ion chemistry of chloroethanes in air at atmospheric pressure Rapid Commun. Mass Spectrom. 2001, 15, 1904-1911
19. Marotta, E.; Bosa, E.; Scorrano, G.; Paradisi, C. Positive and negative ion chemistry of the anesthetic halothane (1-bromo-1-chloro-2,2,2- trifluoroethane) in air plasma at atmospheric pressure Rapid Commun. Mass Spectrom. 2005, 19, 391-396
20. Lias, S. G. Ionization Energy Evaluation. In NIST Chemistry WebBook, NIST Standard Reference Database No. 69; Maillard, W. G.; Linstrom, P. J., Eds.; National Institute of Standards and Technology: Gaithersburg MD, 2006; http://webbook.nist.gov/chemistry.
21. Fraser, P. J.; Oram, D. E.; Reeves, C. E.; Penkett, S. A.; McCulloch, A. Southern Hemispheric halon trends (1978-1998) and global halon emissions J. Geophys. Res. 1999, 104, 985-999
22. 2Br J. Geophys. Res. 1991, 96, 5025-5043
23. Ko, M. K. W.; Poulet, G. Very short-lived halogen and sulfur substances. In Scientific Assessment of Ozone Depletion: 2002, Global Ozone Research and Monitoring Project Report No. 47; World Meteorological Organization: Geneva, Switzerland, 2003; Chapter 2.
24. Hossaini, R.; Chipperfield, M. P.; Feng, W.; Breider, T. J.; Atlas, E.; Montzka, S. A.; Miller, B. R.; Moore, F.; Elkins, J. The contribution of natural and anthropogenic very short-lived species to stratospheric bromine Atmos. Chem. Phys. 2012, 12, 371-380
25. 2 probed by using cavity ring-down absorption spectroscopy J. Chem. Phys. 2005, 123, 134312
26. Murphy, A. B.; Farmer, A. J. D.; Horrigan, E. C.; McAllister, T. Plasma destruction of ozone depleting substances Plasma Chem. Plasma Process. 2002, 22, 371-385
27. Futamura, S.; Einaga, H.; Zhang, A. H. Comparison of reactor performance in the nonthermal plasma chemical processing of hazardous air pollutants IEEE Trans. Ind. Appl. 2001, 37, 978-985
28. Zhang, A.; Futamura, S.; Yamamoto, T. Nonthermal plasma chemical processing of bromomethane J. Air Waste Manage. Assoc. 1999, 49, 1442-1448
29. Slater, R. C.; Douglas-Hamilton, D. H. Electron-beam-initiated destruction of low concentrations of vinyl chloride in carrier gases J. Appl. Phys. 1981, 52, 5820-5828
30. Rudolph, R.; Francke, K.-P.; Meissner, H. Concentration dependance of VOC decomposition by dielectric barrier discharges Plasma Chem. Plasma Process. 2002, 22, 401-412
31. Chen, J. H.; Davidson, J. H. Ozone production in the negative DC corona: The dependence of discharge polarity Plasma Chem. Plasma Process. 2003, 23, 501-518
32. Seinfeld, J. H.; Pandis, S. N. Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, 2 nd ed.; John Wiley & Sons, Inc.: Hoboken, NJ, 2006.
33. - with a variety of brominated compounds Int. J. Mass Spectrom. Ion Process. 1996, 155, 163-183
34. 1D) reactions with bromocarbons Int. J. Chem. Kinet. 1993, 25, 479-487
35. Van Durme, J.; Dewulf, J.; Leys, C.; Van Langenhove, H. Combining non-thermal plasma with heterogeneous catalysis in waste gas treatment: A review Appl. Catal., B 2008, 78, 324-333
36. Laroussi, M. Low temperature plasma-based sterilization: overview and state-of-the-art Plasma Process. Polym. 2005, 2, 391-400
37. 2O formation in ozonizers J. Chim. Phys. 1986, 83, 279-282
38. Kaye, J. A.; Douglass, A. R.; Jackman, C. H.; Stolarski, R. S.; Zander, R.; Roland, G. Two-dimensional model calculation of fluorine-containing reservoir species in the stratosphere J. Geophys. Res. 1991, 96, 12865-12881
39. De Bruyn, W. J.; Shorter, J. A.; Davidovits, P.; Worsnop, D. R.; Zahniser, M. S.; Kolb, C. E. Uptake of haloacetyl and carbonyl halides by water surfaces Environ. Sci. Technol. 1995, 29, 1179-1185
40. Kolb, C. E.; Worsnop, D. R.; Zahniser, M. S.; De Bruyn, W. J.; Shorter, J. A.; Davidovits, P. In Halon Replacements, ACS Symposium Series 611; Miziolek, A. W.; Tsang, W., Eds.; American Chemical Society: Washington DC, 1995; pp 50.
41. 2O with hydrogen atom and water J. Phys. Chem. 1995, 99, 12512-12519
42. 2O): importance of an additional water molecule Chem. Phys. Lett. 2004, 396, 110-116
43. Herron, J. T.; Green, D. S. Chemical kinetics database and predictive schemes for nonthermal humid air plasma chemistry. Part II. Neutral species reactions Plasma Chem. Plasma Process. 2001, 21, 459-481
44. Sieck, L. W.; Herron, J. T.; Green, D. S. Chemical kinetics database and predictive schemes for humid air plasma chemistry. Part I: Positive ion-molecule reactions Plasma Chem. Plasma Process. 2000, 20, 235-258
45. 2 and NO J. Phys. Chem. A 2005, 109, 3045-3051
46. 2 Chem. Phys. Lett. 2000, 318, 125-130
47. Staneke, P. O.; Groothius, G.; Ingemann, S.; Nibbering, N. M. M. The interplay between electron-transfer and attack on halogen in gas-phase reactions of negative-ions with fluoro-chloromethanes and fluoro-bromomethanes Int. J. Mass. Spectrom. Ion Process. 1995, 149-150, 99-110