Formation yields of C8 1,4-hydroxycarbonyls from OH + n-octane in the presence of NO

Environmental Science and Technology

Volumn 46, Issue 24, 2012, Pages 13278-13283

  Aschmann, Sara M ^a   Arey, Janet ^a   Atkinson, Roger ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITIONAL REACTIONS; ANNULAR DENUDERS; DERIVATIZATIONS; IN-SITU DERIVATIZATION; INTERNAL STANDARDS; N-ALKANES; N-OCTANES; XAD RESIN;

FREE RADICALS; GAS CHROMATOGRAPHY; KETONES; NITROGEN COMPOUNDS;

PARAFFINS;

ACETONYLACETONE; ALKANE; CARBONYL DERIVATIVE; HYDROXYL GROUP; HYDROXYLAMINE; NITRIC OXIDE; OCTANE; HYDROXYL RADICAL; METHANE;

GAS CHROMATOGRAPHY; HYDROXYL RADICAL; NITRIC OXIDE; QUANTITATIVE ANALYSIS; RESIN;

ARTICLE; CHEMICAL REACTION; DERIVATIZATION; GAS CHROMATOGRAPHY; QUANTITATIVE ANALYSIS; QUANTUM YIELD; REACTION ANALYSIS; CHEMISTRY; MASS FRAGMENTOGRAPHY;

ALKANES; FLAME IONIZATION; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HYDROXYL RADICAL; METHANE; NITRIC OXIDE; OCTANES;

EID: 84871300889     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es3041175     Document Type: Article

References (22)

1. Kirchstetter, T. W.; Singer, B. C.; Harley, R. A.; Kendall, G. R.; Traverse, M. Impact of California reformulated gasoline on motor vehicle emissions. 1. Mass emission rates Environ. Sci. Technol. 1999, 33, 318-328
2. Kirchstetter, T. W.; Singer, B. C.; Harley, R. A.; Kendall, G. R.; Hesson, J. M. Impact of California reformulated gasoline on motor vehicle emissions. 2. Volatile organic compound speciation and reactivity Environ. Sci. Technol. 1999, 33, 329-336
3. Atkinson, R.; Arey, J. Atmospheric degradation of volatile organic compounds Chem. Rev. 2003, 103, 4605-4638
4. Calvert, J. G.; Derwent, R. G.; Orlando, J. J.; Tyndall, G. S.; Wallington, T. J. Mechanisms of Atmospheric Oxidation of the Alkanes; Oxford University Press, New York, NY, 2008.
5. Atkinson, R. Rate constants for the atmospheric reactions of alkoxy radicals: an updated estimation method Atmos. Environ. 2007, 41, 8468-8485
6. 8 n -alkanes J. Phys. Chem. 1996, 100, 214-219
7. 8 n -alkanes J. Phys. Chem. A 2001, 105, 1020-1027
8. 8 n -alkanes in the presence of NO Environ. Sci. Technol. 2005, 39, 4447-4453
9. Baker, J.; Arey, J.; Atkinson, R. Rate constants for the reactions of OH radicals with a series of 1,4-hydroxyketones J. Photochem. Photobiol. A: Chem. 2005, 176, 143-148
10. Holt, T.; Atkinson, R.; Arey, J. Effect of water vapor concentration on the conversion of a series of 1,4-hydroxycarbonyls to dihydrofurans J. Photochem. Photobiol. A: Chem. 2005, 176, 231-237
11. Arey, J.; Obermeyer, G.; Aschmann, S. M.; Chattopadhyay, S.; Cusick, R. D.; Atkinson, R. Dicarbonyl products of the OH radical-initiated reaction of a series of aromatic hydrocarbons Environ. Sci. Technol. 2009, 43, 683-689
12. Scanlon, J. T.; Willis, D. E. Calculation of flame ionization detector relative response factors using the effective carbon number concept J. Chromatgr. Sci. 1985, 23, 333-340
13. 2 concentration J. Phys. Chem. A 2010, 114, 10140-10147
14. Dagaut, P.; Wallington, T. J.; Liu, R.; Kurylo, M. J. A kinetics investigation of the gas-phase reactions of OH radicals with cyclic ketones and diones: Mechanistic insights J. Phys. Chem. 1988, 92, 4375-4377
15. Aschmann, S. M.; Arey, J.; Atkinson, R. Reaction of OH radicals with 5-hydroxy-2-pentanone: formation yield of 4-oxopentanal and its OH radical reaction rate constant. Environ. Chem. 2012, in press.
16. Taylor, W. D.; Allston, T. D.; Moscato, M. J.; Fazekas, G. B.; Kozlowski, R.; Takacs, G. A. Atmospheric photodissociation lifetimes for nitromethane, methyl nitrite, and methyl nitrate Int. J. Chem. Kinet. 1980, 12, 231-240
17. Atkinson, R. Gas-phase tropospheric chemistry of volatile organic compounds: 1. Alkanes and alkenes J. Phys. Chem. Ref. Data 1997, 26, 215-290
18. Matsunaga, A.; Ziemann, P. J. Gas-wall partitioning of organic compounds in a Teflon film chamber and potential effects on reaction product and aerosol yield measurements Aerosol Sci. Technol. 2010, 44, 881-892
19. Muthuramu, K.; Shepson, P. B.; O'Brien, J. M. Preparation, analysis, and atmospheric production of multifunctional organic nitrates Environ. Sci. Technol. 1993, 27, 1117-1124
20. 6 alkenes with OH in the presence of NO J. Phys. Chem. A 1998, 102, 8903-8908
21. x Environ. Sci. Technol. 2005, 39, 9229-9236
22. Kwok, E. S. C.; Atkinson, R. Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: an update Atmos. Environ. 1995, 29, 1685-1695