The ultra-deep oxidative desulfurization of diesel fuel by an MnO 2/Al2O3/hydrogen peroxide/aldehyde system

Petroleum Science and Technology

Volumn 31, Issue 2, 2013, Pages 215-223

  Guo, W ^a   Wang, C Y ^a   Shen, X ^a   Lu, X P ^a  

^a NANJING TECH UNIVERSITY   (China)

Author keywords

Aldehyde; Diesel; Hydrogen peroxide; MnO2=Al2O 3; Oxidative desulfurization

Indexed keywords

DIESEL; ISOBUTYL; MNO2=AL2O 3; OXIDATIVE DESULFURIZATION; OXIDATIVE PROCESS; REACTION CONDITIONS; SULFUR CONTENTS; SULFUR IMPURITIES; WATER PHASE;

ALDEHYDES; ALUMINUM; ATMOSPHERIC PRESSURE; DESULFURIZATION; DIESEL FUELS; FORMIC ACID; HYDROGEN; HYDROGEN PEROXIDE; ORGANIC COMPOUNDS; REMOVAL; SOLVENT EXTRACTION; SULFUR;

MANGANESE OXIDE;

EID: 84871183527     PISSN: 10916466     EISSN: 15322459     Source Type: Journal    
DOI: 10.1080/10916466.2010.523745     Document Type: Article

References (18)

1. Bernal, H. G., Caero, L. C., and Alejandre, A. G. (2009). Liquid phase oxidation of dibenzothiophene with aluminasupported vanadium oxide catalysts: An alternative to deep desulfurization of diesel. Catal. Today 142:227-233.
2. Fen, Z. Y., and Shun, Z. J. (2006). Catalytic oxidation of thiophenes in diesel oil. Advances Fine Petrochem. 7:11-13.
3. Garcia, T. V., Tapia, J. A. O., and Oehmichen, R. L. (2005). Conceptual design of a reactive distillation process for ultra-low sulfur diesel production. Chem. Eng. 106:119-131.
4. García, J. L., Fuentes, G. A., Murrieta, F., Navarrete, J., and Cruz, F. J. (2006). Ultra-deep oxidative desulfurization of diesel fuel with H 2O2 catalyzed under mild conditions by polymolybdates supported on Al 2O3. Appl. Catal. A: Gen. 305:15-20.
5. García, J. L., Fuentes, G. A., Murrieta, F., Navarrete, J., and Cruz, F. J. (2008). Ultra-deep oxidative desulfurization of diesel fuel by the Mo/Al 2O3-H 2O2 system: The effect of system parameters on catalytic activity. Appl. Catal. A: Gen. 334:366-373.
6. Giuseppe, A. D., Crucianelli, M., and Angelis, F. D. (2009). Efficient oxidation of thiophene derivatives with homogeneous and heterogeneous MTO/H 2O2 systems: A novel approach for, oxidative desulfurization (ODS) of diesel fuel. Appl. Catal. B: Env. 89:239-245.
7. Ju, C. L., Shun, Z. D., and Hui, G. S. (2007). Oxidative desulfurization of thiophene over modified alumina loading oxide. Acta Chim. Sinica 65:1718-1722.
8. Mayo, S., Gudde, N. J., Brevoord, E., and Plantenga, F. (2002). USLD in real life: Commercial performance of stars and nebula technology. Paper AM-02-38, National Petroleum and Refiners Association Annual Meeting, San Antonio, Texas, 17-19.
9. Murata, S., Murata, K., Kidena, K., and Nomura, M. (2004). A novel oxidative desulfurization system for diesel fuels with molecular oxygen in the presence of cobalt catalysts and aldehydes. Energy Fuels 18:116-121.
10. Ming, L. Z., Xian, Y. G., and Xiang, L. S. (2006). Deep desulfurization of diesel oil by oxidation with hydrogen peroxide catalyzed by ferrous ion. Chem. Eng. Oil Gas 35:285-289.
11. Rao, T. V., Sain, B., Kafola, S., Nautiyal, B. R., Sharma, Y. K., Nanoti, S. M., and Gar, M. O. (2007). Oxidative desulfurization of HDS diesel using the aldehyde/molecular oxygen oxidation system. Energy Fuels 21:3420-3424.
12. Rappas, A. S. (2002a). Process for removing low amounts of organic sulfur from hydrocarbon fuels. U.S. Patent No. 6,402,940, 2002
13. Rappas, A. S. (2002b). Process for removing low amounts of organic sulfur from hydrocarbon fuels. U.S. Patent No. 6,406,616, 2002.
14. Sampanthar, J. T., Xiao, H., Dou, J., Nah, T. Y., Rong, X., and Kwan, W. P. (2006). A novel oxidative desulfurization process to remove refractory sulfur compounds from diesel fuel. Appl. Catal. B: Env. 63:85-93.
15. Tam, P. S., Kittrell, J. R., and Eldridge, J. W. (1990). Desulfurization of fuel oil by oxidation and extraction: Enhancement of extraction oil yield. Ind. Eng. Chem. Res. 29:321-325.
16. Tailleur, R. G., Ravigli, J., Quenza, S., and Valencia, N. J. (2005). Catalyst for ultra-low sulfur and aromatic diesel. Appl. Catal. A: Gen. 282:227-235.
17. Venner, S. F. (2000). Hydrocarbon Process. Int. Ed. 51:5-10.
18. Verduzco, L. F., Garcia, E. T., Quintana, R. G., and Guevara, F. M. (2004). Desulfurization of diesel by oxidation/extraction scheme: Influence of the extraction solvent. Catal. Today. 98:289-294.