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Unfortunately the enantiomers of 5 could not be separated in our hands by the usual chromatographic techniques.
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Unfortunately the enantiomers of 5 could not be separated in our hands by the usual chromatographic techniques.
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The model was built from the core formed by the metal and three bis-triazolylpyridine units taken from crystallography data of a similar complex from Ref. [6]. The phosphonate arms were then left to be minimized using MM+ tool of Hyperchem program while the core was fixed and thus unchanged in the calculation.
-
The model was built from the core formed by the metal and three bis-triazolylpyridine units taken from crystallography data of a similar complex from Ref. [6]. The phosphonate arms were then left to be minimized using MM+ tool of Hyperchem program while the core was fixed and thus unchanged in the calculation.
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A precedent of a related case of chiral memory can be found in Ref. [4].
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