Experimental characterization and modeling of the electrochemical reduction of CO2 in solid oxide electrolysis cells

Electrochimica Acta

Volumn 88, Issue , 2013, Pages 644-653

  Shi, Yixiang ^a   Luo, Yu ^a   Cai, Ningsheng ^a   Qian, Jiqin ^b   Wang, Shaorong ^b   Li, Wenying ^a   Wang, Hongjian ^a  

^a TSINGHUA UNIVERSITY   (China)

^b SHANGHAI INSTITUTE OF CERAMICS   (China)

Author keywords

Carbon deposition; Electrochemistry; Elementary reaction; Heterogeneous chemistry; Solid oxide electrolysis cell

Indexed keywords

CARBON DEPOSITION; CELL PERFORMANCE; CO CONTENT; ELECTROCHEMICAL REDUCTIONS; ELECTRODE DESIGN; ELECTRODE SURFACES; ELEMENTARY CHARGE; ELEMENTARY REACTION; EXPERIMENTAL CHARACTERIZATION; HETEROGENEOUS CHEMISTRY; HETEROGENEOUS REACTIONS; MIXTURE GAS; OPERATING CONDITION; PRODUCT COMPOSITION; SOLID OXIDE ELECTROLYSIS CELLS; SPECIES CONCENTRATION;

CARBON; CARBON DIOXIDE; CATHODES; CHARGE TRANSFER; ELECTROCHEMISTRY; ELECTROLYTIC CELLS; ELECTROLYTIC REDUCTION; GASES; MIXTURES;

COMPUTER SIMULATION;

EID: 84870717598     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2012.10.107     Document Type: Article

References (19)

1. 2 for syngas production 2006 Fuel Cell Seminar Honolulu, Hawaii 2006 Paper No. 418
2. S.D. Ebbesen, J. Høgh, K.A. Nielsen, J.U. Nielsen, and J.U.M. Mogensen Durable SOC stacks for production of hydrogen and synthesis gas by high temperature electrolysis International Journal of Hydrogen Energy 36 2011 7363
3. 2O with renewable or nuclear energy Renewable and Sustainable Energy Reviews 15 2011 1
4. G.L. Hawkes, J. O'Brien, C. Stoots, and B. Hawkes 3D CFD model of a multi-cell high-temperature electrolysis stack International Journal of Hydrogen Energy 34 2009 4189
5. J. Udagawa, P. Aguiar, and N.P. Brandon Hydrogen production through steam electrolysis: modelbased dynamic behavior of a cathode-supported intermediate temperature solid oxide electrolysis cell Journal of Power Sources 180 2008 46
6. S.H. Chan, X.J. Chen, and K.A. Khor An electrolyte model for ceramic oxygen generator and solid oxide fuel cell Journal of Power Sources 111 2002 320
7. M. Ni Modeling of a solid oxide electrolysis cell for carbon dioxide electrolysis Chemical Engineering Journal 164 2010 246
8. E.S. Hecht, G.K. Gupta, H. Zhu, A.M. Dean, R.J. Kee, L. Maier, and O. Deutschmann Methane reforming kinetics within a Ni-YSZ SOFC anode support Applied Catalysis A 295 2005 40
9. V.M. Janardhanan, and O. deutschmann CFD analysis of a solid oxide fuel cell with internal reforming: coupled interactions of transport, heterogeneous catalysis and electrochemical processes Journal of Power Sources 162 2006 1192
10. H. Zhu, and R.J. Kee Modeling electrochemical impedance spectra in SOFC button cells with internal methane reforming Journal of the Electrochemical Society 153 2006 A1765
11. Y. Shi, C. Li, and N. Cai Experimental characterization and mechanistic modeling of carbon monoxide fueled solid oxide fuel cell Journal of Power Sources 196 2011 5526
12. R.J. Kee, M.E. Coltrin, and P. Blarborg Chemically Reacting Flow 2003 John Wiley & Sons. Inc. Hoboken, NJ
13. R. Suwanwarangkul, E. Croiset, M.W. Fowler, P.L. Douglas, E. Entchev, and M.A. Douglas Performance comparison of Fick's, dusty-gas and Stefan-Maxwell models to predict the concentration overpotential of a SOFC anode Journal of Power Sources 122 2003 9
14. P. Costamagna, P. Costa, and V. Antonucci Micro-modelling of solid oxide fuel cell electrodes Electrochimica Acta 43 1998 375
15. S.H. Chan, and Z.T. Xia Anode micro model of solid oxide fuel cell Journal of the Electrochemical Society 148 2001 A388
16. A. Mitterdorfer, and L.J. Gauckler Identification of the reaction mechanism of the Pt, O2(g)yttria-stabilized zirconia system. Part II: model implementation, parameter estimation, and validation Solid State Ionics 117 1999 203
17. S.H. Chan, X.J. Chen, and K.A. Khor Cathode micromodel of solid oxide fuel cell Journal of the Electrochemical Society 151 2004 A164
18. S. Nagata, A. Momma, T. Kato, and Y. Kasuga Numerical analysis of output characteristics of tubular SOFC with internal reformer Journal of Power Sources 101 2001 60
19. R.E. Williford, and L.A. Chick Surface diffusion and concentration polarization on oxide-supported metal electrocatalyst particles Surface Science 547 2003 421