Au40(SR)24 cluster as a chiral dimer of 8-electron superatoms: Structure and optical properties

Journal of the American Chemical Society

Volumn 134, Issue 48, 2012, Pages 19560-19563

  Malola, Sami ^a   Lehtovaara, Lauri ^a   Knoppe, Stefan ^b   Hu, Kuo Juei ^c   Palmer, Richard E ^c   Bürgi, Thomas ^b   Häkkinen, Hannu ^a  

^a UNIVERSITY OF JYVÄSKYLÄ   (Finland)

^b UNIVERSITY OF GENEVA   (Switzerland)

^c UNIVERSITY OF BIRMINGHAM   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CHIRAL DIMERS; CHIRAL STRUCTURES; CLUSTER CORES; LIGAND EXCHANGE REACTIONS; LOW ENERGY STRUCTURES; METAL CORE; STRUCTURAL INFORMATION; SUPERATOMS;

DENSITY FUNCTIONAL THEORY; ELECTRONIC STRUCTURE; OLIGOMERS; OPTICAL PROPERTIES; TRANSMISSION ELECTRON MICROSCOPY;

STRUCTURAL OPTIMIZATION;

DIMER; GOLD; OLIGOMER; STRONTIUM; ORGANOGOLD COMPOUND;

ARTICLE; ATOM; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CIRCULAR DICHROISM; DENSITY FUNCTIONAL THEORY; ELECTRON; MOLECULAR ELECTRONICS; STRUCTURE ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; CHEMISTRY; DIMERIZATION; QUANTUM THEORY; STEREOISOMERISM;

CIRCULAR DICHROISM; DIMERIZATION; ELECTRONS; MODELS, MOLECULAR; ORGANOGOLD COMPOUNDS; QUANTUM THEORY; STEREOISOMERISM;

EID: 84870708475     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja309619n     Document Type: Article

References (31)

1. Templeton, A. C.; Wuelfing, W. P.; Murray, R. W. Acc. Chem. Res. 2000, 33, 27
2. Daniel, M.-C.; Astruc, D. Chem. Rev. 2004, 104, 293
3. Häkkinen, H. Chem. Soc. Rev. 2008, 37, 1847
4. Sardar, R.; Funston, A. M.; Mulvaney, O.; Murray, R. W. Langmuir 2009, 25, 13840
5. Jin, R. C. Nanoscale 2010, 2, 343
6. Tsukuda, T. Bull. Chem. Soc. Jpn. 2012, 85, 151
7. Häkkinen, H. Nature Chem. 2012, 4, 443
8. Gautier, C.; Bürgi, T. ChemPhysChem 2009, 10, 483
9. Aikens, C. M. J. Phys. Chem. Lett. 2011, 2, 99
10. deHeer, W. A. Rev. Mod. Phys. 1993, 65, 611
11. Walter, M.; Akola, J.; Lopez-Acevedo, O.; Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Whetten, R. L.; Gronbeck, H.; Hakkinen, H. Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 9157
12. Akola, J.; Walter, M.; Whetten, R. L.; Häkkinen, H.; Grönbeck, H. J. Am. Chem. Soc. 2008, 130, 3756
13. Lopez-Acevedo, O.; Tsunoyama, H.; Tsukuda, T.; Hakkinen, H.; Aikens, C. M. J. Am. Chem. Soc. 2010, 132, 8210
14. Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Science 2007, 318, 430
15. Heaven, M. W.; Dass, A.; White, P. S.; Holt, K. M.; Murray, R. W. J. Am. Chem. Soc. 2008, 130, 3754
16. Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R. C. J. Am. Chem. Soc. 2008, 130, 5883
17. Zhu, M.; Eckenhoff, W. T.; Pintauer, T.; Jin, R. J. Phys. Chem. C 2008, 112, 14221
18. Qian, H.; Eckenhoff, W. T.; Zhu, Y.; Pintauer, T.; Jin, R. J. Am. Chem. Soc. 2010, 132, 8280
19. Qian, H.; Zhu, Y.; Jin, R. J. Am. Chem. Soc. 2010, 132, 4583
20. Knoppe, S.; Dharmaratne, A. C.; Schreiner, E.; Dass, A.; Burgi, T. J. Am. Chem. Soc. 2010, 132, 16783
21. Knoppe, S.; Dass, A.; Burgi, T. Nanoscale 2012, 4, 4211
22. Knoppe, S.; Dolamic, I.; Dass, A.; Burgi, T. Angew. Chem., Int. Ed. 2012, 51, 7589
23. Enkovaara, J. J. Phys.: Condens. Matter 2010, 22, 253202
24. Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865
25. Häkkinen, H.; Walter, M.; Grönbeck, H. J. Phys. Chem. B 2006, 110, 9927
26. Wang, Z. W.; Toikkanen, O.; Quinn, B. M.; Palmer, R. E. Small 2011, 7, 1542
27. Koskinen, M.; Lipas, P. O.; Manninen, M. Z. Phys. D 1995, 35, 285
28. Häkkinen, H.; Manninen, M. Phys. Rev. B 1995, 52, 1540
29. Moseler, M.; Huber, B.; Häkkinen, H.; Landman, U.; Wrigge, G.; Hoffman, M. A.; von Issendorff, B. Phys. Rev. B 2003, 68, 165413
30. Dolamic, I.; Knoppe, S.; Dass, A.; Burgi, T. Nat. Commun. 2012, 3, 798
31. Tsunoyama, R.; Tsunoyama, H.; Pannopard, P.; Limtrakul, J.; Tsukuda, T. J. Phys. Chem. C 2010, 114, 16004