Diastereodivergent synthesis of trisubstituted alkenes through protodeboronation of allylic boronic esters: Application to the synthesis of the californian red scale beetle pheromone

Angewandte Chemie - International Edition

Volumn 51, Issue 50, 2012, Pages 12444-12448

  Hesse, Matthew J ^a   Butts, Craig P ^a   Willis, Christine L ^a   Aggarwal, Varinder K ^a  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

alkenes; allylic compounds; diastereoselectivity; natural products; protodeboronation

Indexed keywords

ALLYLIC COMPOUNDS; BORONIC ESTERS; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE; NATURAL PRODUCTS; PROTODEBORONATION; SEX PHEROMONE; TRISUBSTITUTED ALKENES;

ESTERIFICATION; ESTERS; STEREOSELECTIVITY;

OLEFINS;

4 METHYLBENZENESULFONIC ACID; 4-METHYLBENZENESULFONIC ACID; ALKENE; BENZENESULFONIC ACID DERIVATIVE; BIOLOGICAL PRODUCT; BORON; COPPER; ESTER; HYDROFLUORIC ACID; POTASSIUM DERIVATIVE; POTASSIUM HYDROGEN FLUORIDE; SEX PHEROMONE;

ANIMAL; ARTICLE; BEETLE; CATALYSIS; CHEMISTRY; LIGHT; METABOLISM; STEREOISOMERISM; SYNTHESIS;

ALKENES; ANIMALS; BEETLES; BENZENESULFONATES; BIOLOGICAL AGENTS; BORON; CATALYSIS; COPPER; ESTERS; HYDROFLUORIC ACID; LIGHT; POTASSIUM COMPOUNDS; SEX ATTRACTANTS; STEREOISOMERISM;

EID: 84870594835     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201207312     Document Type: Article

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