Preparation of Cu/ZnO/Al2O3 catalysts in a solvent-free routine for CO hydrogenation

Journal of Zhejiang University: Science A

Volumn 13, Issue 5, 2012, Pages 395-406

  Lei, Hong ^a,b   Nie, Ren Feng ^a   Fei, Jin Hua ^a   Hou, Zhao Yin ^a  

^a ZHEJIANG UNIVERSITY   (China)

^b QUZHOU UNIVERSITY   (China)

Author keywords

CO hydrogenation; Cu ZnO Al2O3 catalyst; Dimethyl ether; Methanol; Solvent free routine

Indexed keywords

CO HYDROGENATION; COPPER NITRATE; CU-BASED CATALYST; CU/ZNO/AL; DIMETHYL ETHERS; IN-SITU XRD; METALLIC COPPER; PHYSICOCHEMICAL PROPERTY; PRECURSOR SALTS; REDUCTION PROCESS; REDUCTION TEMPERATURES; SCANNING ELECTRONIC MICROSCOPY; SOLVENT FREE; SURFACE AREA; TEMPERATURE-PROGRAMMED REDUCTION;

ADSORPTION; ALUMINUM; CALCINATION; CITRIC ACID; DIFFERENTIAL SCANNING CALORIMETRY; FUELS; HYDROGENATION; METHANOL; ORGANIC SOLVENTS; ORGANOMETALLICS; SALTS; SOLVENTS; THERMOGRAVIMETRIC ANALYSIS; X RAY DIFFRACTION;

CATALYSTS;

EID: 84870363862     PISSN: 1673565X     EISSN: 18621775     Source Type: Journal    
DOI: 10.1631/jzus.A1100345     Document Type: Article

References (47)

1. Agrell, J., Boutonnet, M., Fierro, J.L.G., 2003. Production of hydrogen from methanol over binary Cu/ZnO catalysts: Part II. Catalytic activity and reaction pathways. Applied Catalysis A: General, 253(1):213-223. [doi:10.1016/S0926-860X(03)00521-0]
2. 2 catalysts in the hydrogenation of carbon dioxide to methanol. Journal of Catalysis, 249(2): 185-194. [doi:10.1016/j.jcat.2007.04.003]
3. 2 catalysts prepared via the urea-nitrate combustion method. Applied Catalysis A: General, 244(1):155-167. [doi:10.1016/S0926-860X(02)00558- 6]
4. 3/Zr-modified ferrierite: effect of Zr content. Applied Catalysis B: Environmental, 90(3-4):426-435. [doi:10.1016/j. apcatb.2009.04.002]
5. 3 catalysts for me-thanol synthesis. Journal of Catalysis, 258(2):334-344. [doi:10.1016/j.jcat.2008.07.004]
6. Behera, S.K., Barpanda, P., Pratihar, S.K., Bhattacharyya, S., 2004. Synthesis of magnesium-aluminium spinel from autoignition of citrate-nitrate gel. Materials Letters, 58(9):1451-1455. [doi:10.1016/j.matlet.2003.10.004]
7. 3) catalysts. Journal of Catalysis, 267(1): 24-29. [doi:10.1016/j.jcat.2009.07.009]
8. Behrens, M., Kiner, S., Girsgdies, F., Kasatkin, I., Hermer-schmitdt, F., Mette, K., Ruland, H., Muhler, M., Schlögl, R., 2011. Knowledge-based development of a nitrate-free synthesis route for Cu/ZnO methanol synthesis catalysts via formate precursors. Chemical Communications, 47(6): 1701-1703. [doi:10.1039/C0CC04933F]
9. Boldyrev, V.V., Tkácová, K., 2000. Mechanochemistry of solids: past, present, and prospects. Journal of Materials Synthesis and Processing, 8(3-4):121-132. [doi:10.1023/A:1011347706721]
10. Castricum, H.L., Bakker, H., Poels, E.K., 2001. Oxidation and reduction in copper/zinc oxides by mechanical milling. Materials Science and Engineering: A, 304-306:418-423. [doi:10.1016/S0921-5093(00)01485-4]
11. Choi, Y., Futagami, K., Fujitani, T., Nakamura, J., 2001. The role of ZnO in Cu/ZnO methanol synthesis catalysts\morphology effect or active site model. Applied Catalysis A: General, 208(1-2):163-167. [doi:10.1016/S0926-860X (00)00712-2]
12. Fan, J.C., Chen, C.Q., Zhao, J., Huang, W., Xie, K.C., 2010. Effect of surfactant on structure and performance of catalysts for DME synthesis in slurry bed. Fuel Processing Technology, 91(4):414-418. [doi:10.1016/j.fuproc.2009. 05.005]
13. Fei, J.H., Hou, Z.Y., Zhu, B., Lou, H., Zheng, X.M., 2006. Synthesis of dimethyl ether (DME) on modified HY zeolite and modified HY zeolite-supported Cu-Mn-Zn catalysts. Applied Catalysis A: General, 304:49-54. [doi:10.1016/j.apcata.2006.02.019]
14. Fumo, D.A., Morelli, M.R., Segadães, A.M., 1996. Combustion synthesis of calcium aluminates. Materials Research Bulletin, 31(10):1243-1255. [doi:10.1016/0025-5408(96) 00112-2]
15. Gao, Z.H., Huang, W., Yin, L.H., Xie, K.C., 2009. Liquid-phase preparation of catalysts used in slurry reactors to synthesize dimethyl ether from syngas: effect of heat-treatment atmosphere. Fuel Processing Technology, 90(12):1442-1446. [doi:10.1016/j.fuproc.2009.06. 022]
16. Gervasini, A., Bennici, S., 2005. Dispersion and surface states of copper catalysts by temperature-programmed-reduction of oxidized surfaces (s-TPR). Applied Catalysis A: General, 281(1-2):199-205. [doi:10.1016/j.apcata. 2004.11.030]
17. Grunwaldt, J.D., Molenbroek, A.M., Topsoe, N.Y., Topsoe, H., Clausen, B.C., 2000. In situ investigations of structural changes in Cu/ZnO catalysts. Journal of Catalysis, 194(2): 452-460. [doi:10.1006/jcat.2000.2930]
18. Gu, H., Zhu, Y.F., Li, L.Q., 2009. Hydrogen storage properties of Mg-Ni-Cu prepared by hydriding combustion synthesis and mechanical milling (HCSDMM). International Journal of Hydrogen Energy, 34(6):2654-2660. [doi:10. 1016/j.ijhydene.2009.01.068]
19. Gunter, M.M., Ressler, T., Jentoft, R.E., Bems, B., 2001. Redox behavior of copper oxide/zinc oxide catalysts in the steam reforming of methanol studied by in situ X-ray diffraction and absorption spectroscopy. Journal of Catalysis, 203(1):133-149. [doi:10.1006/jcat.2001.3322]
20. 2 hydrogenation. Journal of Catalysis, 271(2):178-185. [doi:10.1016/j.jcat. 2010.01.009]
21. Haynes, W.M., Lide, D.R., 2011. CRC Handbook of Chemistry and Physics. Chemical Rubber Co., Cleveland, US, p.44-101.
22. 3 catalysts prepared by a novel gel-network-coprecipitation method. Catalysis Letters, 82(1-2):37-44. [doi:10.1023/A:1020 531822590]
23. Jin, D.F., Zhu, B., Hou, Z.Y., Fei, J.H., Lou, H., Zheng, X.M., 2007. Dimethyl ether synthesis via methanol and syngas over rare earth metals modified zeolite Y and dual Cu-Mn-Zn catalysts. Fuel, 86(17-18):2707-2713. [doi:10. 1016/j.fuel.2007.03.011]
24. 3 bifunctional catalyst. Energy Fuels, 24(2):804-810. [doi:10.1021/ef901133z]
25. 2. Industrial & Engineering Chemistry Research, 42(25):6518-6530. [doi:10.1021/ie020979s]
26. Liu, X.Y., Wang, A.Q., Li, L., Zhang, T., Mou, C.Y., Lee, J.F., 2011. Structural changes of Au-Cu bimetallic catalysts in CO oxidation: in situ XRD, EPR, XANES, and FT-IR characterizations. Journal of Catalysis, 278(2):288-296. [doi:10.1016/j.jcat.2010.12.016]
27. Mao, D.S., Yang, W.M., Xia, J.C., Zhang, B., Song, Q.Y., Chen, Q.L., 2005. Highly effective hybrid catalyst for the direct synthesis of dimethyl ether from syngas with magnesium oxide-modified HZSM-5 as a dehydration component. Journal of Catalysis, 230(1):140-149. [doi:10.1016/j.jcat. 2004.12.007]
28. Qi, G.X., Zheng, X.M., Fei, J.H., Hou, Z.Y., 2001. A novel catalyst for DME synthesis from CO hydrogenation: activity, structure and surface properties. Journal of Molecular Catalysis A: Chemical, 176(1-2):195-203. [doi:10.1016/S1381-1169(01)00257-6]
29. Reddy, A.J., Kokila, M.K., Nagabhushana, H., Chakradhar, R.P.S., Shivakumara, C., Rao, J.L., Nagabhushana, B.M., 2011. Structural, optical and EPR studies on ZnO:Cu nanopowder prepared via low temperature solution combustion synthesis. Journal of Alloys and Compounds, 509(17):5349-5355. [doi:10.1016/j.jallcom.2011.02.043]
30. Reubroycharoen, P., Vitidsant, T., Yoneyama, Y., Tsubaki, N., 2004. Development of a new low-temperature methanol synthesis process. Catalysis Today, 89(4):447-454. [doi:10.1016/j.cattod.2004.01.006]
31. Ribeiro, N.F.P., Souza, M.M.V.M., Schmal, M., 2008. Combustion synthesis of copper catalysts for selective CO oxidation. Journal of Power Sources, 179(1):329-334. [doi:10.1016/j.jpowsour.2007.12.096]
32. Semelsberger, T.A., Borup, R.L., Greene, H.L., 2006. Dimethyl ether (DME) as an alternative fuel. Journal of Power Sources, 156(2):497-511. [doi:10.1016/j.jpowsour.2005. 05.082]
33. Teng, L.H., 2008. Attrition resistant catalyst for dimethyl ether synthesis in fluidized-bed reactor. Journal of Zhejiang University-SCIENCE A, 9(9):1288-1295. [doi:10.1631/jzus.A0820155]
34. 2 catalysts prepared by high-energy mechanical milling. Journal of Catalysis, 169(2):490-502. [doi:10.1006/jcat.1997.1705]
35. 3: the role of modifier. Journal of Molecular Catalysis A: Chemical, 302(1-2):20-27. [doi:10.1016/j.molcata.2008.11. 038]
36. 2O on Cu-based catalyst in one-step slurry phase dimethyl ether synthesis. Fuel Processing Technology, 90(3):446-451. [doi:10.1016/j.fuproc. 2008.11.007]
37. Wang, D.Y., Zhou, J., Liu, G.Z., 2009. The microstructure and photoluminescence of Cu-doped ZnO nano-crystal thin films prepared by sol-gel method. Journal of Alloys and Compounds, 487(1-2):545-549. [doi:10.1016/j. jallcom. 2009.08.011]
38. Wang, L.C., Liu, Y.M., Chen, M., Cao, Y., He, H.Y., Wu, G.S., Dai, W.L., Fan, K.N., 2007, Production of hydrogen by steam reforming of methanol over Cu/ZnO catalysts prepared via a practical soft reactive grinding route based on dry oxalate-precursor synthesis. Journal of Catalysis, 246(1):193-204. [doi:10.1016/j.jcat.2006.12.006]
39. Wang, L.L., Ding, W., Liu, Y.W., Fang, W.P., Yang, Y.Q., 2010. Effect of preparation methods of aluminum emulsions on catalytic on catalytic performance of copper-based catalysts for methanol synthesis from syngas. Journal of Natural Gas Chemistry, 19(5):487-492. [doi:10.1016/S1003-9953(09)60105-5]
40. Wen, H., Liu, Y.C., Wei, M.R., 2005. Multidimensional modeling of dimethyl ether (DME) spray combustion in DI diesel engine. Journal of Zhejiang University-SCIENCE A, 6(4):276-282. [doi:10.1631/jzus.2005.A0276]
41. 3 capsule catalyst for one-step controlled synthesis. Journal of the American Chemical Society, 132(23):8129-8136. [doi:10.1021/ja101882a]
42. 2. Fuel, 87(4-5): 443-450. [doi:10.1016/j.fuel.2007.06.020]
43. Yuan, Z.L., Wang, L.N., Wang, J.H., Xia, S.X., Chen, P., Hou, Z.Y., Zheng, X.M., 2011. Hydrogenolysis of glycerol over homogenously dispersed copper on solid base catalysts. Applied Catalysis B: Environmental, 101(3-4): 431-440. [doi:10.1016/j.apcatb.2010.10.013]
44. Zhang, J.C., Zhang, H.B., Yang, X.Y., Huang, Z., Cao, W.L., 2011. Study on the deactivation and regeneration of the ZSM-5 catalyst used in methanol to olefins. Journal of Natural Gas Chemistry, 20(3):266-270. [doi:10.1016/S1003- 9953(10)60183-1]
45. Zhang, J.R., Gao, L., 2004. Antimony-doped tin oxide nano-crystallites prepared by a combustion process. Materials Letters, 58(22-23):2730-2734. [doi:10.1016/j.matlet.2004. 01.041]
46. 3 catalyst for methanol synthesis: preparation and catalytic properties. Applied Catalysis A: General, 158(1-2):105-120. [doi:10.1016/S0926-860X(96) 00362-6]
47. 3. Energy Conversion and Management, 47(18-19):3360-3367. [doi:10.1016/j.enconman.2006.01.010]