Speciation of heavy metals in River Rhine

Water Research

Volumn 47, Issue 1, 2013, Pages 363-372

  Vega, Flora A ^a,b   Weng, Liping ^a  

^a WAGENINGEN UNIVERSITY   (Netherlands)

^b UNIVERSITY OF VIGO   (Spain)

Author keywords

Donnan membrane technique; Field flow fractionation; Free metal ion; Metal complexation; Nanoparticles; Speciation modeling

Indexed keywords

CHEMICAL SPECIATION; COPPER; IRON COMPOUNDS; LEAD COMPOUNDS; LIQUID CHROMATOGRAPHY; METAL COMPLEXES; METAL IONS; METAL NANOPARTICLES; METAL RECOVERY; RIVERS;

DONNAN MEMBRANE TECHNIQUE; FIELD FLOW FRACTIONATION; FREE IONS; FREE METAL ION; ION CONCENTRATIONS; IONS DISTRIBUTION; METAL COMPLEXATION; METAL CONCENTRATIONS; RIVER RHINE; SPECIATION MODELING;

HEAVY METALS;

CADMIUM; COPPER; EDETIC ACID; LEAD; NICKEL; ZINC;

ADSORPTION; CATION; COMPLEXATION; CONCENTRATION (COMPOSITION); COPPER; EDTA; FRACTIONATION; HEAVY METAL; IRON HYDROXIDE; LEAD; MEMBRANE; PARTICLE SIZE; RIVER WATER; SPECIATION (CHEMISTRY); WATER CHEMISTRY;

ADSORPTION; ARTICLE; COMPLEX FORMATION; CONCENTRATION (PARAMETERS); FIELD FLOW FRACTIONATION; PARTICLE SIZE; PRIORITY JOURNAL; RIVER; SPECIES DIFFERENTIATION;

RHINE RIVER;

EID: 84870053388     PISSN: 00431354     EISSN: 18792448     Source Type: Journal    
DOI: 10.1016/j.watres.2012.10.012     Document Type: Article

References (37)

1. Baken S., Degryse F., Verheyen L., Merckx R., Smolders E. Metal complexation properties of freshwater dissolved organic matter are explained by its aromaticity and by anthropogenic ligands. Environmental Science and Technology. 2011, 45:2584-2590.
2. Balistrieri L.S., Blank R.G. Dissolved and labile concentrations of Cd, Cu, Pb, and Zn in the South Fork Coeur d'Alene River, Idaho: comparisons among chemical equilibrium models and implications for biotic ligand models. Applied Geochemistry 2008, 23:3355-3371.
3. Bryan S.E., Tipping E., Hamilton-Taylor J. Comparison of measured and modelled copper binding by natural organic matter in freshwaters. Comparative Biochemistry and Physiology Part C: Pharmacology, Toxicology and Endocrinology 2002, 133:37-49.
4. Callander I.J., Barford J.P. Precipitation, chelation, and the availability of metals as nutrients in anaerobic-digestion. 1. Methodology. Biotechnology. Bioengineering 1983, 25:1947-1957.
5. Campbell P.G.C., Errecalde O., Fortin C., Hiriart-Baer W.R., Vigneault B. Metal bioavailability to phytoplankton - applicability of the biotic ligand model. Comparative Biochemistry and Physiology Part C: Pharmacology, Toxicology and Endocrinology 2002, 133:189-206.
6. Cheng T., De Schamphelaere K., Lofts S., Janssen C., Allen H.E. Measurement and computation of zinc binding to natural dissolved organic matter in European surface waters. Analytica Chimica Acta 2005, 542:230-239.
7. 2+ concentration in synthetic and natural samples with AGNES (Absence of Gradients and Nernstian equilibrium stripping) and DMT (Donnan membrane technique). Science of the Total Environment 2012, 421-422:238-244.
8. Cox J.A., Slonawska K., Gatchell D.K., Hiebert A.G. Metal speciation by Donnan dialysis. Analytica Chemica. 1984, 56:650-653.
9. Dzombak D.A., Morel F.M.M. Surface Complexation Modeling: Hydrous Ferric Oxide 1990, Wiley, New York.
10. Guthrie J.W., Hassan N.M., Salam M.S.A., Fasfous, Murimboh C.A., Murimboh J., Chakrabarti C.L., Gregoire D.C. Complexation of Ni, Cu, Zn, and Cd by DOC in some metal-impacted freshwater lakes: a comparison of approaches using electrochemical determination of free-metal-ion and labile complexes and a computer speciation model, WHAM V and VI. Analytica Chimica Acta 2005, 528:205-218.
11. Hiemstra T., Van Riemsdijk W.H. Biogeochemical speciation of Fe in ocean water. Marchem Chemica 2006, 102:181-197.
12. Kalis E.J.J., Weng L.P., Dousma F., Temminghoff E.J.M., Van Riemsdijk W.H. Measuring free metal ion concentrations in situ in natural waters using the Donnan membrane technique. Environmental Science and Technology 2006, 40:955-961.
13. Keizer M.G., Van Riemsdijk W.H. ECOSAT: Equilibrium Calculation of Speciation and Transport 1994, Agricultural University of Wageningen, Wageningen.
14. Kinniburgh D.G., van Riemsdijk W.H., Koopal L.K., Borkovec M., Benedetti M.F., Avena M.J. Ion binding to natural organic matter: competition, heterogeneity, stoichiometry and thermodynamic consistency. Colloids and Surfaces A: Physicochemical and Engineering Aspects 1999, 151:147-166.
15. Litzen A. Separation speed, retention, and dispensing on in asymmetrical flow Field-Flow Fractionation as functions of channel dimensions and flow-rates. Analytic Chemica. 1993, 65:461-470.
16. Liu X.W., Millero F.J. The solubility of iron hydroxide in sodium chloride solutions. Geochimica et Cosmochimica Acta 1999, 63:3487-3497.
17. Liu X.W., Millero F.J. The solubility of iron in seawater. Marchem Chemica 2002, 77:43-54.
18. Lofts S., Tipping E. Solid-solution metal partitioning in the Humber rivers: application of WHAM and SCAMP. Science of the Total Environment 2000, 251:381-399.
19. Lofts S., Tipping E. Assessing WHAM/Model VII against field measurements of free metal ion concentrations: model performance and the role of uncertainty in parameters and inputs. Environment Chemica 2011, 8:501-516.
20. Lofts S., Tipping E., Hamilton-Taylor J. The chemical speciation of Fe(III) in freshwaters. Aquat Geochem 2008, 14:337-358.
21. Lyven B., Hassellov M., Haraldsson C., Turner D.R. Optimisation of on-channel preconcentration in flow field-flow fractionation for the determination of size distributions of low molecular weight colloidal material in natural waters. Analytica Chimica Acta 1997, 357:187-196.
22. Lyven B., Hassellov M., Turner D.R., Haraldsson C., Andersson K. Competition between iron- and carbon-based colloidal carriers for trace metals in a freshwater assessed using flow field-flow fractionation coupled to ICPMS. Geochimica et Cosmochimica Acta 2003, 67:3791-3802.
23. Meylan S., Behra R., Sigg L. Influence of metal speciation in natural freshwater on bioaccumulation of copper and zinc in periphyton: a microcosm study. Environmental Science and Technology 2004, 38:3104-3111.
24. Milne C.J., Kinniburgh D.G., Tipping E. Generic NICA-Donnan model parameters for proton binding by humic substances. Environmental Science and Technology 2001, 35:2049-2059.
25. Milne C.J., Kinniburgh D.G., Van Riemsdijk W.H., Tipping E. Generic NICA-Donnan model parameters for metal-ion binding by humic substances. Environmental Science and Technology 2003, 37:958-971.
26. Regelink I.C., Weng L.P., Van Riemsdijk W.H. The contribution of organic and mineral colloidal nanoparticles to element transport in a podzol soi. Applied Geochemistry 2011, 26:S242-S244.
27. RIWA Jaarrapport 2010 De Rijn (Annual Report 2010, Rhine) 2011, RIWA-Rijn, Vereniging van Rivierwaterbedrijven, Amsterdam.
28. Sigg L., Black F., Buffle J., Cao J., Cleven R., Davison W., Galceran J., Gunkel P., Kalis E., Kistler D., Martin M., Noel S., Nur Y., Odzak N., Puy J., Van Riemsdijk W., Temminghoff E., Tercier-Waeber M.L., Toepperwien S., Town R.M., Unsworth E., Warnken K.W., Weng L.P., Xue H.B., Zhang H. Comparison of analytical techniques for dynamic trace metal speciation in natural freshwaters. Environmental Science and Technology 2006, 40:1934-1941.
29. Stolpe B., Guo L.D., Shiller A.M., Hassellov M. Size and composition of colloidal organic matter and trace elements in the Mississippi River, Pearl River and the northern Gulf of Mexico, as characterized by flow field-flow fractionation. Marchem Chemica 2010, 118:119-128.
30. Temminghoff E.J.M., Plette A.C.C., Van Eck R., Van Riemsdijk W.H. Determination of the chemical speciation of trace metals in aqueous systems by the Wageningen Donnan membrane technique. Analytica Chimica Acta 2000, 417:149-157.
31. Unsworth E.R., Warnken K.W., Zhang H., Davison W., Black F., Buffle J., Cao J., Cleven R., Galceran J., Gunkel P., Kalis E., Kistler D., Van Leeuwen H.P., Martin M., Noel S., Nur Y., Odzak N., Puy J., Van Riemsdijk W., Sigg L., Temminghoff E., Tercier-Waeber M.L., Toepperwien S., Town R.M., Weng L.P., Xue H.B. Model predictions of metal speciation in freshwaters compared to measurements by in situ techniques. Environmental Science and Technology 2006, 40:1942-1949.
32. Van Laer L., Smolders E., Degryse F., Janssen C., De Schamphelaere K.A.C. Speciation of nickel in surface waters measured with the Donnan membrane technique. Analytica Chimica Acta 2006, 578:195-202.
33. Van Leeuwen H.P., Buffle J. Chemodynamics of aquatic metal complexes: from small ligands to colloids. Environmental Science and Technology 2009, 43:7175-7183.
34. Weng L., Temminghoff E.J.M., Van Riemsdijk W.H. Determination of the free ion concentration of trace metals in soil solution using a soil column Donnan membrane technique. European Journal Soil Science 2001, 52:629-637.
35. Weng L.P., Van Riemsdijk W.H., Temminghoff E.J.M. Kinetic aspects of Donnan Membrane Technique for measuring free trace cation concentration. Analytica Chemica. 2005, 77:2852-2861.
36. Weng L.P., Van Riemsdijk W.H., Temminghoff E.J.M. Effects of lability of metal complex on free ion measurement using DMT. Environmental Science and Technology 2010, 44:2529-2534.
37. Weng L.P., Vega F.A., Van Riemsdijk W.H. Strategies in the application of the Donnan membrane technique. Environmental Chemistry 2011, 8:466-474.