Counting the number of active centers in MgCl2-supported Ziegler-Natta catalysts by quenching with 2-thiophenecarbonyl chloride and study on the initial kinetics of propylene polymerization

Catalysis Communications

Volumn 30, Issue , 2013, Pages 66-69

  Shen, Xianrong ^a   Hu, Jie ^a   Fu, Zhisheng ^a   Lou, Junqin ^a   Fan, Zhiqiang ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

2 thiophenecarbonyl chloride; Number of active center; Polymerization kinetics; Propylene; Ziegler Natta catalyst

Indexed keywords

2-THIOPHENECARBONYL CHLORIDE; INITIAL KINETICS; INITIAL STAGES; NUMBER OF ACTIVE CENTERS; POLYMER CHAINS; POLYMERIZATION KINETICS; PROPAGATION RATE CONSTANT; PROPYLENE POLYMERIZATION; QUENCHING AGENTS; REACTION SYSTEM; SULFUR CONTENTS; ZIEGLER-NATTA CATALYSTS;

CATALYSTS; CHLORINE COMPOUNDS; POLYMERS; PROPYLENE; QUENCHING; RATE CONSTANTS; SULFUR;

POLYMERIZATION;

EID: 84869884977     PISSN: 15667367     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.catcom.2012.11.001     Document Type: Article

References (31)

1. H.W. Coover, J.E. Guillet, R.L. Combs, and F.B. Joyner Journal of Polymer Science Part A: Polymer Chemistry 4 1996 2583
2. G.D. Bukatov, V.S. Goncharov, and V.A. Zakharov Makromolekulare Chemie 187 1986 1041
3. T. Keii, M. Terano, K. Kimura, and K. Ishii Makromolekulare Chemie, Rapid Communications 8 1987 583
4. M.M. Marques, P.J.T. Tait, J. Mejzlik, and A.R. Dias Journal of Polymer Science Part A: Polymer Chemistry 36 1997 573
5. V.A. Zakharov, G.D. Bukatov, and A.A. Barabanov Macromolecular Symposia 213 2004 19
6. G.D. Bukatov, V.A. Zakharov, and A.A. Barabanov Kinetics and Catalysis 46 2005 166
7. A.K. Yaluma, P.J.T. Tait, and J.C. Chadwick Journal of Polymer Science Part A: Polymer Chemistry 44 2005 1635
8. B.P. Liu, H. Matsuoka, and M. Terano Macromolecular Rapid Communications 22 2001 1
9. Y.V. Kissin Journal of Catalysis 200 2001 232
10. I. Tritto, M.C. Sacchi, and P. Locatelli Makromolekulare Chemie, Rapid Communications 4 1983 623
11. J. Mejzlik, M. Lesna, and J. Majer Makromolekulare Chemie 184 1983 1975
12. J.C.W. Chien, and C.I. Kuo Journal of Polymer Science Part A: Polymer Chemistry 23 1985 731
13. Z.Q. Fan, L.X. Feng, and S.L. Yang Acta Polymerica Sinica (Chinese) 4 1991 503
14. Z.Q. Fan, L.X. Feng, and S.L. Yang Chinese Journal of Polymer Science 9 1991 113
15. Z.Q. Fan, L.X. Feng, and S.L. Yang Journal of Polymer Science Part A: Polymer Chemistry 34 1996 3329
16. L.T. Zhang, Z.S. Fu, and Z.Q. Fan Macromolecular Research 18 2010 696
17. A. Heuvelsland, S. Wichmann, and J. Schellenberg Journal of Applied Polymer Science 106 2007 354
18. M.S. Pimplapure, X.J. Zheng, J. Loos, and G. Weickert Macromolecular Rapid Communications 26 2005 1155
19. M. Skoumal, I. Cejpek, and C.P. Cheng Macromolecular Rapid Communications 26 2005 357
20. Chinese Patent CN 1169845C (2004).
21. H. Adkins, and C. Scanley Journal of the American Chemical Society 73 1951 2854
22. Y. Yu, Z.S. Fu, and Z.Q. Fan Journal of Molecular Catalysis A: Chemical 363-364 2012 134
23. T. Nitta, B.P. Liu, H. Nakatani, and M. Terano Journal of Molecular Catalysis A: Chemical 180 2002 25
24. I.A. Jaber, and G. Fink Journal of Molecular Catalysis A: Chemical 98 1995 135
25. Z.X. Liu, E. Somsook, and C.R. Landis Journal of the American Chemical Society 123 2001 2915
26. Z.X. Liu, E. Somsook, C.B. White, K.A. Rosaaen, and C.R. Landis Journal of the American Chemical Society 123 2001 11193
27. Y.V. Kissin, R.I. Mink, and T.E. Nowlin Journal of Polymer Science Part A: Polymer Chemistry 37 1999 4255
28. Y.V. Kissin, R.I. Mink, T.E. Nowlin, and A.J. Brandolini Topics in Catalysis 7 1999 69
29. T. Taniike, P. Chammingkwan, and M. Terano Catalysis Communications 27 2012 13
30. U. Giannini Makromolekulare Chemie Suppl. 5 1981 216
31. P.J.T. Tait, and S.M. Wang British Polymer Journal 20 1988 499