Cross-linked poly(arylene ether ketone) electrolyte membranes with enhanced proton conduction for fuel cells

International Journal of Hydrogen Energy

Volumn 37, Issue 24, 2012, Pages 19007-19016

  Dang, Hai Son ^a   Kim, Dukjoon ^a  

^a Sungkyunkwan University   (South Korea)

Author keywords

Conductivity; DMFC; Methanol permeability; PEMFC; Poly(arylen ether ketone); Water uptake

Indexed keywords

3-AMINO-1; CROSS-LINKABLE; CROSS-LINKING DEGREE; DISULFONIC ACID; ELECTROLYTE MEMBRANE; HIGH DIMENSIONAL STABILITY; HIGH STRAINS; HOT WATER; LOW METHANOL PERMEABILITY; LOW WATER; METHANOL PERMEABILITY; METHANOL PERMEATION; POLY(ARYLEN ETHER KETONE); POLYARYLENE ETHER KETONES; PROTON CONDUCTION; SULFONATING AGENTS; SULFONATION DEGREE; SULFONIC ACID GROUPS; TEMPERATURE RANGE; WATER UPTAKE;

DIRECT METHANOL FUEL CELLS (DMFC); ELECTRIC CONDUCTIVITY; ETHERS; KETONES; MEMBRANES; METHANOL; ORGANIC COMPOUNDS; PROTON CONDUCTIVITY;

PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC);

EID: 84869751129     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.09.152     Document Type: Article

References (20)

1. M.A. Hickner, H. Ghassemi, Y.S. Kim, B.R. Einsla, and J.E. McGrath Alternative polymer systems for proton exchange membranes (PEMs) Chem Rev 104 2004 4587 4612
2. M.-H. Jeong, K.-S. Lee, and J.-S. Lee Synthesis and characterization of sulfonated poly(arylene ether ketone) copolymers containing crosslinking moiety J Membr Sci 337 2009 145 152
3. X. Shang, S. Fang, and Y. Meng Synthesis and characterization of poly(arylene ether ketone) with sulfonated fluorene pendants for proton exchange membrane J Membr Sci 297 2007 90 97
4. G. Xiao, G. Sun, and D. Yan Synthesis and characterization of novel sulfonated poly(arylene ether ketone)s derived from 4,4′-sulfonyldiphenol Polym Bull 48 2002 309 315
5. X. Shang, S. Tian, L. Kong, and Y. Meng Synthesis and characterization of sulfonated fluorene-containing poly(arylene ether ketone) for proton exchange membrane J Membr Sci 266 2005 94 101
6. H. Lin, C. Zhao, W. Ma, H. Li, and H. Na Layer-by-layer self-assembly of in situ polymerized polypyrrole on sulfonated poly(arylene ether ketone) membrane with extremely low methanol crossover Int J Hydrogen Energy 34 2009 9795 9801
7. Y. Zhang, K. Shao, C. Zhao, G. Zhang, H. Li, and T. Fu Novel sulfonated poly(ether ether ketone) with pendant benzimidazole groups as a proton exchange membrane for direct methanol fuel cells J Power Sources 194 2009 175 181
8. M. Rirukawa, and K. Sanui Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers Prog Polym Sci 25 2000 1463 1502
9. H.-Y. Du, C.-H. Wang, H.-C. Hsu, S.-T. Chang, S.-C. Yen, and L.-C. Chen High performance of catalysts supported by direct grown PTFE-free micro-porous CNT layer in a proton exchange membrane fuel cell J Mater Chem 21 2011 2512 2516
10. S.J. Paddison Proton conduction mechanisms at low degrees of hydration in sulfonic acid-based polymer electrolyte membranes Annu Rev Mater Res 33 2003 289 319
11. S.M.J. Zaidi, S.D. Mikhailenko, G.P. Robertson, M.D. Guiver, and S. Kaliaguine Proton conducting composite membranes from polyether ether ketone and heteropolyacids for fuel cell applications J Membr Sci 173 2000 17 34
12. D.X. Luu, E.B. Cho, O.H. Han, and D. Kim SAXS and NMR analysis for the cast solvent effect on sPEEK membrane properties J Phys Chem B 113 30 2009 10072 10076
13. C.H. Lee, H.B. Park, Y.S. Chung, Y.M. Lee, and B.D. Freeman Water sorption, proton conduction, and methanol permeation properties of sulfonated polyimide membranes cross-linked with N,N-bis(2-hydroxyethyl) -2-aminoethaesulfonic acid (BES) Macromolecules 39 2006 755 764
14. J. Fang, F. Zhai, X. Guo, H. Xu, and K. Okamoto A facile approach for the preparation of cross-linked sulfonated polyimide membranes for fuel cell application J Mater Chem 17 2007 1102 1108
15. S. Zhou, and D. Kim Cross-linked aryl-sulfonated poly(arylene ether ketone) proton exchange membranes for fuel cell Electrochim Acta 63 2012 238 244
16. J.-E. Kim, and D. Kim Pendant-sulfonated poly(arylene ether ketone) (PAEK) membranes cross-linked with a proton conducting reagent for fuel cells J Membr Sci 405-406 2012 176 184
17. S. Zhou, D. Hai, and D. Kim Cross-linked poly(arylene ether ketone) proton exchange membranes with high ion exchange capacity for fuel cells Fuel Cells 12 2012 589 598
18. N.E. Davis, Ding S. Karfeld-Sulzer, and A.E. Barron Synthesis and characterization of a new class of cationic protein polymers for multivalent display and biomaterial applications Biomacromolecules 10 5 2009 1125 1134
19. B.D. Cahan, and J.S. Wainringht AC impedance investigations of proton conduction in Nafion J Electrochem Soc 140 1993 L185 L186
20. M. Liu, P. Wu, Y. Ding, and S. Li Study on diffusion behavior of water in epoxy resins cured by active ester Phys Chem Chem Phys 5 2003 1848 1852