Correlation between (nano)-mechanical and chemical changes occurring during photo-oxidation of filled vulcanised styrene butadiene rubber (SBR)

Polymer Degradation and Stability

Volumn 97, Issue 11, 2012, Pages 2195-2201

  Mertz, Grégory ^a,b   Hassouna, Fatima ^a   Leclère, Philippe ^b   Dahoun, Abdesselam ^c   Toniazzo, Valérie ^a   Ruch, David ^a  

^a CRP Henri Tudor ^*  (Luxembourg)

^b UNIVERSITY OF MONS   (Belgium)

^c INSTITUT JEAN LAMOUR   (France)

Author keywords

Depth profiling; Mechanical properties; Photo oxidation; Styrene butadiene rubber; Vulcanisation

Indexed keywords

ATOMIC FORCE MICROSCOPY; BUTADIENE; CROSSLINKING; DEPTH PROFILING; FOURIER TRANSFORM INFRARED SPECTROSCOPY; IRRADIATION; MECHANICAL PROPERTIES; OXIDATION; RUBBER; RUBBER APPLICATIONS; RUBBER PRODUCTS; STYRENE; TENSILE TESTING; TITANIUM DIOXIDE;

CHEMICAL PROFILES; CROSSLINKING REACTION; DEGREE OF DEFORMATIONS; DYNAMIC MECHANICAL ANALYSIS (DMA); MECHANICAL BEHAVIOUR; PHYSICOCHEMICAL PROPERTY; STYRENE BUTADIENE RUBBER; VULCANISATION;

DYNAMIC MECHANICAL ANALYSIS;

EID: 84869203123     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2012.08.008     Document Type: Article

References (21)

1. White Jr. Polymer ageing: physics, chemistry or engineering? Time to reflect. C R Chim 2006;9(11):1396-408.
2. Piton M, Rivaton A. Photooxidation of polybutadiene at long wavelengths (l > 300 nm). Polym Deg Stab 1996;53(3):343-59.
3. Adam C, Lacoste J, Lemaire J. Photo-oxidation of elastomeric materials. Part 1dPhoto-oxidation of polybutadienes. Polym Deg Stab 1989;24(3):185-200.
4. Adam C, Lacoste J, Lemaire J. Photo-oxidation of elastomeric materials: Part IIdphoto-oxidation of styrene-butadiene copolymer. Polym Deg Stab 1989; 26(3):269-84.
5. Bussière PO, Gardette JL, Lacoste J, Baba M. Characterization of photodegradation of polybutadiene and polyisoprene: chronology of crosslinking and chain-scission. Polym Deg Stab 2005;88(2):182-8.
6. Li GY, Koening JL. A review of rubber oxidation. Rubb Chem Technol 2005; 78(3):355-90.
7. Delor F, Barrois-Oudin N, Duteurtre X, Cardinet C, Lemaire J, Lacoste J. Oxidation of rubbers analysed by HATR/IR spectroscopy. Polym Deg Stab 1998;62(2):395-401.
8. Bottino FA, Cinquegrani AR, Di Pasquale G, Leonardi L, Pollicino A. Chemical modifications, mechanical properties and surface photo-oxidation of films of polystyren (PS). Polym Test 2004;23(4):405-11.
9. Jubete E, Liauw CM, Jacobson K, Allen NS. Degradation of carboxylated styrene butadiene rubber based water born paints. Part 1: effect of talc filler and titania pigment on UV stability. Polym Deg Stab 2007;92(8):1611-21.
10. Celina M, Wise J, Ottesen DK, Gillen KT, Clough RL. Oxidation profiles of thermally aged nitrile rubber. Polym Deg Stab 1998;60(2):493-504.
11. Mailhot B, Bussière PO, Rivaton A, Morlat-Thérias S, Gardette JL. Depth profiling by AFM nanoindentations and micro-FTIR spectroscopy for the study of polymer ageing. Macromol Rapid Commun 2004;25(2):436-40.
12. Kumar A, Commereuc S, Gonon L, Verney V. Depth-profile of photo-oxidation of polyoctenamer. Polym Deg Stab 2002;75(3):509-16.
13. Schön P, Bagdi K, Molnar K, Markus P, Pukanszky B, Vancso GJ. Quantitative mapping of elastic moduli at the nanoscale in phase separated polyurethanes by AFM. Eur Polym J 2011;47(4):692-8.
14. Mertz G, Hassouna F, Toniazzo V, Dahoun A, Ruch D. Effect of coated rutile and disazopyrazolone dye additives on unvulcanised SBR during photo-ageing. J Eng Mat Tech 2012;134(1):0109031-7.
15. Schnabel W, Levchik GF, Wilkie CA, Jiang DD, Levchik SV. Thermal degradation of polystyrene, poly(1, 4-butadiene) and copolymers of styrene and 1, 4-butadiene irradiated under air or argon with 60Co-g-rays. Polym Degrad Stab 1999; 63(3):365-75.
16. Guzzo M, De Paoli MA. The photo-oxidation of EPDM rubber: Part Vdmechanical properties degradation of vulcanized filled samples. Polym Degrad Stab 1992;38(1):41-5.
17. Perera MCS, Ishiaku US, Ishak ZAM. Thermal degradation of PVC/NBR and PVC/ENR50 binary blends and PVC/ENR50/NBR ternary blends studied by DMA and solid state NMR. Polym Deg and Stab 2000;68(3):393-402.
18. Haward RN, editor. The physics of glassy polymers. New York: Wiley; 1973.
19. Chailan JF, Boiteux G, Chauchard J, Pinel B, Seytre G. Viscoelastic and dielectric study of thermally aged ethylene-propylene diene monomer (EPDM) compounds. Polym Deg Stab 1995;47(3):397-403.
20. Delor F, Lacoste J, Barrois-oudin N, Cardinet C, Lemaire J. Photo-, thermal and natural ageing of ethylene-propylene-diene monomer (EPDM) rubber used in automotive applications. Influence of carbon black, crosslinking and stabilizing agents. Polym Deg Stab 2000;67(3):469-77.
21. Poh BT, Ismail H, Tan KS. Effect of filler loading on tensile and tear properties of SMR L/ENR 25 and SMR L/SBR blends cured via a semi-efficient vulcanization system. Polym Test 2002;21(7):801-6.