Acid activated montmorillonite as catalysts in methyl esterification reactions of lauric acid

Journal of Oleo Science

Volumn 61, Issue 9, 2012, Pages 497-504

  Zatta, Leandro ^a   Ramos, Luiz Pereira ^a   Wypych, Fernando ^a  

^a FEDERAL UNIVERSITY OF PARANÁ   (Brazil)

Author keywords

Acid activation; Esterification; Lauric acid; Methyl esters; Montmorillonite

Indexed keywords

ACID ACTIVATED CLAY; ACID ACTIVATION; ACID SITE; CLAY CATALYSTS; COST EFFECTIVE; ENVIRONMENTAL-FRIENDLY; FREE FATTY ACID; GOOD CORRELATIONS; LAURATE; LAURIC ACID; METHYL ESTERIFICATION; METHYL ESTERS; MOLAR RATIO; NON-CORROSIVE; RESULTING MATERIALS; TEXTURAL PROPERTIES; THERMAL CONVERSION; UNTREATED CLAY;

CATALYST ACTIVITY; CLAY MINERALS; ESTERIFICATION; ESTERS; PHOSPHORIC ACID; SATURATED FATTY ACIDS; SULFURIC ACID;

NITRIC ACID;

BENTONITE; LAURIC ACID; LAURIC ACID DERIVATIVE; NITRIC ACID; PHOSPHORIC ACID; SULFURIC ACID;

ARTICLE; CATALYSIS; CHEMISTRY; SYNTHESIS;

BENTONITE; CATALYSIS; LAURIC ACIDS; NITRIC ACID; PHOSPHORIC ACIDS; SULFURIC ACIDS;

EID: 84869016712     PISSN: 13458957     EISSN: 13473352     Source Type: Journal    
DOI: 10.5650/jos.61.497     Document Type: Article

References (18)

1. Pisarello, M. L.; Dalla Costa, B.; Mendow, G.; Querini, C. A. Esterification with ethanol to produce biodiesel from high acidity raw materials: Kinetic studies and analysis of secondary reactions. Fuel Process. Technol. 91, 1005-1014(2010).
2. 2supported metaloxide catalysts for brown grease esterification and sulfur removal. Bioresour. Technol. 102, 2380-2386(2011).
3. Zatta, L.; Gardolinski, J. E. F. d. C.; Wypych, F. Raw halloysite as reusable heterogeneous catalyst for esterification of lauric acid. Appl. Clay Sci. 51, 165-169 (2011).
4. Vijayakumar, B.; Nagendrappa, G.; Jai Prakash, B. Acid Activated Indian Bentonite, an Efficient Catalyst for Esterification of Carboxylic Acids. Catal. Lett. 128, 183-189(2009).
5. Neji, S. B.; Trabelsi, M.; Frikha, M. H. Esterification of Fatty Acids with Short-Chain Alcohols over Commercial Acid Clays in a Semi-Continuous Reactor. Energies 2, 1107-1117(2009).
6. Neji, S. B.; Trabelsi, M.; Frikha, M. H. Esterification of Fatty Acid over Tunisian Acid Activated Clay: Kinetic Study. J. Oleo Sci. 60, 293-299(2011).
7. 4treated metakaolinite of a natural kaolinite as Friedel-Crafts alkylation catalyst. Catal. Today 49, 321-326 (1999).
8. Lenarda, M.; Storaro, L.; Talon, A.; Moretti, E.; Riello, P. Solid acid catalysts from clays: Preparation of mesoporous catalysts by chemical activation of metakaolin under acid conditions. J. Colloid Interface Sci. 311, 537-543(2007).
9. Hart, M. P.; Brown, D. R. Surface acidities and catalytic activities of acid-activated clays. J. Mol. Catal. A: Chem. 212, 315-321(2004).
10. Mermut, A. R.; Cano, A. F. Baseline studies of the clay minerals society source clays: Chemical analyses of major elements. Clays Clay Miner. 49, 381-386 (2001).
11. thChampaign, (1998)
12. Cordeiro, C. S., Compostos lamelares como catalisadores heterogeneos em reações de(trans) esterificação(m) etílica, Thesis in Química 2009, Universidade Federal do Paraná: Curitiba-Brazil.
13. Reddy, C. R.; Bhat, Y. S.; Nagendrappa, G.; Jai Prakash, B. S. Brönsted and Lewis acidity of modified montmorillonite clay catalysts determined by FT-IR spectroscopy. Catal. Today 141, 157-160(2009).
14. Viani, A.; Gualtieri, A. F.; Artioli, G. The nature of disorder in montmorillonite by simulation of X-ray powder patterns. Am. Mineral. 87, 966-975(2002).
15. Chipera, S. J.; Bish, D. L. Baseline studies of the clay minerals society source clays: Powder X-ray diffraction analyses. Clays Clay Miner. 49, 398-409(2001).
16. Wilson, K.; Clark, J. H. Solid Acids and Their Use as Environmentally Friendly Catalysts in Organic Synthesis. Pure Appl. Chem. 72, 1313-1319(2001).
17. Madejova, J.; Komadel, P. Baseline studies of the clay minerals society source clays: Infrared methods. Clays Clay Miner. 49, 410-432(2001).
18. Okada, K.; Shimai, A.; Takei, T.; Hayashi, S.; Yasumori, A.; MacKenzie, K. J. D. Preparation of microporous silica from metakaolinite by selective leaching method. Microporous and Mesoporous Mater. 21, 289-296 (1998).