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Volumn 2, Issue 10, 2012, Pages 2194-2198

Continuous partial hydrogenation reactions by Pd@unconventional bimodal porous titania monolith catalysts

Author keywords

Catalysis; Flow reaction; Hydrogenation; Monolith; Pd nanoparticles

Indexed keywords

CONTINUOUS-FLOW; DUAL POROSITY; FLOW REACTIONS; HYDROGENATION REACTIONS; MONOLITH; MONOLITH CATALYST; PARTIAL HYDROGENATION; PD NANO PARTICLE; POROUS TITANIA; TITANIA;

EID: 84868596640     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs3005902     Document Type: Article
Times cited : (62)

References (52)
  • 6
    • 79953702549 scopus 로고    scopus 로고
    • Microfluidic and minifluidic reactors are defined as devices in which chemical reactions take place in channels sized between ca. 10- 500 μm and 0.1-1 mm, respectively
    • Microfluidic and minifluidic reactors are defined as devices in which chemical reactions take place in channels sized between ca. 10- 500 μm and 0.1-1 mm, respectively. See: Wegner, J.; Ceylan, S.; Kirschning, A. Chem. Commun. 2011, 47, 4583.
    • (2011) Chem. Commun. , vol.47 , pp. 4583
    • Wegner, J.1    Ceylan, S.2    Kirschning, A.3
  • 37
    • 0004154804 scopus 로고
    • The Accepted Definition Of STY Is "the number of molecules of a specified product made per unit volume of reactor per unit time", for example Springer: London, U.K
    • The accepted definition of STY is "the number of molecules of a specified product made per unit volume of reactor per unit time". See, for example, Pletcher, D.; Walsh, F. Industrial Electrochemistry; Springer: London, U.K., 1990; p 83.
    • (1990) Industrial Electrochemistry , pp. 83
    • Pletcher, D.1    Walsh, F.2
  • 38
    • 63749108261 scopus 로고    scopus 로고
    • The hydrogenation of 1 under continuous flow was reported using 4-8 μL volume devices providing 2 order magnitude higher STY and lower TOF compared to our system, which is usual for small reactors (2%Pd@Al2O3) and references therein
    • The hydrogenation of 1 under continuous flow was reported using 4-8 μL volume devices providing 2 order magnitude higher STY and lower TOF compared to our system, which is usual for small reactors; see Trachsel, F.; Tidona, B.; Desportes, S.; von Rohr, P. R. J. Supercrit. Fluid. 2009, 48, 146 (2%Pd@Al2O3) and references therein.
    • (2009) J. Supercrit. Fluid. , vol.48 , pp. 146
    • Trachsel, F.1    Tidona, B.2    Desportes, S.3    Von Rohr, P.R.4
  • 39
    • 0032355053 scopus 로고    scopus 로고
    • A 5 mL volume reactor (5%Pd@Deloxan) was reported to hydrogenate 1 with high conversion at 340 °C.
    • A 5 mL volume reactor (5%Pd@Deloxan) was reported to hydrogenate 1 with high conversion at 340 °C. See: Hitzler, M. G.; Smail, F. R.; Ross, S. K.; Poliakoff, M. Org. Process. Res. Dev. 1998, 2, 137.
    • (1998) Org. Process. Res. Dev. , vol.2 , pp. 137
    • Hitzler, M.G.1    Smail, F.R.2    Ross, S.K.3    Poliakoff, M.4
  • 40
    • 84868528235 scopus 로고    scopus 로고
    • Our monolithic design also compares favorably with the Ni/ TiO2 packed-system previously described which provided lower activity under higher temperature (170 °C) and H2 pressure (30 mL/min). See ref 35
    • Our monolithic design also compares favorably with the Ni/ TiO2 packed-system previously described which provided lower activity under higher temperature (170 °C) and H2 pressure (30 mL/min). See ref 35.
  • 43
    • 80054741820 scopus 로고    scopus 로고
    • SMSI: enhancement of the catalytic activity of a metal due to an oxide support. See, for example
    • SMSI: enhancement of the catalytic activity of a metal due to an oxide support. See, for example, Lewera, A.; Timperman, L.; Roguska, A.; Alonso-Vante, N. J. Phys. Chem. C 2011, 115, 20153.
    • (2011) J. Phys. Chem. C , vol.115 , pp. 20153
    • Lewera, A.1    Timperman, L.2    Roguska, A.3    Alonso-Vante, N.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.