Partial oxidation of ethanol to acetaldehyde over LaMnO3-based perovskites: A kinetic study

Industrial and Engineering Chemistry Research

Volumn 52, Issue 1, 2013, Pages 37-42

  Jiang, Bing Shiun ^a   Chang, Ray ^a   Lin, Yu Chuan ^a  

^a YUAN ZE UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFERENTIAL METHODS; ELEMENTARY REACTION; FIXED-BED REACTORS; IN-DEPTH UNDERSTANDING; KINETIC ANALYSIS; KINETIC STUDY; LANGMUIR-HINSHELWOOD-HOUGEN-WATSON; MARS-VAN KREVELEN; OXYGEN ADSORPTION; PARTIAL OXIDATION OF ETHANOL; PARTIAL OXIDATIONS; PREEXPONENTIAL FACTOR; RATE EQUATIONS; RATE LIMITING; REDOX CYCLES; WATER DESORPTION;

ACETALDEHYDE; ACTIVATION ENERGY; CHEMICAL ANALYSIS; CHEMICAL REACTORS; CHEMISORPTION; DESORPTION; GAS ADSORPTION; OXIDATION; OXYGEN; PALLADIUM; PEROVSKITE; REDOX REACTIONS; SOL-GEL PROCESS; SURFACE REACTIONS;

ETHANOL;

EID: 84868526860     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie300348u     Document Type: Article

References (35)

1. Peña, M. A.; Fierro, J. L. G. Chemical structures and performance of perovskite oxides Chem. Rev. 2001, 101, 1981
2. Nishihata, Y.; Mizuki, J.; Akao, T.; Tanaka, H.; Uenishi, M.; Kimura, M.; Okamoto, T.; Hamada, N. Self-regeneration of a Pd-perovskite catalyst for automotive emissions control Nature 2002, 418, 164
3. Li, C.-L.; Wang, C.-L.; Lin, Y.-C. Pd-integrated lanthanum-transition metal perovskites for methanol partial oxidation Catal. Today 2011, 174, 135
4. 3 perovskites Appl. Catal., B 2011, 107, 284
5. 2 catalysts prepared by grafting Ind. Eng. Chem. Res. 2004, 43, 1623
6. Kilos, B.; Bell, A. T.; Iglesia, E. Mechanism and site requirements for ethanol oxidation on vanadium oxide domains J. Phys. Chem. C 2009, 113, 2830
7. Mars, P.; van Krevelen, D. W. Oxidations carried out by means of vanadium oxide catalysts Chem. Eng. Sci. 1954, 3, 41
8. Legendre, M.; Cornet, D. Catalytic oxidation of ethanol over tantalum oxide J. Catal. 1972, 25, 194
9. Tsuruya, S.; Tsukamoto, M.; Watanabe, M.; Masai, M. Ethanol oxidation over Y-type zeolite ion-exchanged with copper(II) and cobalt(II) ions J. Catal. 1985, 93, 303
10. 2 catalysts and some relations to the structure J. Catal. 1985, 94, 24
11. Oyama, S. T.; Somorjai, G. A. Effect of structure in selective oxide catalysis: oxidation reactions of ethanol and ethane on vanadium oxide J. Phys. Chem. 1990, 94, 5022
12. Zhang, W.; Desikan, A.; Oyama, S. T. Effect of support in ethanol oxidation on molybdenum oxide J. Phys. Chem. 1995, 99, 14468
13. 3 in ethanol oxidation Appl. Catal., A 1996, 136, 191
14. Gomez, M. F.; Arrua, L. A.; Abello, M. C. Kinetic study of partial oxidation of ethanol over VMgO catalyst Ind. Eng. Chem. Res. 1997, 36, 3468
15. 2 Catalysts J. Catal. 1997, 171, 1
16. Idriss, H.; Seebauer, E. G. Reactions of ethanol over metal oxides J. Mol. Catal. A 2000, 152, 201
17. 2 sol-gel mixed oxides J. Mol. Catal. A 2001, 165, 199
18. 2 catalysts obtained by grafting vanadium and titanium alkoxides on silica J. Mol. Catal. A 2003, 204-205, 617
19. Gucbilmez, Y.; Dogu, T.; Balci, S. Ethylene and acetaldehyde production by selective oxidation of ethanol using mesoporous V-MCM-41 catalysts Ind. Eng. Chem. Res. 2006, 45, 3496
20. x catalysts on mesoporous silica: Synthesis, characterization, and catalytic activity in the partial oxidation of ethanol Appl. Catal., A 2006, 300, 109
21. Chimentão, R. J.; Herrera, J. E.; Kwak, J. H.; Medina, F.; Wang, Y.; Peden, C. H. F. Oxidation of ethanol to acetaldehyde over Na-promoted vanadium oxide catalysts Appl. Catal., A 2007, 332, 263
22. 2 as supports Catal. Commun. 2008, 9, 675
23. Jørgensen, B.; Kristensen, S.; Kunov-Kruse, A.; Fehrmann, R.; Christensen, C.; Riisager, A. Gas-phase oxidation of aqueous ethanol by nanoparticle vanadia/anatase catalysts Top. Catal. 2009, 52, 253
24. Najjar, H.; Batis, H. La-Mn perovskite-type oxide prepared by combustion method: Catalytic activity in ethanol oxidation Appl. Catal., A 2010, 383, 192
25. Wachs, I. E.; Briand, L. E.; Jehng, J.-M.; Burcham, L.; Gao, X. Molecular structure and reactivity of the group V metal oxides Catal. Today 2000, 57, 323
26. Weckhuysen, B. M.; Keller, D. E. Chemistry, spectroscopy and the role of supported vanadium oxides in heterogeneous catalysis Catal. Today 2003, 78, 25
27. Friedler, F.; Tarjan, K.; Huang, Y. W.; Fan, L. T. Graph-theoretic approach to process synthesis: axioms and theorems Chem. Eng. Sci. 1992, 47, 1973
28. Friedler, F.; Tarjan, K.; Huang, Y. W.; Fan, L. T. Graph-theoretic approach to process synthesis: Polynomial algorithm for maximal structure generation Comput. Chem. Eng. 1993, 17, 929
29. Fan, L. T.; Bertók, B.; Friedler, F.; Shafie, S. Mechanisms of ammonia-synthesis reaction revisited with the aid of a novel graph-theoretic method for determining candidate mechanisms in deriving the rate law of a catalytic reaction Hung. J. Ind. Chem. 2001, 29, 71
30. Fan, L. T.; Bertók, B.; Friedler, F. A graph-theoretic method to identify candidate mechanisms for deriving the rate law of a catalytic reaction Comput. Chem. 2002, 26, 265
31. Stewart, W. E.; Caracotsios, M.; Sørensen, J. P. Parameter estimation from multiresponse data AIChE J. 1992, 38, 641
32. Li, X.; Iglesia, E. Selective catalytic oxidation of ethanol to acetic acid on dispersed Mo-V-Nb mixed oxides Chem.-Eur. J. 2007, 13, 9324
33. Hougen, O. A.; Watson, K. M. Solid catalysts and reaction rates Ind. Eng. Chem. 1943, 35, 529
34. Dumesic, J. A.; Trevino, A. A.; Milligan, B. A.; Greppi, L. A.; Balse, V. R.; Sarnowski, K. T.; Beall, C. E.; Kataoka, T.; Rudd, D. F. A kinetic modeling approach to the design of catalysts: formulation of a catalyst design advisory program Ind. Eng. Chem. Res. 1987, 26, 1399
35. 5 AIChE J. 1991, 37, 87