Synthesis, characterization and properties of amphiphilic block copolymers of 2-hydroxyethyl methacrylate and polydimethylsiloxane prepared by atom transfer radical polymerization

Polymer Journal

Volumn 44, Issue 11, 2012, Pages 1087-1097

  Bas, Serkan ^a   Soucek, Mark D ^b  

^a UNIVERSITY AT BUFFALO   (United States)

^b University of Akron   (United States)

Author keywords

amphiphilic; ATRP; block copolymers; controlled polymerization; HEMA; polydimethylsiloxane; triblock copolymer

Indexed keywords

2-HYDROXYETHYL METHACRYLATE; AMPHIPHILIC BLOCK COPOLYMERS; AMPHIPHILICS; BLOCK LENGTHS; CONTROLLED POLYMERIZATION; CROSS-LINK DENSITIES; DYNAMIC MECHANICAL PROPERTY; FILM MORPHOLOGY; HEMA; POLY(2-HYDROXYETHYL METHACRYLATE); POLYDISPERSITY INDICES; SELECTIVE SOLVENTS; SELF-ASSEMBLY BEHAVIORS; SIZE AND SIZE DISTRIBUTIONS; SMALL ANGLE X-RAY SCATTERING; VISCOELASTIC PROPERTIES;

ATOM TRANSFER RADICAL POLYMERIZATION; ATOMIC FORCE MICROSCOPY; BLOCK COPOLYMERS; MECHANICAL PROPERTIES; MOLECULAR WEIGHT; MORPHOLOGY; PHASE SEPARATION; PHEMA; POLYDIMETHYLSILOXANE; POLYMERIZATION; TRANSMISSION ELECTRON MICROSCOPY;

SILICONES;

EID: 84868522277     PISSN: 00323896     EISSN: 13490540     Source Type: Journal    
DOI: 10.1038/pj.2012.86     Document Type: Article

References (37)

1. Soni, S. S., Sastry, N. V. & George, J. Dynamic light scattering and viscosity studies on the association behavior of silicone surfactants in aqueous solutions. J. Phys. Chem. B. 107, 5382 (2003).
2. Freij-Larsson, C., Nylander, T., Jannasch, P. & Wesslen, B. Adsorption behaviour of amphiphilic polymers at hydrophobic surfaces: effects on protein adsorption. Biomaterials 17, 2199 (1996).
3. Xu, J., Bohnsack, D. A., Mackay, M. E. & Wooley, K. L. Unusual mechanical performance of amphiphilic crosslinked polymer networks. J. Am. Chem. Soc. 129, 506 (2007).
4. Bruns, N., Scherble, J., Hartmann, L., Thomann, R., Ivan, B., Mulhaupt, R. & Tiller, J. C. Nanophase separated amphiphilic conetwork coatings and membranes. Macromolecules 38, 2431 (2005).
5. Kimerling, A. S. & Bhatia, S. R. Block copolymers as low-VOC coatings for wood: characterization and tannin bleed resistance. Prog. Org. Coat 51, 15 (2004).
6. Amado, E., Augsten, C., Mader, K., Blume, A. & Kressler, J. Amphiphilic water soluble triblock copolymers based on poly(2,3-dihydroxypropyl methacrylate) and poly(propylene oxide): synthesis by atom transfer radical polymerization and micellization in aqueous solutions. Macromolecules 39, 9486 (2006).
7. Yun, J., Faust, R., Szilagyi, L. Sz., Keki, S. & Zsuga, M. Effect of architecture on the micellar properties of amphiphilic block copolymers: comparison of AB linear diblock, A1A2B, and A2B heteroarm star block copolymers. Macromolecules 36, 1717 (2003).
8. Remant Bahadur, K. C., Bhattarai, S. R., Aryal, S, Khil, M. S., Dharmaraj, N. & Kim, H. Y. Novel amphiphilic triblock copolymer based on PPDO, PCL, and PEG: Synthesis, characterization, and aqueous dispersion. Colloids Surf. A: Physicochem. Eng. Aspects 292, 69 (2007).
9. Wang, S. F., Lu, L. C., Gruetzmacher, J. A., Currier, B. L. & Yaszemski, M. J. A biodegradable and cross-linkable multiblock copolymer consisting of poly(propylene fumarate) and poly(e-caprolactone): synthesis, characterization, and physical properties. Macromolecules 38, 7358 (2005).
10. Bae, Y. H., Huh, K. M., Kim, Y. & Park, K. H. Biodegradable amphiphilic multiblock copolymers and their implications for biomedical applications. J. Controlled Release 64, 3 (2000).
11. Chen, Y. H. & Yang, C. P. Coemulsion and electrodeposition properties of mixtures of cationic epoxy resin and cationic acrylic resin containing blocked-isocyanate groups. J. Appl. Polym. Sci 51, 1539 (1994).
12. Pellice, S. A., Fasce, D. P. & Williams, R. Development of a bilayer coating to improve the adhesion between stainless steel and in situ-polymerized poly(methyl methacrylate). J. Appl. Polym. Sci. 105, 2351 (2007).
13. Kucukoglu, E., Acar, I., Iyim, T. B. & Ozgumus, S. A novel type of Si-containing acrylic resins: synthesis, characterization, and film properties. J. Appl. Polym. Sci. 104, 3324 (2007).
14. Hill, R. M. in Encyclopedia of Physical Science and Technology. (ed. Meyers, R. A.). 3rd edn, vol 14, 40 (Academic Press, San Diego, CA, 2002).
15. Lazzari, M., Liu, G. & Lecommandoux, S. Block Copolymers in Nanoscience: Block Copolymers in Nanoscience. 391 (Wiley-VCH, Weinheim, 2006).
16. Muhlebach, A, Gaynor, S. G. & Matyjaszewski, K. Synthesis of amphiphilic block copolymers by atom transfer radical polymerization (ATRP). Macromolecules 31, 6046 (1998).
17. Beers, K. L., Boo, S., Gaynor, S. G. & Matyjaszewski, K. Atom transfer radical polymerization of 2-hydroxyethyl methacrylate. Macromolecules 32, 5772 (1999).
18. Wang, J. S. & Matyjaszewski, K. Controlled/''Living'' radical polymerization. halogen atom transfer radical polymerization promoted by a Cu(I)/Cu(II) redox process. Macromolecules 28, 7901 (1995).
19. Duxin, N., Liu, F., Vali, H. & Eisenberg, A. Cadmium sulphide quantum dots in morphologically tunable triblock copolymer aggregates. J. Am. Chem. Soc. 127, 10063 (2005).
20. Zhang, L., Niu, H., Chen, Y., Liu, H. & Gao, M. Preparation of platinum nanoparticles using star-block copolymer with a carboxylic core. J. Colloid Interface Sci. 298, 177 (2006).
21. Duquesne, E., Habimana, J., Degee, P. & Dubois, P. Synthesis of silicone-methacrylate copolymers by ATRP using a nickel-based supported catalyst. Macromol. Chem. Phys. 207, 1116 (2006).
22. Miller, P. J. & Matyjaszewski, K. Atom transfer radical polymerization of (Meth)acrylates from poly(dimethylsiloxane) macroinitiators. Macromolecules 32, 8760 (1999).
23. Dai, S., Ravi, P., Leong, C. Y., Tam, K. C. & Gan, L. H. Synthesis and aggregation behavior of amphiphilic block copolymers in aqueous solution: Di- and triblock copolymers of poly(ethylene oxide) and poly(ethyl acrylate). Langmuir 20, 1597 (2004).
24. Otsu, T. & Yoshida, M. Role of initiator-transfer agent-terminator (iniferter) in radical polymerizations: Polymer design by organic disulfides as iniferters. Makromol. Chem. Rapid Commun. 3, 127 (1982).
25. Otsu, T., Yoshida, M. & Tazaki, T. A model for living radical polymerization. Makromol. Chem. Rapid Commun. 3, 133 (1982).
26. Matyjaszewski, K., Patten, T. & Xia, J. Controlled/''Living'' radical polymerization. kinetics of the homogeneous atom transfer radical polymerization of styrene. J. Am. Chem. Soc. 119, 674 (1997).
27. Lee, S. C., Chang, Y. K., Yoon, J. S., Kim, C. H., Kwon, I. C., Kim, Y. H. & Jeong, S. Y. Synthesis and micellar characterization of amphiphilic diblock copolymers based on poly(2-ethyl-2-oxazoline) and aliphatic polyesters. Macromolecules 32, 1847 (1999).
28. Yuan, J., Xu, Z., Heng, S. & Feng, L. The aggregation of polystyrene-b-poly(ethylene oxide)-b-polystyrene triblock copolymers in aqueous solution. Eur. Polym. J. 38, 1537 (2002).
29. Dingenouts, N. & Ballauff, M. First stage of film formation by latexes investigated by small-angle X-ray scattering. Langmuir 15, 3283 (1999).
30. Sheth, J. P., Yilgor, E., Erenturk, B., Ozhalici, H., Wilkes, G. L. & Yilgor, I. Structure- property behavior of poly(dimethylsiloxane) based segmented polyurea copolymers modified with poly(propylene oxide). Polymer 46, 8185 (2005).
31. Bendejacq, D., Ponsinet, V., Joanicot, M., Loo, Y.-L. & Register, R. A. Well-ordered microdomain structures in polydisperse poly(styrene) poly(acrylic acid) diblock copolymers from controlled radical polymerization. Macromolecules 35, 6645 (2002).
32. Seitz, M. E., Burghardt, W. R., Faber, K. T. & Shull, K. R. Article self-assembly and stress relaxation in acrylic triblock copolymer gels. Macromolecules 40, 1218 (2007).
33. Caykara, T., Ozyurek, C., Kantoglu, O. & Guven, O. Influence of gel composition on the solubility parameter of poly(2-hydroxyethyl methacrylate-itaconic acid) hydrogels. J. Polym. Sci. Part B Polym. Phys 40, 1995 (2002).
34. Ruzette, A. V., Tence-Girault, S., Leibler, L., Chauvin, F., Bertin, D., Guerret, O. & Gerard, P. Molecular disorder and mesoscopic order in polydisperse acrylic block copolymers prepared by controlled radical polymerization. Macromolecules 39, 5804 (2006).
35. Han, C. D., Baek, D. M., Kim, J. K. & Chu, S. G. Rheological behaviour of block copolymers in the disordered state: effects of molecular weight and block length ratio. Polymer 33, 294 (1992).
36. Wu, N., Zheng, A., Huang, Y. & Liu, H. Morphology of poly(styrene-block-dimethylsiloxane) copolymer films. J. Appl. Polym. Sci. 104, 1010 (2007).
37. Dai, B., Song, M., Hourston, D. J., He, X., Liang, H. & Pan, C. Influence of block lengths and symmetries of block copolymers on phase behavior of polymer A/polymer B/block copolymer ternary blends. Polymer 45, 1019 (2004).