Adsorption of toxic metal ion Cr(VI) from aqueous state by TiO2-MCM-41: Equilibrium and kinetic studies

Journal of Hazardous Materials

Volumn 241-242, Issue , 2012, Pages 395-403

  Parida, Kulamani ^a   Mishra, Krushna Gopal ^b   Dash, Suresh Kumar ^c  

^a CSIR INSTITUTE OF MINERALS AND MATERIALS TECHNOLOGY   (India)

^b KIIT UNIVERSITY   (India)

^c SIKSHA O ANUSANDHAN DEEMED TO BE UNIVERSITY   (India)

Author keywords

Cr(VI) adsorption; Isotherms; Kinetics; Thermodynamic studies; TiO2 MCM 41

Indexed keywords

ADSORPTION ACTIVITY; ADSORPTION CAPACITIES; ADSORPTION PROCESS; CR ADSORPTIONS; DESORPTION STUDY; FOURIER TRANSFORM INFRARED; INTRA-PARTICLE DIFFUSION; KINETIC STUDY; LANGMUIR AND FREUNDLICH ISOTHERMS; MESOPOROUS MCM-41; METAL ION CONCENTRATION; NITROGEN ADSORPTION-DESORPTION; PORE BLOCKAGES; PORE DIAMETERS; SECOND ORDER KINETICS; SURFACE AREA; THERMODYNAMIC PARAMETER; THERMODYNAMIC STUDIES; TIO; TOXIC METALS; UV-VIS DIFFUSE REFLECTANCE SPECTROSCOPY; WEIGHT PERCENTAGES;

ADSORPTION; CHEMISORPTION; CHROMIUM COMPOUNDS; DESORPTION; DYES; ENZYME KINETICS; ISOTHERMS; KINETICS; MESOPOROUS MATERIALS; METAL IONS; NITROGEN REMOVAL; X RAY DIFFRACTION;

TITANIUM DIOXIDE;

CHROMIUM; MCM 41; METAL ION; TITANIUM DIOXIDE;

ADSORPTION; AQUEOUS SOLUTION; CONCENTRATION (COMPOSITION); DESORPTION; IMMOBILIZATION; ISOTHERM; OXIDE; POLLUTANT REMOVAL; REACTION KINETICS; THERMODYNAMICS; TOXIC SUBSTANCE; ULTRAVIOLET RADIATION;

ADSORPTION; ARTICLE; DESORPTION; DIFFUSE REFLECTANCE SPECTROSCOPY; INFRARED SPECTROSCOPY; KINETICS; PH; TEMPERATURE; THERMODYNAMICS; ULTRAVIOLET RADIATION; X RAY DIFFRACTION;

ADSORPTION; CHROMIUM; HYDROGEN-ION CONCENTRATION; KINETICS; MODELS, THEORETICAL; SILICON DIOXIDE; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; SURFACE PROPERTIES; THERMODYNAMICS; TIME FACTORS; TITANIUM; WATER POLLUTANTS, CHEMICAL; WATER PURIFICATION; X-RAY DIFFRACTION;

EID: 84868489578     PISSN: 03043894     EISSN: 18733336     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2012.09.052     Document Type: Article

References (57)

1. Aaseth J., Norseth T. Handbook on the Toxicity of Metals 1986, Elsevier, pp. 233-257.
2. Enshirah D., Sayari A. Adsorption of copper on amine-functionalized SBA-15 prepared by co-condensation: equilibrium properties. Chem. Eng. J. 2011, 166:445-453.
3. 2+ on spherical Fe-MCM-41 and its catalytic application for oxidation of adamantane. J. Hazard. Mater. 2010, 179:642-647.
4. 2-MCM-41 and its application for epoxidation of styrene. Ind. Eng. Chem. Res. 2011, 51:2235-2246.
5. Benhamou A., Baudu M., Derriche Z., Basly J.P. Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48. J. Hazard. Mater. 2009, 171:1001-1008.
6. Selvam P., Bhatia S.K., Sonwane C.G. Recent advances in processing and characterization of periodic mesoporous MCM-41 silicate molecular sieves. Ind. Eng. Chem. Res. 2001, 40:3237-3261.
7. Nityanandi D., Subbhuraam C.V. Kinetics and thermodynamic of adsorption of chromium(VI) from aqueous solution using puresorbe. J. Hazard. Mater. 2009, 170:876-882.
8. Marjanovic V., Lazarevic S., Jankovic-Castvan I., Potkonjak B., Janackovic D.D., Petrovic R. Chromium(VI) removal from aqueous solutions using mercaptosilane functionalized sepiolites. Chem. Eng. J. 2011, 166:198-206.
9. 2 leaching. J. Colloid Interface Sci. 2006, 297:419-425.
10. Das J., Das D., Das G.P., Das D.P., Parida K.M. Studies on Mg/Fe hydrotalcite-like compounds (HT): removal of Cr(VI) from aqueous solution. Int. J. Environ. Stud. 2004, 61(5):605-616.
11. Rengaraj S., Yeon K.H., Moon S.-H. Removal of chromium from water and waste water by ion-exchange resins. J. Hazard. Mater. 2001, 87:273-287.
12. Venkateswarlu P., Ratnam M.V., Subba Rao D., Rao M.V. Removal of chromium from an aqueous solution using Azadirachta indica (neem) leaf powder as an adsorbent. Int. J. Phys. Sci. 2007, 2:188-195.
13. Ghosh G., Bhattacharya P.K. Hexavalent chromium ion removal through micellar enhanced ultrafiltration. Chem. Eng. J. 2006, 119:45-53.
14. ISI, Tolerance limits for industrial effluents, ISI 2490. Part I. Indian Standard Institution, 1982.
15. Mohan D., Pittman C.U. Review: activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water. J. Hazard. Mater. 2006, 137:762-811.
16. Namasivayam C., Yamuna R.T. Adsorption of Cr(VI) by a low cost adsorbent: biogas residual slurry. Chemosphere 1995, 30:561-578.
17. Schmuhl R., Krieg H.M., Keizer K. Adsorption of Cu(II) and Cr(VI) ions by chitosan: kinetics and equilibrium studies. Water SA 2001, 27:1-7.
18. Das D.P., Parida K.M., De B.R. Photocatalytic reduction of hexavalent chromium in aqueous solution over titania pillared zirconium phosphate and titanium phosphate under solar radiation. J. Mol. Catal. A: Chem. 2006, 245:217-224.
19. Mohapatra P., Samantaray S., Parida K.M. Photocatalytic reduction of hexavalent chromium in aqueous solution over sulphate modified titania. J. Photochem. Photobiol. A: Chem. 2005, 170:189-194.
20. Sarma A., Battacharya K.G. Adsorption of chromium (VI) on Azadirachta indica (neem) leaf. powder. Adsorption 2005, 10:327-338.
21. Garg V.K., Gupta R., Kumar R., Gupta R.K. Adsorption of chromium from aqueous solution on treated sawdust. Bioresour. Technol. 2004, 92:79-81.
22. Tian L., Xie G., Li R., Yu X., Hou Y. Removal of Cr(VI) from aqueous solution using MCM-41. Desalination Water Treatment 2011, 36:334-343.
23. Zheng S., Gao L., Zhang Q., Guo J. Synthesis, characterization and photocatalytic properties of titania-modified mesoporous silicate MCM-41. J. Mater. Chem. 2000, 10:723-727.
24. Lihitkar N.B., Abyaneh M.K., Samuel V., Pasricha R., Gosavi S.W., Kulkarni S.K. Titania nanoparticles synthesis in mesoporous molecular sieve MCM-41. J. Colloid Interface Sci. 2007, 314:310-316.
25. 2/Al-MCM-41 composite systems using solar light. Chemosphere 2008, 72:644-651.
26. Tanev P.T., Chibwe M., Pinnavaia T.J. Titanium-containing mesoporous molecular sieves for catalytic oxidation of aromatic compounds. Nature 1994, 368:321-323.
27. Bhaumik A., Tatsumi T. Organically modified titanium-rich Ti-MCM-41, efficient catalysts for epoxidation reactions. J. Catal. 2000, 189:31-39.
28. Luan Z., Macs W.M., van der Heidi P.A.W., Zhao D., Czernuszewicz R.S., Kevan I. Incorporation of titanium into mesoporous silica molecular sieve SBA-15. Chem. Mater. 1999, 11:3680-3686.
29. Zhang W., Lu J., Han B., Li M., Xiu J., Ying P., Li C. Direct synthesis and characterization of titanium-substituted mesoporous molecular sieve SBA-15. Chem. Mater. 2002, 14:3413-3421.
30. Yang J., Zhang J., Zhu L., Chen S., Zhang Y., Tang Y., Zhu Y., Li Y. Synthesis of nano titania particles embedded in mesoporous SBA-15: characterization and photocatalytic activity. J. Hazard. Mater. 2006, 137:952-958.
31. 2 photocatalysis. J. Photochem. Photobiol. A: Chem. 2002, 148:315-322.
32. Lin K., Pescarmona P.P., Houthoofd K., Liang D., Tendaloo G.V., Jacobs P.A. Direct room-temperature synthesis of methyl-functionalized Ti-MCM-41 nanoparticles and their catalytic performance in epoxidation. J. Catal. 2009, 263:75-82.
33. Kim T.J., Kim J.-H., Seo G. Physico-chemical state of titania impregnated on MCM-41 mesoporous material upon liquid-phase reaction of titanium-alkoxide. React. Kinet. Catal. Lett. 2001, 73:275-282.
34. Trens P., Russell M.L., Spjuth L., Hudson M.J. Linjenzin preparation of malonamide-MCM-41 materials for the heterogeneous extraction of radionuclides. Ind. Eng. Chem. Res. 2002, 41:5220-5225.
35. Shigematsu T., Gohda S., Yamazaki H., Nishikawa Y. Spectrophotometric determination of chromium(III) and chromium (VI) in sea water. Bull. Inst. Chem. Res. 1977, 55:429-440.
36. Shankar H., Saravaran R., Suresh V., Narayanan V., Rossi F., Stephen A. Synthesis and characterization of nano-titania photocatalyst loaded on Mo-MCM-41. Adv. Sci. Lett. 2011, 4:89-95.
37. Redlich O.J., Peterson D.L. A useful adsorption isotherm. J. Phys. Chem. 1959, 63:1024-1026.
38. Mohan D., Pittman C.U. Review activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water. J. Hazard. Mater. 2006, 137:762-811.
39. Zheng S., Gao L., Zhang Q., Zhang W., Guo J. Preparation, characterization and photocatalytic properties of singly and doubly titania-modified mesoporous silicate MCM-41 by varying titanium precursors. J. Mater. Chem. 2001, 11:578-583.
40. Morey M.S., Obrien S., Schwarz S., Stucky G.D. Hydrothermal and postsynthesis surface modification of cubic MCM-48, and ultralarge pore SBA-15 mesoporous silica with titanium. Chem. Mater. 2000, 12:898-911.
41. Smitha V.S., Manjumol K.A., Baiju K.V., Ghosh S., Perumal P., Warrier K.G.K. Sol-gel route to synthesize titania-silica nano precursors for photoactive particulates and coatings. J. Sol-Gel Sci. Technol. 2010, 54:203-211.
42. Artkla S., Kim W., Choi W., Wittayakun J. Highly enhanced photocatalytic degradation of tetramethylammonium on the hybrid catalyst of titania and MCM-41 obtained from rice husk silica. Appl. Catal. B: Environ. 2009, 91:157-164.
43. Lin K., Pescarmona P.P., Houthoofd K., Liang D., Tendeloo G.V., Jacobs P.A. Direct room-temperature synthesis of methyl-functionalized Ti-MCM-41 nanoparticles and their catalytic performance in epoxidation. J. Catal. 2009, 263:75-82.
44. Cheng P., Zheng M.P., Jin Y.P., Huang Q., Gu M.Y. Preparation and characterization of silica doped titania photocatalyst through sol-gel method. Mater. Lett. 2003, 57:2989-2994.
45. Baiju K.V., Periyat P., Pillai P.K., Mukundan P., Warrier K.G.K., Wunderlich W. Enhanced photoactivity and antase thermal stability of silica-alumina mixed oxide additives on sol-gel nanocrystalline titania. Mater. Lett. 2007, 61:1751-1755.
46. Xu G.Q., Zheng Z.X., Yu Y.C., Feng N. Effect of silica on the microstructure and photocatalytic properties of titania. Ceram. Int. 2009, 35:1-5.
47. Smith B. Infrared Spectral Interpretation 1998, CRC Press, Boca Raton.
48. Enshirah D., De Silva N., Sayari A. Adsorption of copper on amine-functionalized SBA-15 prepared by co-condensation: kinetic properties. Chem. Eng. J. 2011, 166:454-459.
49. Zhao X.S., Lu (Max) G.Q., Miller G.J. Advances in mesoporous molecular sieves. Ind. Eng. Chem. Res. 1996, 35:2075-2090.
50. Moussavi G., Barikbin B. Biosorption of chromium(VI) from industrial wastewater onto pistachio hull waste biomass. Chem. Eng. J. 2010, 162:893-900.
51. Hu J., Wang S.W., Shao D.D., Dong Y.H., Li J.X., Wang M.K. Adsorption and reduction of chromium(VI) from aqueous solution by multiwalled carbon nanotubes. Open Environ. Toxicol. J. 2009, 1:66-73.
52. Lach J., Okoniewska E., Neczaj E., Kacprzak M. The adsorption of Cr(III) and Cr(VI) on activated carbons in the presence of phenol. Desalination 2008, 223:249-255.
53. Wu X.-W., Ma H.-W., Zhang Y.-R. Adsorption of chromium(VI) from aqueous solution by a mesoporous aluminosilicates synthesized from microcline. Appl. Clay Sci. 2010, 48:538-541.
54. Shawabkeh R.A. Adsorption of chromium ions from aqueous solution by using activated carbo-aluminosilicate material from oil shale. J. Colloid Interface Sci. 2006, 299:530-536.
55. Malkoc E., Nuhoglu Y., Dundar M. Adsorption of chromium(VI) on pomace-an olive oil industry waste: batch and column studies. J. Hazard. Mater. 2006, 138:142-151.
56. Ho Y.S., McKay G. Kinetic model for Pb(II) sorption on peat. Adsorpt. Sci. Technol. 1998, 16:243-255.
57. Wan Ngah W.S., Hanafiah M.A.K.M. Adsorption of copper on rubber (Hevea brasiliensis) leaf powder; kinetic, equilibrium and thermodynamic studies. Biochem. Eng. J. 2008, 39:521-530.