Adsorption- and desorption-controlled magnesium isotope fractionation during extreme weathering of basalt in Hainan Island, China

Earth and Planetary Science Letters

Volumn 359-360, Issue , 2012, Pages 73-83

  Huang, Kang Jun ^a,b   Teng, Fang Zhen ^b   Wei, Gang Jian ^c   Ma, Jin Long ^c   Bao, Zheng Yu ^a  

^a CHINA UNIVERSITY OF GEOSCIENCES   (China)

^b Department of Biological Sciences   (United States)

^c GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

Author keywords

Adsorption; Basalt; Chemical weathering; Desorption; Isotope fractionation; Magnesium

Indexed keywords

CATION EXCHANGES; CHEMICAL WEATHERING; DESORPTION PROCESS; HAINAN ISLAND; HALLOYSITE; HYDRATION ENERGIES; ISOTOPE FRACTIONATION; ISOTOPIC COMPOSITION; MAGNESIUM CONCENTRATIONS; MG CONCENTRATIONS; MG ISOTOPES; NEGATIVE CORRELATION; NEO GENES; POSITIVE CORRELATIONS; RIVER WATER; SOUTHERN CHINA; THOLEIITIC BASALTS; WEATHERING PROFILES;

ADSORPTION; BASALT; CESIUM; DESORPTION; KAOLIN; KAOLINITE; MAGNESIUM; MINERALS; POSITIVE IONS; ROCKS; WEATHERING;

ISOTOPES;

ADSORPTION; CHEMICAL WEATHERING; CONCENTRATION (COMPOSITION); DESORPTION; ION EXCHANGE; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATION; MAGNESIUM; NEOGENE; SAPROLITE; THOLEIITIC BASALT;

CHINA; HAINAN;

EID: 84868451092     PISSN: 0012821X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.epsl.2012.10.007     Document Type: Article

References (87)

1. Balistrieri L.S., Borrok D.M., Wanty R.B., Ridley W.I. Fractionation of Cu and Zn isotopes during adsorption onto amorphous Fe(III) oxyhydroxide: experimental mixing of acid rock drainage and ambient river water. Geochim. Cosmochim. Acta 2008, 72(2):311-328.
2. Barling J., Anbar A.D. Molybdenum isotope fractionation during adsorption by manganese oxides. Earth Planet. Sci. Lett. 2004, 217(3-4):315-329.
3. Başçetin E., Atun G. Adsorption behavior of strontium on binary mineral mixtures of Montmorillonite and Kaolinite. Appl. Radiat. Isot. 2006, 64(8):957-964.
4. 2+ on kaolin from aqueous solutions and the stability constants for complex formation. J. Chem. Soc. Pak. 1998, 20(1):19-24.
5. Berner R.A., Lasaga A.C., Garrels R.M. The carbonate-silicate geochemical cycle and its effect on atmospheric carbon dioxide over the past 100 million years. Am. J. Sci. 1983, 283:641-683.
6. Black J.R., Epstein E., Rains W.D., Yin Q.-Z., Casey W.H. Magnesium-isotope fractionation during plant growth. Environ. Sci. Technol. 2008, 42(21):7831-7836.
7. Bleam W.F., McBride M.B. Cluster formation versus isolated-site adsorption. A study of Mn(II) and Mg(II) adsorption on boehmite and goethite. J. Colloid Interf. Sci. 1985, 103(1):124-132.
8. Bolou-Bi E.B., Poszwa A., Leyval C., Vigier N. Experimental determination of magnesium isotope fractionation during higher plant growth. Geochim. Cosmochim. Acta 2010, 74(9):2523-2537.
9. Bolou-Bi E.B., Vigier N., Poszwa A., Boudot J.-P., Dambrine E. Effects of biogeochemical processes on magnesium isotope variations in a forested catchment in the Vosges Mountains (France). Geochim. Cosmochim. Acta 2012, 87(15):341-355.
10. Brennecka G.A., Wasylenki L.E., Bargar J.R., Weyer S., Anbar A.D. Uranium isotope fractionation during adsorption to Mn-oxyhydroxides. Environ. Sci. Technol. 2011, 45(4):1370-1375.
11. Brenot A., Cloquet C., Vigier N., Carignan J., France-Lanord C. Magnesium isotope systematics of the lithologically varied Moselle river basin. France Geochim. Cosmochim. Acta 2008, 72(20):5070-5089.
12. Carroll D., Starkey H.C. Effect of sea-water on clay minerals. Clays Clay Miner. 1960, 7:80-101.
13. Chang V.T.C., Makishima A., Belshaw N.S., O'Nions R.K. Purification of Mg from low-Mg biogenic carbonates for isotope ratio determination using multiple collector ICP-MS. J. Anal. At. Spectrom. 2003, 18(4):296-301.
14. Cornell R.M. Adsorption of cesium on minerals: a review. J. Radioanal. Nucl. Chem. 1993, 171(2):483-500.
15. Dessert C., Dupr B., Gaillardet D., Françoisc L.M., Allègre C.J. Basalt weathering laws and the impact of basalt weathering on the global carbon cycle. Chem. Geol. 2003, 202(3-4):257-273.
16. -: a theoretical study. Geochim. Cosmochim. Acta 2000, 64(17):3007-3033.
17. Evangelou V. Environmental Soil and Water Chemistry: Principles and Applications 1998, John Wiley & Sons, New York, 592 p.
18. Fantle M.S., Tollerud H., Eisenhauer A., Holmden C. The Ca isotopic composition of dust-producing regions: measurements of surface sediments in the Black Rock Desert, Nevada. Geochim. Cosmochim. Acta 2012, 87(15):178-193.
19. Foster G.L., Pogge von Strandmann P.A.E., Rae J.W.B. Boron and magnesium isotopic composition of seawater. Geochem. Geophys. Geosyst. 2010, 11(8):Q08015. 10.1029/2010GC003201.
20. 2 consumption rates deduced from the chemistry of large rivers. Chem. Geol. 1999, 159(1-4):3-30.
21. Galy A., Yoffe O., Janney P.E., Williams R.W., Cloquet C., Alard O., Halicz L., Wadhwa M., Hutcheon I.D., Ramon E., Carignan J. Magnesium isotope heterogeneity of the isotopic standard SRM980 and new reference materials for magnesium-isotope-ratio measurements. J. Anal. At. Spectrom. 2003, 18:1352-1356.
22. Goldberg T., Archer C., Vance D., Poulton S.W. Mo isotope fractionation during adsorption to Fe (oxy-hydr)oxides. Geochim. Cosmochim. Acta 2009, 73(21):6502-6516.
23. Gu X., Evans L.J. Surface complexation modelling of Cd(II), Cu(II), Ni(II), Pb(II) and Zn(II) adsorption onto kaolinite. Geochim. Cosmochim. Acta 2008, 72(2):267-276.
24. Hoefs J. Stable Isotope Geochemistry 2009, Springer Verlag, Berlin, Heidelberg. sixth edition.
25. Icopini G.A., Anbar A.D., Ruebush S.S., Tien M., Brantley S.L. Iron isotope fractionation during microbial reduction of iron: the importance of adsorption. Geology 2004, 32(3):205-208.
26. James R.H., Palmer M.R. Marine geochemical cycles of the alkali elements and boron: the role of sediments. Geochim. Cosmochim. Acta 2000, 64(18):3111-3122.
27. Joussein E., Petit S., Churchman J., Theng B., Righi D., Delvaux B. Halloysite clay minerals-a review. Clay Miner. 2005, 40(4):383-426.
28. Kashiwabara T., Takahashi Y., Tanimizu M., Usui A. Molecular-scale mechanisms of distribution and isotopic fractionation of molybdenum between seawater and ferromanganese oxides. Geochim. Cosmochim. Acta 2011, 75(19):5762-5784.
29. Kinniburgh D.G., Jackson M.L., Syers J.K. Adsorption of alkaline earth, transition, and heavy metal cations by hydrous oxide gels of iron and aluminum. Soil Sci. Soc. Am. J. 1976, 40(5):796-799.
30. Kosmulski M. pH-dependent surface charging and points of zero charge: III. Update. J. Colloid Interf. Sci. 2006, 298(2):730-741.
31. Kosmulski M. Surface charging and points of zero charge. Surfactant Science Series. 2009, The CRC Press Taylor & Francis Group, Florida, USA, vol. 145, 1092 p.
32. Lemarchand E., Schott J., Gaillardet J. How surface complexes impact boron isotope fractionation: evidence from Fe and Mn oxides sorption experiments. Earth Planet. Sci. Lett. 2007, 260(1-2):277-296.
33. 4 solution. Geochim. Cosmochim. Acta 2011, 75:1814-1828.
34. Li W.-Y., Teng F.-Z., Ke S., Rudnick R.L., Gao S., Wu F.-Y., Chappell B.W. Heterogeneous magnesium isotopic composition of the upper continental crust. Geochim. Cosmochim. Acta 2010, 74(23):6867-6884.
35. Ling M.-X., Sedaghatpour F., Teng F.-Z., Hays P.D., Strauss J., Sun W. Homogeneous magnesium isotopic composition of seawater: an excellent geostandard for Mg isotope analysis. Rapid Commun. Mass Spectrom. 2011, 25(19):2828-2836.
36. Liu S.-A., Teng F.-Z., He Y., Ke S., Li S. Investigation of magnesium isotope fractionation during granite differentiation: implication for Mg isotopic composition of the continental crust. Earth Planet. Sci. Lett. 2010, 297(3-4):646-654.
37. Ma C., Eggleton R.A. Cation exchange capacity of kaolinite. Clays Clay Miner. 1999, 47(2):174-180.
38. Ma J.-L., Wei G.-J., Xu Y.-G., Long W.-G., Sun W.-D. Mobilization and re-distribution of major and trace elements during extreme weathering of basalt in Hainan Island, South China. Geochim. Cosmochim. Acta 2007, 71(13):3223-3237.
39. Ma J., Wei G., Xu Y., Long W. Variations of Sr-Nd-Hf isotopic systematics in basalt during intensive weathering. Chem. Geol. 2010, 269(3-4):376-385.
40. Ma L., Chabaux F., Pelt E., Granet M., Sak P.B., Gaillardet J., Lebedeva M., Brantley S.L. The effect of curvature on weathering rind formation: evidence from Uranium-series isotopes in basaltic andesite weathering clasts in Guadeloupe. Geochim. Cosmochim. Acta 2012, 80:92-107.
41. Manceau A., Schlegel M.L., Musso M., Sole V.A., Gauthier C., Petit P.E., Trolard F. Crystal chemistry of trace elements in natural and synthetic goethite. Geochim. Cosmochim. Acta 2000, 64(21):3643-3661.
42. Marcus Y. Ionic radii in aqueous solutions. Chem. Rev. 1988, 88(8):1475-1498.
43. Nesbitt H.W., Markovics G., Price R.C. Chemical processes affecting alkalis and alkaline earths during continental weathering. Geochim. Cosmochim. Acta 1980, 44(11):1659-1666.
44. Nesbitt H.W., Wilson R.E. Recent chemical weathering of basalts. Am. J. Sci. 1992, 292:740-777.
45. Oi T., Yanase S., Kakihana H. Magnesium isotope fractionation in cation-exchange chromatography. Sep. Sci. Technol. 1987, 22(11):2203-2215.
46. Olu-Owolabi B.I., Ajayi S.O. Cations adsorption on goethite-humic acid complex. Sci. Iran. 2003, 10(3):329-333.
47. Opfergelt S., Georg R.B., Delvaux B., Cabidoche Y.M., Burton K.W., Halliday A.N. Mechanisms of magnesium isotope fractionation in volcanic soil weathering sequences, Guadeloupe. Earth Planet. Sci. Lett. 2012, 341-344:176-185.
48. Palmer M.R., Spivack A.J., Edmond J.M. Temperature and pH controls over isotopic fractionation during adsorption of boron on marine clay. Geochim. Cosmochim. Acta 1987, 51(9):2319-2323.
49. Peacock C.L., Sherman D.M. Surface complexation model for multisite adsorption of copper(II) onto kaolinite. Geochim. Cosmochim. Acta 2005, 69(15):3733-3745.
50. Peskleway C.D., Henderson G.S., Wicks F.J. Dissolution of gibbsite: direct observations using fluid cell atomic force microscopy. Am. Mineral. 2003, 88(1):18-26.
51. Pistiner J.S., Henderson G.M. Lithium-isotope fractionation during continental weathering processes. Earth Planet. Sci. Lett. 2003, 214(1-2):327-339.
52. Pogge von Strandmann P.A.E., Burton K.W., James R.H., van Calsteren P., Gislason S.R., Sigfússon B. The influence of weathering processes on riverine magnesium isotopes in a basaltic terrain. Earth Planet. Sci. Lett. 2008, 276(1-2):187-197.
53. Pogge von Strandmann P.A.E., James R.H., van Calsteren P., Gíslason S.R., Burton K.W. Lithium, magnesium and uranium isotope behaviour in the estuarine environment of basaltic islands. Earth Planet. Sci. Lett. 2008, 274(3-4):462-471.
54. Pogge von Strandmann P.A.E., Burton K.W., James R.H., van Calsteren P., Gislason S.R. Assessing the role of climate on uranium and lithium isotope behaviour in rivers draining a basaltic terrain. Chem. Geol. 2010, 270:227-239.
55. Pogge von Strandmann P.A.E., Elliott T., Marschall H.R., Coath C., Lai Y.-J., Jeffcoate A.B., Ionov D.A. Variations of Li and Mg isotope ratios in bulk chondrites and mantle xenoliths. Geochim. Cosmochim. Acta 2011, 75:5247-5268.
56. Pogge von Strandmann P.A.E., Opfergelt S., Lai Y.-J., Sigfússon B., Gislason S.R., Burton K.W. Lithium, magnesium and silicon isotope behaviour accompanying weathering in a basaltic soil and pore water profile in Iceland. Earth Planet. Sci. Lett. 2012, 339-340:11-23.
57. Pokrovsky O.S., Viers J., Freydier R. Zinc stable isotope fractionation during its adsorption on oxides and hydroxides. J. Colloid Interf. Sci. 2005, 291(1):192-200.
58. Riechelmann S., Buhl D., Schröder-Ritzrau A., Spötl C., Riechelmann D.F.C., Richter D.K., Kluge T., Marx T., Immenhauser A. Hydrogeochemistry and fractionation pathways of Mg isotopes in a continental weathering system: lessons from field experiments. Chem. Geol. 2012, 300-301:109-122.
59. 26/24Mg geochemistry of granite weathering at pH=1 and T=25°C: power-law processes and the relative reactivity of minerals. Geochim. Cosmochim. Acta 2011, 75(20):6004-6026.
60. Sawhney B.L. Selective sorption and fixation of cations by clay minerals: a review. Clays Clay Miner. 1972, 20(2):93-100.
61. Schauble E.A. First-principles estimates of equilibrium magnesium isotope fractionation in silicate, oxide, carbonate and hexaaquamagnesium(2+) crystals. Geochim. Cosmochim. Acta 2011, 75(3):844-869.
62. Schwarcz H.P., Agyei E.K., McMullen C.C. Boron isotopic fractionation during clay adsorption from sea-water. Earth Planet. Sci. Lett. 1969, 6(1):1-5.
63. Scroth B.K., Sposito G. Surface charge properties of kaolinite. Clays Clay Miner. 1997, 45(1):85-91.
64. Srivastava P., Singh B., Angove M. Competitive adsorption behavior of heavy metals on kaolinite. J. Colloid Interf. Sci. 2005, 290(1):28-38.
65. Tatsuya T., Komarneni S. Alkali metal and alkaline earth metal ion exchange with Na-4-mica prepared by a new synthetic route from kaolinite. J. Mater. Chem. 1999, 9:2475-2479.
66. Teng F.-Z., Li W.-Y., Ke S., Marty B., Dauphas N., Huang S., Wu F.-Y., Pourmand A. Magnesium isotopic composition of the Earth and chondrites. Geochim. Cosmochim. Acta 2010, 74(14):4150-4166.
67. Teng F.-Z., Li W.-Y., Rudnick R.L., Gardner L.R. Contrasting lithium and magnesium isotope fractionation during continental weathering. Earth Planet. Sci. Lett. 2010, 300(1-2):63-71.
68. Teng F.-Z., Wadhwa M., Helz R.T. Investigation of magnesium isotope fractionation during basalt differentiation: implications for a chondritic composition of the terrestrial mantle. Earth Planet. Sci. Lett 2007, 261(1-2):84-92.
69. Teppen B.J., Miller D.M. Hydration energy determines isovalent cation exchange selectivity by clay minerals. Soil Sci. Soc. Am. J. 2006, 70(1):31-40.
70. Tipper E.T., Galy A., Bickle M.J. Riverine evidence for a fractionated reservoir of Ca and Mg on the continents: implications for the oceanic Ca cycle. Earth Planet. Sci. Lett 2006, 247(3-4):267-279.
71. Tipper E.T., Galy A., Gaillardet J., Bickle M.J., Elderfield H., Carder E.A. The magnesium isotope budget of the modern ocean: constraints from riverine magnesium isotope ratios. Earth Planet. Sci. Lett. 2006, 250(1-2):241-253.
72. Tipper E.T., Galy A., Bickle M.J. Calcium and magnesium isotope systematics in rivers draining the Himalaya-Tibetan-Plateau region: lithological or fractionation control?. Geochim. Cosmochim. Acta 2008, 72(4):1057-1075.
73. Tipper E.T., Gaillardet J., Louvat P., Capmas F., White A.F. Mg isotope constraints on soil pore-fluid chemistry: evidence from Santa Cruz, California. Geochim. Cosmochim. Acta 2010, 74(14):3883-3896.
74. Tipper E.T., Lemarchand E., Hindshaw R.S., Reynolds B.C., Bourdon B. Seasonal sensitivity of weathering processes: hints from magnesium isotopes in a glacial stream. Chem. Geol. 2012, 312-313:80-92.
75. Trolard F., Tardy Y. The stabilities of gibbsite, boehmite, aluminous goethites and aluminous hematites in bauxites, ferricretes and laterites as a function of water activity, temperature and particle size. Geochim. Cosmochim. Acta 1987, 51(4):945-957.
76. Wasylenki L.E., Rolfe B.A., Weeks C.L., Spiro T.G., Anbar A.D. Experimental investigation of the effects of temperature and ionic strength on Mo isotope fractionation during adsorption to manganese oxides. Geochim. Cosmochim. Acta 2008, 72(24):5997-6005.
77. Wasylenki L.E., Weeks C.L., Bargar J.R., Spiro T.G., Hein J.R., Anbar A.D. The molecular mechanism of Mo isotope fractionation during adsorption to birnessite. Geochim. Cosmochim. Acta 2011, 75(17):5019-5031.
78. Weaver C.E., Pollard L.D. The chemistry of clay minerals. Development in Sedimentology 1973, Elsevier, Amsterdam, 213 p.
79. White A.F., Schulz M.S., Stonestrom D.A., Vivit D.V., Fitzpatrick J., Bullen T.D., Maher K., Blum A.E. Chemical weathering of a marine terrace chronosequence, Santa Cruz, California. Part II: Solute profiles, gradients and the comparisons of contemporary and long-term weathering rates. Geochim. Cosmochim. Acta 2009, 73(10):2769-2803.
80. Wilson M.J. The origin and formation of clay minerals in soils: past, present and future perspectives. Clay Miner. 1999, 34(1):7-25.
81. Wimpenny J., Burton K.W., James R.H., Gannoun A., Mokadem F., Gíslason S.R. The behaviour of magnesium and its isotopes during glacial weathering in an ancient shield terrain in West Greenland. Earth Planet. Sci. Lett. 2011, 304(1-2):260-269.
82. Wimpenny J., Gíslason S.R., James R.H., Gannoun A., Pogge Von Strandmann P.A.E., Burton K.W. The behaviour of Li and Mg isotopes during primary phase dissolution and secondary mineral formation in basalt. Geochim. Cosmochim. Acta 2010, 74(18):5259-5279.
83. Yang W., Teng F.-Z., Zhang H.-F. Chondritic magnesium isotopic composition of the terrestrial mantle: a case study of peridotite xenoliths from the North China craton. Earth Planet. Sci. Lett 2009, 288(3-4):475-482.
84. Yang W., Teng F.-Z., Zhang H.-F., Li S.-G. Magnesium isotopic systematics of continental basalts from the North China craton: implications for tracing subducted carbonate in the mantle. Chem. Geol. 2012, 328:185-194.
85. Young E.D., Galy A. The isotope geochemistry and cosmochemistry of magnesium. Rev. Mineral. Geochem. 2004, 55(1):197-230.
86. Zhang L., Chan L.-H., Gieskes J.M. Lithium isotope geochemistry of pore waters from ocean drilling program Sites 918 and 919, Irminger Basin. Geochim. Cosmochim. Acta 1998, 62(14):2437-2450.
87. Zhu B., Wang H. Nd-Sr-Pb isotopic and chemical evidence for the volcanism with MORB-OIB source characteristics in the Leiqiong Area. China. Geochim. 1989, 18(3):193-201.