Synthesis, characterization, redox and biological screening studies of copper(ii), nickel(ii), cobalt(ii), zinc(ii) and vanadium(iv) complexes derived from 1-phenyl-2,3-dimethyl-4-imino-(2- hydroxybenzylidene)-pyrozol-5-(α-imino)-indole-3- propionic acid

International Journal of ChemTech Research

Volumn 4, Issue 4, 2012, Pages 1571-1581

  Kavitha, Thavuduraj ^a   Kulandaisamy, Antonysamy ^b   Thillaiarasu, Ponnusamy ^c  

^a Sri S Ramasamy Naidu Memorial College   (India)

^b Raja Doraisingam Government Arts College   (India)

^c KALASALINGAM UNIVERSITY   (India)

Author keywords

Biological screening studies; Cyclic voltammogram; ESR spectra; Salicylidene 4 aminoantipyrine; Tryptophan

Indexed keywords

ANTIFUNGAL AGENT; ANTIINFECTIVE AGENT; CHELATING AGENT; COBALT COMPLEX; COPPER COMPLEX; NICKEL COMPLEX; PROPIONIC ACID DERIVATIVE; SCHIFF BASE; UNCLASSIFIED DRUG; VANADIUM; VANADIUM COMPLEX; ZINC COMPLEX; 1 PHENYL 2,3 DIMETHYL 4 IMINO (2 HYDROXYBENZYLIDENE) PYROZOL 5 (ALPHA IMINO) INDOLE 3 PROPIONIC ACID;

ANTIBACTERIAL ACTIVITY; ANTIFUNGAL ACTIVITY; ARTICLE; ASPERGILLUS NIGER; CANDIDA ALBICANS; CONDUCTANCE; CONTROLLED STUDY; CYCLIC POTENTIOMETRY; DRUG SCREENING; DRUG STRUCTURE; DRUG SYNTHESIS; ELECTRON SPIN RESONANCE; ESCHERICHIA COLI; INFRARED SPECTROSCOPY; MASS SPECTROMETRY; NONHUMAN; OXIDATION REDUCTION POTENTIAL; PHYSICAL CHEMISTRY; PROTON NUCLEAR MAGNETIC RESONANCE; PSEUDOMONAS AERUGINOSA; SALMONELLA TYPHI; STAPHYLOCOCCUS AUREUS; STREPTOCOCCUS; ULTRAVIOLET SPECTROSCOPY; ANTIMICROBIAL ACTIVITY; CHEMICAL COMPOSITION; CHEMICAL STRUCTURE; COMPLEX FORMATION; GEOMETRY; INFRARED RADIATION; MAGNETISM; ULTRAVIOLET RADIATION;

EID: 84868326963     PISSN: 09744290     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (39)

1. Ismail K. Z., El-Dissouky A. and Shehada A. Z., Spectroscopic and magnetic studies on some copper(II) complexes of antipyrine Schiff base derivatives. Polyhedron, 1997, 16, 2909-2916.
2. Singh L., Sharma A. and Sindhu S. K., Structure and bonding of some newly synthesized complexes of lanthanide(III) complexes of 4[N-(p- Dimethylaminobenalidene) amino]antipyrine, Asian J. Chem., 1999, 11, 1445-1450.
3. Shankar G., Premkumar P. R. and Ramalingam S. K., 4-aminoantipyrine Schiff base complexes of lanthanide and Uranyl ions, Polyhedron, 1986, 15, 991-994.
4. Chopra J. R., Uppal D., Arrora U. S. and Gupta S. K., Synthesis ectral studies of Cu(II) complexes of 4[N-(2-hydroxy-1- naphthalidene0amino]antipyrine, Asian J. Chem., 2000, 12, 1277-1281.
5. S. Cunha, S. M. Oliveira, M.T. Rodrigues, R. M. Bastos, J. Ferrari, C. M. A. De Oliveira, L. Kato, H. B. Napolitano, I. Vencato, C. Lariucci, Structural studies of 4- aminoantipyrine derivatives. J. Mol. Struct., 2005, 752 32-39.
6. Raman N., Mitu L., Sakthivel A. and Pandi M. S. S., Studies on DNA cleavage and antimicrobial screening of transition metal complexes of 4-aminoantipyrine derivatives of N2O2 type, J. Iran. Chem. Soc., 2009, 9, 738-748.
7. Raman, N. Raja, J.D., Sakthivel, A., Transition metal complexes with Schiff base ligands: 4-aminoantipyrine based derivatives-A review, J. Coord. Chem., 2009, 62, 691-709.
8. Rosu T., Pasculescu S., Laza V., Chifiriuc C. and Cernat R., Copper(II) complexes with ligands derived from 4-amino-2,3-dimethyl-1- phenyl-3-pyrazolin-5-one: Synthesis and biological activity, Molecules, 2006, 11, 904-914.
9. N. Raman, C. Thangaraja, Synthesis, structural characterization, cyclicvoltammetric and antimicrobial studies of tetraaza 13-membered macrocyclic copper(II), cobalt(II), nickel(II) and zinc(II) complexes derived from the Schiff base 3-salicylidene-2,4-di(imino-4'- antipyrinyl)pentane and o-phenylenediamine, Polish J. Chem., 2005, 79, 1123-1134.
10. Nag J. K., Pal S. and Sinha C., Synthesis and characterization of cobalt(II), nickel(II), copper(II), palladium(II) and dioxouranium(VI) complexes of the antipyrine schiff base of 3-formylsalicylic acid, Transition Met. Chem., 2005, 30, 523-526.
11. Zambre A. P., Kulkarni V. M., Padhye S., Sandur S. K. and Aggarwal B. B., Novel curcumin analogs targeting TNF-induced NF- @kB activation and proliferation in human leukemic KBM-5 cells, Bioinorg. and Med. Chem., 2006, 14, 7196-7204.
12. Sabaa, M. W., Mohamed, R. R., Oraby, E. H., Vanilin-Schiff bases as organic thermal stabiliser and co-stabilisers for rigid polyvinyl chloride, European Polymer J. 2009, 45, 3072-3080.
13. Selvakumar P. M., Suresh E. and Subramanian P. S., Synthesis, spectral characterization and structural investigation on some 4- aminoantipyrine containing Schiff base Cu(II) complexes and their molecular association, Polyhedran, 2007, 26, 749-756.
14. Omar M. M., Mahamed G. G. and Ibrahim A. A., Spectroscopic characterization of metal complexes of novel Schiff base. Synthesis, thermal and biological activity studies, Spectrachimca Acta, 2009, 73A, 358-369.
15. Padhye S., Yang H., Jamadar A., Cindy Cui Q., Chavan D., Dominiak K., McKinney J., Banerjee S., Ping Dou Q. and Sarkar F. H., New difluoro knoevenagel condensates of curcumin, their Schiff bases and copper complexes as proteasome inhibitors and apoptosis inducers in cancer cells, Pharmaceutical Research, 2009, 26, 1874-1880.
16. Deepa K., Madhu N. T. and Radhakrishnan P. K., Cadmium(II) complexes of 1,2-Di(imino-4-antipyrinyl)ethane, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2005, 35, 883-888.
17. Ismail K. Z., Synthesis, spectroscopic, magnetic and biological activity studies of copper(II) complexes of an antipyrine schiff base, Transition Met. Chem., 2000, 25, 522-528.
18. Agrawal R. K. and Prakash B., Studies on the effect of various anions and diphenyl sulphoxide on the stereochemistry of lanthanide(III) coordination compounds of 4[N-(2'-hydroxy-1'-naphthalidene)amino] antipyrine semicarbazone, Transition Met. Chem., 2005, 30, 696-705.
19. Chandra S., Deepali J., Sharma A. K. and Pratibha S., Coordination modes of a schiff base pentadentate derivative of 4- aminoantipyrine with cobalt(II), nickel(II) and copper(II) metal ions: synthesis, spectroscopic and antimicrobial studies, Molecules, 2009, 14, 174-190.
20. Raman N., Syed Ali Fathima S. and Dhaveethuraja J., Designing, synthesis and spectral characterization of Schiff base transition metal complexes: DNA cleavage and antimicrobial activity studies, J. Serb. Chem. Soc., 2008, 73, 1063-1071.
21. Geary W. J., The use of conductivity measurements in organic solvents for the characterisation of coordination compounds, Coord. Chem. Rev., 1970, 7, 81-122.
22. Nakamoto K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley Inter science, III Edition, New York, 1977, 296-346.
23. Zamian J. R., Dockal E. R., Castellano G. and Oliva G., Synthesis and characterisation of [N,N'-Ethylenebis(3- ethoxysalicylideneaminato]oxovanadium(IV), Polyhedron, 1995, 14, 2411-2418.
24. D. U. Warad, C. D. Satish, V. H. Kulkarni, C. S. Bajgur, Indian J. Chem., 39A (2000) 415-420.
25. Lever A.B.P., Inorganic Electronic spectroscopy, Elsevier, II Edition, New York, 1968 355-362.
26. Duta R. L. and Syamal A., Elements of Magnetochemistry, East-west press, II Edition, New Delhi, 1992, 206-361.
27. Jeyasubramanian K., Samath S. A., Thambidurai S., Murugesan R. and Ramalingam S. K., Cyclic voltammetric and ESR studies of a tetraaza 14-membered macrocyclic copper(II) complex derived from 3-salicylideneacetylacetone and ophenylenediamine: Stabilization and activation of unusual oxidation states, Transition Met. Chem., 1996, 20, 76-80.
28. Dutton K. G., Fallon D. and Murray K. S., Synthesis, structure, ESR spectra and redox properties of [N,N'-ethylenebis (thio salicylidene-aminato)]oxovanadium(IV) and related [S,N] chelates of vanadium(IV), Inorg. Chem., 1988, 27, 34-38.
29. P. Knopp, K. Wieghardt, B. Nuber, J. Weiss, W. S. Sheldrick, Inorg. Chem., 29 (1990) 363.
30. 2- chromophore, Inorg. Chim. Acta, 1990, 173, 207-214.
31. Srinivasan S., Rajagopal G. and Athappan P. R., Synthesis, spectral and redox properties of metal complexes of macrocyclic tetraza chiral Schiff bases, Transition Met. Chem., 2001, 26, 588-593.
32. Sharma A. L., Singh I. O., Singh M. A. and Singh H. R., EPR studies on dichloromono (1-phenyamidino-o-alkylurea)copper(II) complexes. Evidence for field induced partial ordering in the solid state and some unusual features in solution, Transition Met. Chem., 2001, 26, 532-537.
33. Yen T. F., Electron Spin Resonance of Metal Complexes, 1st Edn. Plenum Press, New York, 1969.111-133.
34. Anjaneyalu Y. and Rao R. P., Preparation, characterization and antimicrobial activity studies on some ternary complexes of Cu(II) with acetylacetone and various salicylic acids, Synth. React. Inorg. Met.-Org. Chem., 1986, 16, 257-272.
35. Mishra L. and Singh V. K., Synthesis, Characterization and antifungal activity of Co(II), Ni(II), Cu(II) and Zn(II) complexes with new Schiff bases bearing Benzimidazoles, Indian J. Chem., 1993, 37A, 446-449.
36. Thimmaiah, K. N., Chandrappa, Lloyd, W. D., Parkanyi, C., Synthesis and structural investigation of biologically active complexes of 4-acetyl-2-(acetylamino)-5-dimethyl-1,3,4- thiadiazole with Zn(II), Hg(II), Cd(II) and Cu(II), Inorg. Chim. Acta, 1985, 107, 1-4.
37. Dharmaraj N., Viswanathamurthi P. and Natarajan K., Ruthenium(II) complexes containing bidentate Schiff base and their antifungal activity, Transition Met. Chem., 2001, 26, 105-109.
38. Malhotra R., Kumar S. and Dhindsa K. S., Synthesis, Characterization and microbiocidal activity of Co(II), Ni(II), Cu(II) and Zn(II) complexes of aryloxyacetic acid and hydrazides, Indian J. Chem., 1993, 32A, 457-459.
39. Mohamed G. G. and El-Wahab Z. H. A., Mixed ligand complexes of bis(phenylimine) Schiff base ligands incorporating pyridinium moiety - Synthesis, characterization and antibacterial activity, Spectrachimica Acta, 2005, 61A, 1059-1068.