How surface and textural properties affect the behaviour of Mn-based catalysts during transesterification reaction to produce biodiesel

Catalysis Today

Volumn 195, Issue 1, 2012, Pages 32-43

  Cannilla, C ^a   Bonura, G ^a   Arena, F ^a,b   Rombi, E ^c   Frusteri, F ^a  

^a CNR ITAE   (Italy)

^b Dip Chimica Ind and Ingegneria Mat   (Italy)

^c Dip Scienze Chimiche   (Italy)

Author keywords

Basicity; Biodiesel; Mn catalysts; Reaction mechanism; Spectroscopic study; Transesterification

Indexed keywords

ACID SITE; ACTIVE SITE; BASIC SITES; BIODIESEL PRODUCTION; CATALYTIC BEHAVIOUR; COMPLEX REACTION MECHANISM; KEY FACTORS; LINEAR DEPENDENCE; METHOXY SPECIES; METHYL ESTERS; MN CATALYST; MN-BASED CATALYSTS; POROUS STRUCTURES; REACTION MECHANISM; SPECTROSCOPIC STUDIES; SUNFLOWER OIL; SURFACE REACTIVITY; TEXTURAL PROPERTIES; TRANSESTERIFICATION REACTION;

ALKALINITY; BIODIESEL; CATALYST ACTIVITY; COORDINATION REACTIONS; MANGANESE; METHANOL; SPECTROSCOPIC ANALYSIS; TRANSESTERIFICATION; VEGETABLE OILS;

SURFACE REACTIONS;

EID: 84868205893     PISSN: 09205861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cattod.2012.04.051     Document Type: Article

References (49)

1. C.R.V. Reddy, R. Oshel, and J.G. Verkade Energy and Fuels 20 2006 1310 1314
2. F. Ataya, M.A. Dubé, and M. Ternan Energy and Fuels 22 2008 679 685
3. J. Van Gerpen Fuel Processing Technology 86 2005 1097 1107
4. F. Ma, and M.A. Hanna Bioresource Technology 70 1999 1 15
5. A. Demirbas Energy Conversion and Management 44 2003 2093 2109
6. G. Vicente, M. Martínez, and J. Aracil Industrial and Engineering Chemistry Research 44 2005 5447 5454
7. S. Semwal, A.K. Arora, R.P. Badoni, and D.K. Tuli Bioresource Technology 102 2011 2151
8. H.J. Kim, B.S. Kang, M.J. Kim, Y.M. Park, D.K. Kim, J.S. Lee, and K.Y. Lee Catalysis Today 315 2004 93 95
9. L. Bournay, D. Casanave, B. Delfort, G. Hillion, and J.A. Chodorge Catalysis Today 106 2005 190 192
10. E. Lotero, J.G. Goodwin, D.A. Bruce, K. Suwannakarn, Y. Liu, and D.E. Lopez Catalysis 19 2006 41 83
11. A. Macario, G. Giordano, B. Onida, D. Cocina, A. Tagarelli, and A.M. Giuffrè Applied Catalysis A: General 378 2010 160 168
12. A. Demirbas Progress in Energy and Combustion Science 33 2007 1 18
13. M. Di Serio, R. Tesser, L. Pengmei, and E. Santacesaria Energy Fuels 22 2008 207 217
14. T. Ebiura, T. Echizen, A. Ishikawa, K. Murai, and T. Baba Applied Catalysis A: General 283 2005 111 116
15. A. Kawashima, K. Matsubara, and K. Honda Bioresource Technology 99 2008 3439 3443
16. D.G. Cantrell, L.J. Gillie, A.F. Lee, and K. Wilson Appl. Catal. A 287 2005 183 190
17. W. Xie, H. Peng, and L. Chen Journal of Molecular Catalysis A: Chemical 246 2006 24 32
18. J.L. Shumaker, C. Crofcheck, S.A. Tackett, E. Santillan-Jimenez, T. Morgan, Y. Ji, M. Crocker, and T.J. Toops Applied Catalysis B 82 2008 120 130
19. P.S. Sreeprasanth, R. Srivasta, D. Srinivas, and P. Ratnasamy Applied Catalysis A 314 2006 148 159
20. J. Jitputti, B. Kitiyanan, P. Rangsunvigit, K. Bunyakiat, L. Attanatho, and P. Jenvanitpanjakul Chemical Engineering Journal 116 2006 61 66
21. I.K. Mbaraka, and B.H. Shanks Journal of the American Oil Chemists Society 83 2006 79 91
22. E. Leclercq, A. Finiels, and C. Moreau Journal of the American Oil Chemists Society 78 2001 1161 1165
23. M.G. Kulkarni, and A.K. Dalai Industrial and Engineering Chemistry Research 45 2006 2901 2913
24. J.V. Matson, D.C. Kannan, Green biodiesel, United States Patent #7563,915 (2009).
25. K. Gombotz, R. Parette, G. Austic, D. Kannan, and J.V. Matson Fuel 92 2012 9 15
26. C. Cannilla, G. Bonura, E. Rombi, F. Arena, and F. Frusteri Applied Catalysis A: General 382 2010 158 166
27. ASTM Powder Diffraction Files, Joint Committee on Powder Diffraction Standards, Park Lane, PA, 1979.
28. EN14103: Determination of Total FAME and Linolenic Acid Methyl Ester in Pure Biodiesel (B100).
29. J. Sauer Journal of Molecular Catalysis 54 1989 312 323
30. D.H. Aue, and M.T. Bowers Stabilities of Positive Ions from Equilibrium Gas-Phase Basicity Measurements M.T. Bowers, Gas Phase Ion Chemistry Vol II 1979 Academic: New York 1 51
31. M. Brändle, and J. Sauer Journal of the American Chemical Society 120 1998 1556 1570
32. D. Farcasiu, A. Ghenciu, and J. Qi Li Journal of Catalysis 158 1996 116 127
33. S. Bancquart, C. Vanhove, Y. Pouilloux, and J. Barrault Applied Catalysis A: General 218 2001 1 11
34. M. Daturi, C. Binet, J.C. Lavalley, A. Galtayries, and R. Sporken Physical Chemistry Chemical Physics 1 1999 5717 5724
35. F. Arena, G. Trunfio, J. Negro, and L. Spadaro Materials Research Bulletin 43 2008 539 545
36. D.E. López, K. Suwannakarn, D.A. Bruce, and J.G. Goodwin Jr. Journal of Catalysis 247 2007 43 50
37. J. Lamotte, V. Moravek, M. Bensitel, and J.C. Lavalley Reaction Kinetics and Catalysis Letters 36 1988 113 118
38. D. Bianchi, T.C. Hafik, M. Khalfallah, and S.J. Teicher Applied Catalysis A 123 1995 89 110
39. A. Badri, C. Binet, and J.C. Lavalley Journal of the Chemical Society, Faraday Transactions 93 6 1997 1159 1168
40. M. Hara, M. Kawamura, J.N. Kondo, K. Domen, and K. Maruya Journal of Physical Chemistry 100 1996 14462 14467
41. G. Busca, J. Lamotte, J. Lavallay, and V. Lorenzelli Journal of the American Chemical Society 109 1987 5197 5202
42. I.A. Fisher, and A.T. Bell Journal of Catalysis 184 1999 357 376
43. A.R. McInroy, D.T. Lundie, J.M. Winfield, C.C. Dudman, P. Jones, and D. Lennonm Langmuir 21 2005 11092 11098
44. T. Tabakova, F. Boccuzzi, M. Manzoli, and D. Andreeva Applied Catalysis A 252 2003 385 397
45. C. Binet, and M. Daturi Catalysis Today 70 2001 155 167
46. E. Finocchio, M. Daturi, C. Binet, J.C. Lavalley, and G. Blanchard Catalysis Today 52 1999 53 63
47. M.G. Kulkarni, R. Gopinath, L.C. Meher, and A.K. Dalai Green Chemistry 8 2006 1056 1062
48. T. Ebiura, T. Echizen, A. Ishikawa, K. Murai, and T. Baba Applied Catalysis A 283 2005 111 116
49. H. Hattori Chemical Reviews 95 1995 537 550