Origin of anomalous activities for electrocatalysts in alkaline electrolytes

Journal of Physical Chemistry C

Volumn 116, Issue 42, 2012, Pages 22231-22237

  Subbaraman, Ram ^a   Danilovic, N ^a   Lopes, P P ^a,b   Tripkovic, D ^a   Strmcnik, D ^a   Stamenkovic, V R ^a   Markovic, N M ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

3D TRANSITION METALS; ALKALINE ELECTROLYTES; ANOMALOUS ACTIVITY; BENEFICIAL EFFECTS; CATALYTIC SITES; CO OXIDATION; ELECTROCATALYTIC REACTIONS; EXTENDED SURFACES; HYDROGEN EVOLUTION REACTIONS; HYDROGEN OXIDATION REACTION; OXYGEN REDUCTION REACTION; REACTION ACTIVITY;

ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTROLYTIC REDUCTION; HYDROGEN; IMPURITIES; PLATINUM; SCANNING TUNNELING MICROSCOPY; THREE DIMENSIONAL COMPUTER GRAPHICS; TRANSITION METAL COMPOUNDS; TRANSITION METALS;

ELECTROLYTES;

EID: 84867858726     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp3075783     Document Type: Article

References (26)

1. Marković, N. M.; Ross, P. N. Surf. Sci. Rep. 2002, 45, 117
2. Vielstich, W.; Lamm, A.; Gasteiger, H. A. Handbook of Fuel Cells: Fundamentals, Technology, and Applications; John Wiley & Sons: New York, 2003.
3. McLean, G. F.; Niet, T.; Prince-Richard, S.; Djilali, N. Int. J. Hydrogen Energy 2002, 27, 507
4. Spendelow, J. S.; Wieckowski, A. Phys. Chem. Chem. Phys. 2007, 9, 2654
5. Pivovar, B.; Fedkiw, P.; Mantz; Alkaline Membrane Fuel Cell Workshop Final Report, Phoenix, AZ, 2006; 1-13; (http://www1.eere.energy.gov/ hydrogenandfuelcells/pdfs/amfc-dec2006-workshop-report.pdf).
6. Merle, G.; Wessling, M.; Nijmeijer, K. J. Membr. Sci. 2011, 377, 1
7. Lasia, A. In Handbook of Fuel Cells: Fundamentals, Technology and Applications; Vielstich, W.; Lamm, A.; Gasteiger, H. A., Eds.; Wiley: New York, 2003; Vol. 2, p 416.
8. Pletcher, D.; Walsh, F. Industrial Electrochemistry; Springer: New York, 1990.
9. Trasatti, S.; Transition MetalOxides: Versatile Materials for Electrocatalysis, In Electrochemistry of novel materials. Lipkowski, J.; Ross, P. N., Eds.; VCH: New York, 1994.
10. Strmcnik, D.; van der Vliet, D. F.; Chang, K. C.; Komanicky, V.; Kodama, K.; You, H.; Stamenkovic, V. R.; Marković, N. M. J. Phys. Chem. Lett. 2012, 2, 2733
11. Strmcnik, D.; Kodama, K.; Van der Vliet, D.; Greeley, J.; Stamenkovic, V. R.; Marković, N. M. Nat. Chem. 2009, 1, 466
12. Sitta, E.; Batista, B. C.; Varela, H. Chem. Commun. 2011, 47, 3775
13. Danilovic, N.; Subbaraman, R.; Strmcnik, D.; Paulikas, A.; Myers, D.; Stamenkovic, V.; Markovic, N. Electrocatalysis 2012, 1-9
14. Subbaraman, R.; Tripkovic, D.; Strmcnik, D.; Chang, K. C.; Uchimura, M.; Paulikas, A. P.; Stamenkovic, V.; Markovic, N. M. Science 2011, 334, 1256
15. Angerstein-Kozlowska, H.; Conway, B. E.; Barnett, B.; Mozota, J. J. Electroanal. Chem. Interfacial Electrochem. 1979, 100, 417
16. Conway, B. E.; Tilak, B. V. Electrochim. Acta 2002, 47, 3571
17. Conway, B. E.; Barber, J.; Morin, S. Electrochim. Acta 1998, 44, 1109
18. Spendelow, J. S.; Goodpaster, J. D.; Kenis, P. J. A.; Wieckowski, A. J. Phys. Chem. B 2006, 110, 9545
19. Mayrhofer, K. J. J.; Crampton, A. S.; Wiberg, G. K. H.; Arenz, M. J. Electrochem. Soc. 2008, 155, P78
20. van der Vliet, D.; Strmcnik, D. S.; Wang, C.; Stamenkovic, V. R.; Markovic, N. M.; Koper, M. J. Electroanal. Chem. 2010, 647, 29
21. Markovic, N. M.; Schmidt, T. J.; Grgur, B. N.; Gasteiger, H. A.; Behm, R. J.; Ross, P. N. J. Phys. Chem. B 1999, 103, 8568
22. Tripković, A. V.; Popović, K. D.; Lović, J. D. J. Serb. Chem. Soc. 2001, 66, 825
23. Subbaraman, R.; Tripkovic, D.; Chang, K.-C.; Strmcnik, D.; Paulikas, A. P.; Hirunsit, P.; Chan, M.; Greeley, J.; Stamenkovic, V.; Markovic, N. M. Nat. Mater. 2012, 11, 550
24. Mayrhofer, K. J. J.; Juhart, V.; Hartl, K.; Hanzlik, M.; Arenz, M. Angew. Chem., Int. Ed. 2009, 48, 3529
25. Mayrhofer, K. J. J.; Wiberg, G. K. H.; Arenz, M. J. Electrochem. Soc. 2008, 155, P1
26. Petrii, O. A.; Tsirlina, G. A. Electrochim. Acta 1994, 39, 1739