LSM-YSZ interactions and anode delamination in solid oxide electrolysis cells

International Journal of Hydrogen Energy

Volumn 37, Issue 22, 2012, Pages 16776-16785

  Keane, Michael ^a   Mahapatra, Manoj K ^a   Verma, Atul ^a   Singh, Prabhakar ^a  

^a University of Connecticut   (United States)

Author keywords

Anode electrolyte interface; Delamination; Lanthanum zirconate; Solid oxide electrolysis cell; Strontium doped lanthanum manganite

Indexed keywords

APPLIED VOLTAGES; CHEMICAL CHANGE; COMPOUND FORMATION; ELECTRICAL PERFORMANCE; ELECTROLYTE SURFACES; LANTHANUM ZIRCONATE; MICRO-STRUCTURAL; MICROSTRUCTURAL ANALYSIS; MORPHOLOGICAL CHANGES; SOLID OXIDE ELECTROLYSIS CELLS; STRONTIUM DOPED LANTHANUM MANGANITES; VOLTAGE CONDITIONS;

CHEMICAL ANALYSIS; DELAMINATION; ELECTROLYTIC CELLS; GRAIN BOUNDARIES; LANTHANUM; LANTHANUM ALLOYS; LANTHANUM OXIDES;

ELECTROLYTES;

EID: 84867856937     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.08.104     Document Type: Article

References (33)

1. R. Ramachandran, and R.K. Menon An overview of industrial uses of hydrogen Int J Hydrogen Energy 23 7 1999 593 598
2. R. Elder, and R.W.K. Allen Nuclear heat for hydrogen production: coupling a very high/high temperature reactor to a nuclear power plant Prog Nucl Energy 51 2009 500 525
3. J.E. O'Brien, M.G. McKellar, E.A. Harvego, and C.M. Stoots High-temperature electrolysis for large-scale hydrogen and syngas production from nuclear energy - summary of system simulation and economics analyses Int J Hydrogen Energy 35 2010 4808 4819
4. 3 with enhanced oxygen electrode performance Int J Hydrogen Energy 35 2010 3221 3226
5. J.R. Mawdsley, J.D. Carter, A.J. Kropf, B. Yildiz, and V.A. Maroni Post-test evaluation of oxygen electrodes from solid oxide electrolysis stacks Int J Hydrogen Energy 34 2009 4198 4207
6. J.E. O'Brien, C.M. Stoots, J.S. Herring, and J.J. Hartvigsen Performance of planar high-temperature electrolysis stacks for hydrogen production from nuclear energy Nucl Technol 158 2007 118 131
7. 3 as contact layer on the solid oxide electrolysis cell anode J Electrochem Soc 157 3 2010 B441 B448
8. Ge L, Verma A, Goettler R, Lovett D, Singh Raman RK, Singh P. Oxide scale morphology and Cr evaporation characteristics of alloys for balance of plant applications in solid oxide fuel cells. Metall Mater Trans A, submitted for publication.
9. S.D. Ebbesen, C. Graves, A. Hauch, S.H. Jensen, and M. Mogensen Poisoning of solid oxide electrolysis cells by Impurities J Electrochem Soc 157 10 2010 B1419 B1429
10. P. Singh, and S.D. Vora Vapor phase silica transport during SOFC operation at 1000°C Ceram Eng Sci Proc 26 4 2005 99 110
11. K. Zhang, M.K. Mahapatra, A. Verma, L. Ge, S. Bhowmick, and P. Singh Long term stability of Ni-YSZ SOFC anode 2010 European Fuel Cell Forum Lucerne, Switzerland
12. R. Hino, K. Haga, H. Aita, and K. Sekita R&D on hydrogen production by high-temperature electrolysis of steam Nucl Eng Des 233 2004 363 375
13. A. Momma, T. Kato, Y. Kaga, and S. Nagata Polarization behavior of high temperature solid oxide electrolysis cells (SOEC) J Ceram Soc Jpn 105 5 1997 369 373
14. 3 under anodic current Ionics 2 1996 184 189
15. J. Guan, N. Minh, B. Ramamurthi, J. Ruud, J. Hong, and P. Riley High performance flexible reversible solid oxide fuel cell. Final technical report, performed under DOE cooperative agreement DE-FC36-04GO14351 2004 2006 GE Global Research Center Torrance, CA.
16. H. Lim, and A.V. Virkar A study of solid oxide fuel cell stack failure by inducing abnormal behavior in a single cell test J Power Sources 185 2008 790 800
17. A.V. Virkar, J. Nachlas, A.V. Joshi, and J. Diamond Internal precipitation of molecular oxygen and electromechanical failure of zirconia solid electrolytes J Am Ceram Soc 73 11 1990 3382 3390
18. R. Knibbe, M.L. Traulsen, A. Hauch, S.D. Ebbesen, and M. Mogensen Solid oxide electrolysis cells: degradation at high current densities J Electrochem Soc 157 8 2010 B1209 B1217
19. M.S. Sohal, J.E. O'Brien, C.M. Stoots, J.S. Herring, J.J. Hartvigsen, and D. Larsen Critical causes of degradation in integrated laboratory scale cells during high-temperature electrolysis. INL/EXT-09-16004 prepared for the US May 2009 Department of Energy, Office of Nuclear Energy, Under DOE Idaho Operations Office, Contract DE-AC07-05ID14517, Idaho National Laboratory Idaho Falls, ID
20. 3 oxygen electrodes of solid oxide electrolysis cells Int J Hydrogen Energy 36 2011 10541 10549
21. 2(g)YSZ system Solid State Ionics 111 1998 185 218
22. T.P. Holme, R. Pornprasertsuk, and F.B. Prinz Interpretation of low temperature solid oxide fuel cell electrochemical impedance spectra J Electrochem Soc 157 1 2010 B64 B70
23. 3-δ electrodes Solid State Ionics 111 1998 125 134
24. S.P. Jiang, J.G. Love, J.P. Zhang, M. Huong, Y. Ramprakash, and A.E. Hughes The electrochemical performance of LSM/zirconia-yttria interface as a function of a-site non-stoichiometry and cathodic current treatment Solid State Ionics 121 1999 1 10
25. M. Backhaus-Ricoult, K. Adib, T. St. Clair, B. Luerssen, L. Gregoratti, and A. Barinov In-situ study of operating SOFC LSM/YSZ cathodes under polarization by photoelectron microscopy Solid State Ionics 179 2008 891 895
26. M. Liang, B. Yu, M. Wen, J. Chen, J. Xu, and Y. Zhai Preparation of LSM-YSZ composite powder for anode of solid oxide electrolysis cell and its activation mechanism J Power Sources 190 2009 341 345
27. J.I. Gazzarri, and O. Kesler Non-destructive delamination detection in solid oxide fuel cells J Power Sources 167 2007 430 441
28. 3-YSZ interface in SOFC. Ph.D. dissertation. ETH Zurich; 2005.
29. 7 formed at ceramic electrode/YSZ contacts J Mater Sci 28 1993 3809 3815
30. A.V. Virkar Mechanism of oxygen electrode delamination in solid oxide electrolyzer cells Int J Hydrogen Energy 35 2010 9527 9543
31. M. De Ridder, R.G. van Welzenis, A.W. Denier van der Gon, H.H. Brongersma, S. Wulff, and W.-F. Chu Subsurface segregation of yttria in yttria-stabilized zirconia J Appl Phys 92 6 2002 3056 3064
32. 2 Solid State Ionics 70/71 1994 59 64
33. W.W. Mullins Theory of thermal grooving J Appl Phys 28 3 1957 333 339