Mechanistic investigation of the nickel-catalyzed Suzuki reaction of N, O-acetals: Evidence for boronic acid assisted oxidative addition and an iminium activation pathway

Journal of the American Chemical Society

Volumn 134, Issue 41, 2012, Pages 16967-16970

  Sylvester, Kevin T ^a   Wu, Kevin ^a   Doyle, Abigail G ^a  

^a PRINCETON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PATHWAY; BORONIC ACID; ELECTROPHILES; IMINIUM; KINETIC ISOTOPE EFFECTS; LEWIS ACID; LOW-VALENT; OXIDATIVE ADDITIONS; SUZUKI COUPLING REACTION; SUZUKI REACTION;

CHEMICAL REACTIONS; ISOTOPES; TRANSITION METALS;

ORGANOMETALLICS;

ACETAL DERIVATIVE; BORONIC ACID DERIVATIVE; LEWIS ACID; NICKEL; QUINOLINE;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; OXIDATION; STEREOCHEMISTRY; SUZUKI REACTION;

ACETALS; BORONIC ACIDS; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; NICKEL; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; QUINOLINES;

EID: 84867507022     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3079362     Document Type: Article

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