Thermal transformation of polyacrylonitrile deposited on SBA-15 type silica: Effect on adsorption capacity of methyl-ethyl ketone vapor

Journal of Thermal Analysis and Calorimetry

Volumn 110, Issue 1, 2012, Pages 119-125

  Janus, Rafał ^a   Natkański, Piotr ^a   Wach, Anna ^a   Drozdek, Marek ^a   Piwowarska, Zofia ^a   Cool, Pegie ^b   Kuśtrowski, Piotr ^a  

^a JAGIELLONIAN UNIVERSITY   (Poland)

^b UNIVERSITY OF ANTWERP   (Belgium)

Author keywords

Adsorption of volatile organic compounds; Diffuse reflectance Fourier transform spectroscopy; SBA 15 support; Thermal transformation of polyacrylonitrile; Thermogravimetry; X ray photoelectron spectroscopy

Indexed keywords

ADSORPTION CAPACITIES; AQUEOUS SUSPENSIONS; CARBONIZATION TEMPERATURES; DIFFUSE REFLECTANCE INFRARED FOURIER TRANSFORM SPECTROSCOPIES; FOURIER TRANSFORM SPECTROSCOPY; LOW TEMPERATURE TRANSFORMATIONS; MESOPOROUS SILICA; POLYMER CHAINS; PRECIPITATION POLYMERIZATIONS; SBA-15 SUPPORTS; SORPTION CAPACITIES; STRUCTURAL CHANGE; THERMAL TRANSFORMATIONS; THERMALLY INDUCED;

ADSORPTION; CARBONIZATION; CYCLIZATION; DEPOSITS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; KETONES; PHOTOELECTRONS; REFLECTION; SILICA; THERMOGRAVIMETRIC ANALYSIS; VAPORS; VOLATILE ORGANIC COMPOUNDS; X RAY PHOTOELECTRON SPECTROSCOPY;

POLYACRYLONITRILES;

EID: 84867497443     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-011-2157-6     Document Type: Conference Paper

References (23)

1. Ryu Z, Rong H, Zheng J, Wang M, Zhang B. Microstructure and chemical analysis of PAN-based activated carbon fibers prepared by different activation methods. Carbon. 2002;40:1144-7.
2. Sun J, Wang Q. Effects of activation temperature on the properties and structure of PAN-based activated carbon hollow fiber. J Appl Polym Sci. 2006;100:3778-83.
3. Chiang YC, Lee CC, Lee HC. Characterization of microstructure and surface properties of heat-treated PAN-and rayon-based activated carbon fibers. J Porous Mater. 2007;14:227-37.
4. Szychowski D, Pacewska B, Makomaski G, Zieliński J, Ciesińska W, Brzozowska T. Adsorption and DSC study of mineral-carbon sorbents obtained from coal tar pitch-polymer compositions. J Therm Anal Calorim. 2011. doi: 10.1007/s10973-010-1257-z.
5. 2 adsorptive properties of activated carbons prepared from polyacrylonitrile and its blends with coal-tar pitch. Micropor Mesopor Mater. 2009;118:163-8.
6. Lu CY, Wey MY. Simultaneous removal of VOC and NO by activated carbon impregnated with transition metal catalysts in combustion flue gas. Fuel Proc Technol. 2007;88:557-67.
7. Huang G, Shi JX, Langrish TAG. Removal of Cr(VI) from aqueous solution using activated carbon modified with nitric acid. Chem Eng J. 2009;152:434-9.
8. Molenda M, Dziembaj R, Piwowarska Z, Drozdek M. A new method of coating powdered supports with conductive carbon films. J Therm Anal Calorim. 2007;88:503-6.
9. Gribanov AV, Sazanov YN. Polyacrylonitrile: Carbonization problems. Russ J Appl Chem. 2008;81:919-32.
10. Kuśtrowski P, Janus R, Kochanowski A, Chmielarz L, Dudek B, Piwowarska Z, Michalik M. Adsorption properties of carbonized polyacrylonitrile deposited on γ-alumina and silica gel by precipitation polymerization. Mater Res Bull. 2010;45:787-93.
11. Van Bavel E, Cool P, Aerts K, Vansant EF. Plugged Hexagonal templated silica (PHTS): an in-depth study of the structural characteristics. J Phys Chem B. 2004;108:5263-8.
12. Janus R, Kuśtrowski P, Dudek B, Piwowarska Z, Kochanowski A, Michalik M, Cool P. Removal of methyl-ethyl ketone vapor on polyacrylonitrile- derived carbon/mesoporous silica nanocomposite adsorbents. Micropor Mesopor Mater. 2011;145:65-73.
13. Barbosa MN, Araujo AS, Galvao LPFC, Silva EFB, Santos AGD, Luz GE, Fernandes VJ. Carbon dioxide adsorption over DIPA functionalized MCM-41 and SBA-15 molecular sieves. J Therm Anal Calorim. 2011;106:779-82.
14. Xue T, McKinney M, Wilkie C. The thermal degradation of polyacrylonitrile. Polym Degrad Stab. 1997;58:193-202.
15. Jing M, Wang C, Wang Q, Bai Y, Zhu B. Chemical structure evolution and mechanism during pre-carbonization of PAN-based stabilized fiber in the temperature range of 350-600 °C. Polym Degrad Stab. 2007;92:1737-42.
16. Rahaman MSA, Ismail AF, Mustafa A. A review of heat treatment on polyacrylonitrile fiber. Polym Degrad Stab. 2007;92:1421-32.
17. Katok KV, Tertykh VA, Yanishpolskii VV, Ragulya AV, Klimenko VP, Klymchuk DO. Synthesis and investigation of barium titanate nanoparticles covered with silica shell. J Therm Anal Calorim. 2010;101:725-8.
18. Setnescu R, Jipa S, Setnescu T, Kappel W, Kobayashi S, Osawa Z. IR and X-ray characterization of the ferromagnetic phase of pyrolysed polyacrylonitrile. Carbon. 1999;37:1-6.
19. Wu CR, Salaneck WR. X-ray photoelectron spectroscopy of polyacrylonitrile. Synth Met. 1986;16:147-59.
20. Wang PH, Hong KL, Zhu QR. Surface analysis of polyacrylonitrile-based activated carbon fibers by X-ray photoelectron spectroscopy. J Appl Polym Sci. 1996;62:1987-91.
21. Pels JR, Kapteijn F, Moulijn JA, Zhu Q, Thomas KM. Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis. Carbon. 1995;33:1641-53.
22. Weidenthaler C, Lu AH, Schmidt W, Schüth F. X-ray photoelectron spectroscopic studies of PAN-based ordered mesoporous carbons (OMC). Micropor Mesopor Mater. 2006;88:238-43.
23. László K, Tombácz E, Josepovits K. Effect of activation on the surface chemistry of carbons from polymer precursors. Carbon. 2001;39:1217-28.