Thin films of intumescent flame retardant-polyacrylamide and exfoliated graphene oxide fabricated via layer-by-layer assembly for improving flame retardant properties of cotton fabric

Industrial and Engineering Chemistry Research

Volumn 51, Issue 38, 2012, Pages 12355-12366

  Huang, Guobo ^a   Yang, Jianguo ^a   Gao, Jianrong ^b   Wang, Xu ^b  

^a TAIZHOU UNIVERSITY   (China)

^b ZHEJIANG UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLAMIDES; BI-LAYER; CONE CALORIMETER; FLAME RETARDANT COATINGS; FLAME RETARDANT PROPERTIES; GRAPHENE OXIDES; HIGH HOMOGENEITY; HYDROGEN INTERACTION; HYDROPHOBIC ASSOCIATION; LAYER-BY-LAYER ASSEMBLIES; LESS FLAMMABLE; LINEAR GROWTH; PEAK HEAT RELEASE RATES; SCANNING ELECTRONIC MICROSCOPY; SEM IMAGE; TIME TO IGNITION;

ACRYLIC MONOMERS; AMIDES; ATOMIC FORCE MICROSCOPY; COTTON FABRICS; HYDROGEN; PROTECTIVE COATINGS; THERMOGRAVIMETRIC ANALYSIS; ULTRATHIN FILMS;

FLAME RETARDANTS;

EID: 84867487988     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie301911t     Document Type: Article

References (37)

1. Siriviriyanun, A.; O'Rear, E. A.; Yanumet, N. Self-extinguishing cotton fabric with minimal phosphorus deposition. Cellulose 2008, 15, 731-737.
2. Chang, S. C.; Condon, B.; Graves, E.; Uchimiya, M.; Fortier, C.; Easson, M.; Wakelyn, P. Flame retardant properties of triazine phosphonates derivative with cotton fabric. Fibers Polym. 2011, 12, 334-339.
3. Yang, H.; Yang, C. Q. Flame retardant finishing of Nylon/cotton blend fabric using a hydroxy-functional organophosphorus oligomer. Ind. Eng. Chem. Res. 2008, 47, 2160-2165.
4. Li, Y. C.; Mannen, S.; Morgan, A. B.; Chang, S.; Yang, Y. H.; Condon, B.; Grunlan, J. C. Intumescent all-polymer multilayer nanocoating capable of extinguishing flame on fabric. Adv. Mater. 2011, 23, 3926-3931.
5. Yuan, H. X.; Xing, W. Y.; Zhang, P.; Song, L.; Hu, Y. Functionalization of cotton with UV-cured flame retardant coatings. Ind. Eng. Chem. Res. 2012, 51, 5394-5401.
6. Alongi, J.; Ciobanu, M.; Malucelli, G. Cotton fabric treated with hybrid organic-inorganic coatings obtained through dual-cure processes. Cellulose 2011, 18, 1335-1348.
7. Li, Y. C.; Schulz, J.; Grunlan, J. C. Polyelectrolytes/nanosilicate thin-film assemblies: influence of pH on growth, mechanical behavior, and flammability. ACS Appl. Mater. Interfaces 2009, 1, 2338-2347.
8. Li, Y. C.; Schulz, J.; Mannen, S.; Delhom, C.; Condon, B.; Chang, S. C.; Zammarano, M.; Grunlan, J. C. Flame retardant behavior of polyelectrolytes-clay thin film assemblies on cotton fabric. ACS Nano 2010, 4, 3325-3337.
9. Laachachi, A.; Ball, V.; Apaydin, K.; Toniazzo, V.; Ruch, D. Diffusion of polyphosphates into (poly(allylamine)-montmorillonite) multilayer films: flame retardant-intumescent films with improved oxygen barrier. Langmuir 2011, 27, 13789-11077.
10. Laufer, G.; Carosio, F.; Martinez, R.; Camino, G.; Grunlan, J. C. Growth and fire resistance of colloidal silica-polyelectrolite thin film assemblies. J. Colloid Interface Sci. 2011, 356, 69-77.
11. Li, Y. C.; Mannen, S.; Schulz, J.; Jaime, C.; Grunlan, J. C. Growth and fire protection behavior of POSS-based multilayer thin films. J. Mater. Chem. 2011, 21, 3060-3069.
12. Carosio, F.; Laufer, G.; Alongi, J.; Camino, G.; Grunlan., J. C. Layer by layer assembly of silica-based flame retardant thin film on PET fabric. Polym. Degrad. Stab. 2011, 96, 745-750.
13. Carosio, F.; Alongi, J.; Malucelli, G. α-Zirconium phosphatebased nanoarchitectures on PET fabrics through layer-by-layer assembly: morphology, thermal stability and flame retardancy. J. Mater. Chem. 2011, 21, 10370-10376.
14. Carosio, F.; Alongi, J.; Malucelli, G. Layer by layer ammonium polyphosphate-based coatings for flame retardancy of polyester-cotton blends. Carbohydr. Polym. 2012, 88, 1460-1469.
15. Decher, G. Fuzzy nanoassemblies: toward layered polymeric multicomposites. Science 1997, 277, 1232-1237.
16. Jiang, C.; Tsukruk, V. V. Free standing nanostructures via layerby- layer assembly. Adv. Mater. 2006, 18, 829-840.
17. Lutkenhaus, J. L.; Olivetti, E. A.; Verploegen, E. A.; Cord, B. M.; Sadoway, D. R.; Hammond, P. T. Anisotropic structure and transport in self-assembled layered polymer-clay nanocomposites. Langmuir 2007, 23, 8515-8521.
18. Podsiadlo, P.; Kaushik, A. K.; Arruda, E. M.; Waas, A. M.; Shim, B. S.; Xu, J. D.; Nandivada, H.; Pumplin, B. G.; Lahann, J.; Ramamoorthy, A.; Kotov, N. A. Ultrastrong and stiff layered polymer nanocomposites. Science 2007, 318, 80-83.
19. Han, J. B.; Lu, J.; Wei, M.; Wang, Z. L.; Duan, X. Heterogeneous ultrathin films fabricated by alternate assembly of exfoliated layered double hydroxides and polyanion. Chem. Commun. 2008, 41, 5188- 5190.
20. Srivastava, S.; Kotov, N. A. Composite layer-by-layer (LBL) assembly with inorganic nanoparticles and nanowires. Acc. Chem. Res. 2008, 41, 1831-1841.
21. Wu, J. H.; Tang, Q. W.; Sun, H.; Lin, J. M.; Ao, H. Y.; Huang, M. L.; Huang, Y. F. Conducting film from graphite oxide nanoplatelets and poly(acrylamide) by layer-by-layer self-assembly. Langmuir 2008, 24, 4800-4805.
22. Huang, S.; Cen, X.; Peng, H. D.; Guo, S. Z.; Wang, W. Z.; Liu, T. X. Heterogeneous ultrathin films of poly(vinyl alcohol)/layered double hydroxide and montmorillonite nanosheets via layer-by-layer assembly. J. Phys. Chem. B 2009, 113, 15225-15230.
23. Zhao, X.; Zhang, Q. H.; Hao, Y. P.; Li, Y. Z.; Fang, Y.; Chen, D. J. Alternate multilayer films of poly(vinyl alcohol) and exfoliated graphene oxide fabricated via a facial layer-by-layer assembly. Macromolecules 2010, 43, 9411-9416.
24. Huang, G. B.; Gao, J. R.; Wang, X.; Liang, H. D.; Ge, C. H. How can graphene reduce the flammability of polymer nanocomposites. Mater. Lett. 2012, 66, 187-189.
25. Huang, G. B.; Liang, H. D.; Wang, Y.; Wang, X.; Gao, J. R.; Fei, Z. D. Combination effect of melamine polyphosphate and graphene on flame retardant properties of poly(vinyl alcohol). Mater. Chem. Phys. 2012, 132, 520-528.
26. Wang, X.; Song, L.; Yang, H. Y.; Lu, H. D.; Hu, Y. Synergistic effect of graphene on antidripping and fire resistance of intumescent flame retardant poly(butylene succinate) composites. Ind. Eng. Chem. Res. 2011, 50, 5376-83.
27. Guo, Y. Q.; Bao, C. L.; Song, L.; Yuan, B. H.; Hu, Y. In situ polymerization of graphene, graphite oxide, and functionalized graphite oxide into epoxy resin and comparison study of on-theflame behavior. Ind. Eng. Chem. Res. 2011, 50, 7772-7783.
28. Huang, G. B.; Chen, S. Q.; Tang, S. W.; Gao, J. R. A novel intumescent flame retardant-functionalized graphene: nanocomposite synthesis, characterization, and flammability properties. Mater. Chem. Phys. 2012, 135, 947-956.
29. Huang, G. B.; Gao, J. R.; Li, Y. J.; Han, L.; Wang, X. Functionalizing nano-montmorillonites by modified with intumescent flame retardant: preparation and application in polyurethane. Polym. Degrad. Stab. 2010, 95, 245-253.
30. Kovtyukhova, N. I.; Ollivier, P. J.; Martin, B. R.; Mallouk, T. E.; Chizhik, S. A.; Buzaneva, E, V.; Gorchinskiy, A. D. Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations. Chem. Mater. 1999, 11, 771-778.
31. Xu, Z.; Gao, C. In situ polymerization approach to graphenereinforced nylon-6 composites. Macromolecules 2010, 43, 6716-6723.
32. Shi, Y.; Peterson, S.; Sogah, D. Y. Surfactant-free method for the synthesis of poly(vinyl acetate) masterbatch nanocomposites as a route to ethylene vinyl acetate/silicate nanocomposites. Chem. Mater. 2007, 19, 1552-1564.
33. Gao, B. J.; Guo, H. P.; Wang, J.; Zhang, Y. Preparation of hydrophobic association polyacrylamide in a new micellar copolymerization system and its hydrophobically associative property. Macromolecules 2008, 41, 2890-2897.
34. Kim, H.; Abdala, A. A.; Macosko, C. W. Graphene/polymer nanocomposites. Macromolecules 2010, 43, 6515-6530.
35. Leung, W. M.; Axelson, D. E.; Van Dyke, J. D. Thermal degradation of polyacrylamide and poly(acrylamide-co-acrylate). J. Polym. Sci., Part A: Polym. Chem. 1987, 25, 1825-1846.
36. Zhao, X.; Zhang, Q.; Chen, D. J.; Lu, P. Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites. Macromolecules 2010, 43, 2357-2363.
37. Lerf, A.; Buchsteiner, A.; Pieper, J.; Schottl, S.; Dekany, I.; Szabo, T.; Boehm, H. P. Hydratation behavior and dynamics of water molecules in graphite oxide. J. Phys. Chem. Solids 2006, 67, 1106- 1110.