Acetic acid internal reforming in a solid oxide fuel cell-reactor using Cu-CeO 2 anodic composites

International Journal of Hydrogen Energy

Volumn 37, Issue 21, 2012, Pages 16722-16732

  Kaklidis, N ^a   Besikiotis, V ^b   Pekridis, G ^a   Marnellos, G E ^a,c  

^a UNIVERSITY OF WESTERN MACEDONIA   (Greece)

^b UNIVERSITY OF OSLO   (Norway)

^c Centre for Research Technology Hellas   (Greece)

Author keywords

Acetic acid internal reforming; Cu CeO 2 anodes; Direct hydrocarbon SOFC; Electro catalytic hydrogen production

Indexed keywords

AC IMPEDANCE MEASUREMENT; CARBONACEOUS DEPOSITS; CATALYST SURFACES; CELL TEMPERATURE; CHARGE TRANSFER PROCESS; CLOSED CIRCUIT; DECOMPOSITION REACTION; DISSOCIATIVE ADSORPTION; EFFECT OF TEMPERATURE; ELECTROCHEMICAL MEMBRANE REACTORS; ELECTROCHEMICAL PERFORMANCE; ELECTRODE PERFORMANCE; FUEL CELL MODES; INTERFACIAL RESISTANCES; INTERNAL REFORMING; KINETIC EXPERIMENT; NEUTRAL SPECIES; OHMIC LOSS; OPEN CIRCUIT CONDITIONS; OVER POTENTIAL; OVERALL EFFICIENCY; POLARIZATION CONDITIONS; PRODUCTION OF HYDROGEN; REACTION MECHANISM; REVERSE WATER-GAS SHIFT REACTION; SOFC REACTORS; SOLID OXIDE; SYN-GAS; TRIPLE PHASE BOUNDARY;

ACETIC ACID; ACETONE; ADSORPTION; ANODES; BIOREACTORS; CATALYST ACTIVITY; CHARGE TRANSFER; EFFLUENTS; FISCHER-TROPSCH SYNTHESIS; HYDROCARBONS; HYDROGEN; HYDROGEN PRODUCTION; PH; SOLID OXIDE FUEL CELLS (SOFC); STEAM REFORMING; SYNTHESIS GAS;

ELECTROCHEMICAL ELECTRODES;

EID: 84867401542     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.02.030     Document Type: Conference Paper

References (33)

1. S. Thaicharoensutcharittham, V. Meeyoo, B. Kitiyanan, P. Rangsunvigit, and T. Rirksomboon Hydrogen production by steam reforming of acetic acid over Ni-based catalysts Catal Today 164 2011 257 261
2. G.E. Marnellos, C. Athanasiou, S.S. Makridis, and E.S. Kikkinides Integration of hydrogen energy technologies in autonomous power systems Ch. 3, pp. 23-82 N. Lymberopoulos, E.I. Zoulias, Hydrogen based autonomous power systems. Technoeconomic analysis of the integration of hydrogen in autonomous power systems 2008 Springer 978-1-84800-246-3
3. K. Takanabe, K.I. Aika, K. Seshan, and L. Lefferts Sustainable hydrogen from bio-oil - steam reforming of acetic acid as a model oxygenate J Catal 227 2004 101 108
4. A.C. Basagiannis, and X.E. Verykios Reforming reactions of acetic acid on nickel catalysts over a wide temperature range Appl Catal B 308 2006 182 193
5. A.C. Basagiannis, and X.E. Verykios Catalytic steam reforming of acetic acid for hydrogen production Int J Hydrogen Energy 32 2007 3343 3355
6. 3 catalysts Catal Today 127 2007 256 264
7. A.C. Basagiannis, and X.E. Verykios Influence of the carrier on steam reforming of acetic acid over Ru-based catalysts Appl Catal B 82 2008 77 88
8. ECh Vagia, and A.A. Lemonidou Hydrogen production via steam reforming of bio-oil components over calcium aluminate supported nickel and noble metal catalysts Appl Catal A 351 2008 111 121
9. ECh Vagia, and A.A. Lemonidou Investigations on the properties of ceria-zirconia-supported Ni and Rh catalysts and their performance in acetic acid steam reforming J Catal 269 2010 388 396
10. 2 catalysts J Catal 243 2006 263 269
11. N. Kaklidis, G. Pekridis, C. Athanasiou, and G.E. Marnellos Direct electro-oxidation of iso-octane in a solid electrolyte fuel cell Solid State Ionics 192 2011 435 443
12. R.J. Gorte, J.M. Vohs, and S. McIntosh Recent developments on anodes for direct fuel utilization in SOFC Solid State Ionics 175 2004 1 6
13. H. He, J.M. Vohs, and R.J. Gorte Carbonaceous deposits in direct utilization hydrocarbon SOFC anode J Power Sources 144 2005 135 140
14. R.M. Ormerod Solid oxide fuel cells Chem Soc Rev 32 2003 17 28
15. G.J. Saunders, J. Preece, and K. Kendall Formulating liquid hydrocarbon fuels for SOFCs J Power Sources 131 2004 23 26
16. 2, CO, and syngas J Power Sources 141 2005 241 249
17. G.J. Saunders, and K. Kendall Reactions of hydrocarbons in small tubular SOFCs J Power Sources 106 2002 258 263
18. A. Faes, J.M. Fuerbringer, D. Mohamedi, A. Hessler-Wyser, G. Caboche, and J. Van Herle Design of experiment approach applied to reducing and oxidizing tolerance of anode supported solid oxide fuel cell. Part I: microstructure optimization J Power Sources 196 2011 7058 7069
19. C.H. Bartholomew Carbon deposition in steam reforming and methanation Catal Rev Sci Eng 24 1982 67 112
20. 4 and C2 hydrocarbons and carbon deposition on Ni-YSZ cermets J Power Sources 112 2002 588 595
21. K. Sasaki, and Y. Teraoka Equilibria in fuel cell gases. I. Equilibrium compositions and reforming conditions J Electrochem Soc 150 2003 A878 A884
22. R.J. Gorte, H. Kim, and J.M. Vohs Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbon J Power Sources 106 2002 10 15
23. R.J. Gorte, and J.M. Vohs Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbons J Catal 216 2003 477 486
24. S. Park, J.M. Vohs, and R.J. Gorte Direct oxidation of hydrocarbons in a solid-oxide fuel cell Nature 404 2000 265 267
25. R.J. Gorte, S. Park, J.M. Vohs, and C. Wang Anodes for direct oxidation of dry hydrocarbons in a solid-oxide fuel cell Adv Mater 12 2000 1465 1469
26. H.P. He, Y.Y. Huang, J.M. Vohs, and R.J. Gorte Characterization of YSZ-YST composites for SOFC anodes Solid State Ionics 175 2004 171 176
27. Kaklidis N, Pekridis G, Besikiotis V, Athanasiou C, Marnellos GE. Direct electro-oxidation of acetic acid for hydrogen production and power generation in a solid oxide fuel cell reactor. Solid State Ionics, submitted for publication.
28. B.A. Boukamp Linear Kronig-Kramers transform test for immittance data validation J Electrochem Soc 142 1995 1885 1894
29. B.A. Boukamp A nonlinear least squares fit procedure for analysis of immittance data of electrochemical systems Solid State Ionics 20 1986 31 44
30. S.M. Haile, D.L. West, and J. Campbell The role of microstructure and processing on the proton conducting properties of gadolinium-doped barium cerate J Mater Res 13 1998 1576 1595
31. ECh Vagia, and A.A. Lemonidou Thermodynamic analysis of hydrogen production via steam reforming of selected components of aqueous bio-oil fraction Int J Hydrogen Energy 32 2007 212 223
32. J.I. Gazzarri, and O. Kesler Non-destructive delamination detection in solid oxide fuel cells J Power Sources 167 2007 430 441
33. M. Liu, D. Dong, F. Zhao, J. Gao, D. Ding, and X. Liu High-performance cathode-supported SOFCs prepared by a single-step co-firing process J Power Sources 182 2008 585 588