Microwave frequency effects on dielectric properties of some common solvents and on microwave-assisted syntheses: 2-Allylphenol and the C 12-C 2-C 12 Gemini surfactant

Radiation Physics and Chemistry

Volumn 81, Issue 12, 2012, Pages 1885-1895

  Horikoshi, Satoshi ^a   Matsuzaki, Shohei ^a   Mitani, Tomohiko ^b   Serpone, Nick ^c  

^a SOPHIA UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

^c UNIVERSITY OF PAVIA   (Italy)

Author keywords

2 Allylphenol synthesis; 5.8GHz; 915MHz; Frequency effect; Gemini surfactant synthesis; Microwave

Indexed keywords

5.8GHZ; 915MHZ; CLAISEN REARRANGEMENT; COMMON SOLVENTS; DIELECTRIC PARAMETERS; DISSIPATION FACTORS; FREQUENCY EFFECT; GEMINI SURFACTANT; MICROWAVE APPARATUS; MICROWAVE ASSISTED SYNTHESIS; MICROWAVE-ASSISTED; MODEL REACTIONS; NON-POLAR SOLVENTS; ORGANIC SYNTHESIS; SINGLE-MODE RESONANCES; SOLVENT FREE SYNTHESIS; TEMPERATURE DEPENDENCE; TEMPERATURE-TIME PROFILES;

DIELECTRIC LOSSES; ETHANOL; MICROWAVE FREQUENCIES; MICROWAVES; SOLVENTS; SURFACE ACTIVE AGENTS; SYNTHESIS (CHEMICAL);

ORGANIC SOLVENTS;

2 ALLYLPHENOL; ALCOHOL; CARBON; ORGANIC SOLVENT; PHENOL; SOLVENT; SURFACTANT; UNCLASSIFIED DRUG;

ANALYTICAL PARAMETERS; ARTICLE; CHEMICAL MODEL; CLAISEN REARRANGEMENT; FREQUENCY MODULATION; HEATING; HIGH TEMPERATURE; MICROWAVE RADIATION; ORGANIC CHEMISTRY; SYNTHESIS; TEMPERATURE DEPENDENCE; TIME;

EID: 84867211537     PISSN: 0969806X     EISSN: 18790895     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2012.07.011     Document Type: Article

References (15)

1. Agilent Technologies Inc. 2006 Basics of Measuring the Dielectric Properties of Materials, Application Note No. 5989-2589EN.
2. Handbook of Microwave Technology for Food Applications 2001, Marcel Dekker, Inc., NY, USA. A.K. Dalta, R.C. Ananlheswaran (Eds.).
3. Gabriel C., Gabriel S., Grant E.H., Halstead B.S.J., Mingos D.M.P. Dielectric parameters relevant to microwave dielectric heating. Chem. Soc. Rev. 1998, 27:213-223.
4. Horikoshi S., Iida S., Kajitani M., Sato S., Serpone N. Chemical reactions with a novel 5.8-GHz microwave apparatus. 1. Characterization of properties of common solvents and application in a Diels-Alder organic synthesis. Org. Proc. Res. Dev. 2008, 12:257-263.
5. Horikoshi S., Hamamura T., Kajitani M., Yoshizawa-Fujita M., Serpone N. Green chemistry with a Novel 5.8-GHz microwave apparatus prompt one-pot solvent-free synthesis of a major ionic liquid-the 1-butyl-3-methylimidazolium tetrafluoroborate system. Org. Proc. Res. Dev. 2008, 12:1089-1093.
6. Horikoshi S., Matsubara A., Takayama S., Sato M., Sakai F., Kajitani M., Abe M., Serpone N. Characterization of microwave effects on metal-oxide materials: zinc oxide and titanium dioxide. Appl. Catal. B: Environ. 2009, 91:362-367.
7. Horikoshi S., Abe H., Sumi T., Torigoe K., Sakai H., Serpone N., Abe M. Access to small size distributions of nanoparticles by microwave-assisted synthesis. Formation of Ag nanoparticles in aqueous carboxymethylcellulose solutions in batch and continuous-flow reactors. Nanoscale 2011, 3:1697-1702.
8. Horikoshi S., Osawa A., Abe M., Serpone N. On the generation of hot-spots by microwave, electric and magnetic fields and their impact on a microwave-assisted heterogeneous reaction in the presence of metallic Pd nanoparticles on an activated carbon support. J. Phys. Chem. C 2011, 115:23030-23035.
9. Horikoshi, S., Serpone, N. In: de la Hoz, A., Loupy, A. (Eds.), Microwaves Organic Synthesis, 3rd edition. Wiley-VCH Verlag, GmbH, Weinheim, Germany, ISBN:978-3-527-33116-1, in press.
10. Menger F.M., Littau C.A. Gemini-surfactants: synthesis and properties. J. Am. Chem. Soc. 1991, 113:1451-1452.
11. Meredith, R., Ed. 1998. Engineers' Handbook of Industrial Microwave Heating IEE power series, vol. 25, London, UK.
12. Metaxas, A.C., Technical Report ; Available from: (accessed 29. 05. 12). http://www.pueschner.com/downloads/MicrowaveHeating.pdf#search='40680ISMband3390'.
13. Metaxas A.C., Meredith R.J. Industrial Microwave Heating, IEE Power Engineering Series 4 1988, Peter Peregrines Ltd., UK.
14. Nessim I.M., Hamdy A., Osman M.M., Shalaby M.N. Inhibitory effect of some cationic Gemini surfactants for carbon steel in sea water. J. Am. Sci. 2011, 7:78-90.
15. Zana R.J. Dimeric and oligomeric surfactants. Behavior at interfaces and in aqueous solution: a review. J. Colloid Interface Sci. 2002, 248:203-220.