Synthesis, structural characterization, and physical properties of the type-I clathrates A 8Zn 18As 28 (A = K, Rb, Cs) and Cs 8Cd 18As 28

Chemistry of Materials

Volumn 24, Issue 18, 2012, Pages 3596-3603

  He, Hua ^a   Zevalkink, Alex ^b   Gibbs, Zachary M ^c   Snyder, G Jeffrey ^b   Bobev, Svilen ^a  

^a UNIVERSITY OF DELAWARE   (United States)

^b California Institute of Technology   (United States)

^c California Institute of Technology   (United States)

Author keywords

arsenides; clathrates; crystal structure; thermoelectrics

Indexed keywords

ANTIMONIDES; ARSENIDES; CD ATOM; CLATHRATES; HIGH YIELD; OPTICAL ABSORPTION MEASUREMENT; PROPERTY MEASUREMENT; SINGLE CRYSTAL X-RAY DIFFRACTION; STRUCTURAL CHARACTERISTICS; STRUCTURAL CHARACTERIZATION; STRUCTURAL FEATURE; THERMOELECTRICS;

ANTIMONY COMPOUNDS; ARSENIC COMPOUNDS; CRYSTAL STRUCTURE; ELECTRONIC PROPERTIES; HYDRATES; RUBIDIUM; X RAY DIFFRACTION; ZINC;

CESIUM;

EID: 84866693470     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm3020226     Document Type: Article

References (55)

1. Koh, C. A. Chem. Soc. Rev. 2002, 31, 157
2. Sloan, E. D. Nature 2003, 426, 353
3. Kasper, J. S.; Hagenmuller, P.; Pouchard, M.; Cros, C. Science 1965, 150, 1713
4. Cros, C.; Pouchard, M.; Hagenmuller, P. C. R. Acad. Sci. Paris 1965, 260, 4764
5. Gallmeier, P.; Schäfer, H.; Weiss, A. Z. Naturforsch. 1969, 24b, 665
6. Kroener, R.; Peters, K.; von Schnering, H. G.; Nesper, R. Z. Kristallogr. 1998, 213, 667
7. Eisenmann, B.; Schaefer, H.; Zagler, R. J. Less-Common Met. 1986, 118, 43
8. Cordier, G.; Woll, P. J. Less-Common Met. 1991, 169, 291
9. Bobev, S.; Sevov, S. C. J. Solid State Chem. 2000, 153, 92
10. Kovnir, K. A.; Shevelkov, A. V. Russ. Chem. Rev. 2004, 73, 923
11. Beekman, M.; Nolas, G. S. J. Mater. Chem. 2008, 18, 842
12. Rogl, P. Int. Conf. Thermoelectr. 2005, 24, 443
13. Rowe, D. M., Ed.; CRC Handbook of Thermoelectrics; CRC Press: Boca Raton, FL, 1995.
14. Blake, N. P.; Mollnitz, L.; Kresse, G.; Metiu, H. J. Chem. Phys. 1999, 111, 3133
15. Nolas, G. S.; Cohn, J. L.; Slack, G. A.; Schujman, S. B. Appl. Phys. Lett. 1998, 73, 178
16. Kuznetsov, V. L.; Kuznetsova, L. A.; Kaliazin, A. E.; Rowe, D. M. J. Appl. Phys. 2000, 87, 7871
17. Zhang, H.; Borrmann, H.; Oeschler, N.; Candolfi, C.; Schnelle, W.; Schmidt, M.; Burkhardt, U.; Baitinger, M.; Zhao, J.-T.; Grin, Y. Inorg. Chem. 2011, 50, 1250
18. Shi, X.; Yang, J.; Bai, S.; Yang, J.; Wang, H.; Chi, M.; Salvador, J. R.; Zhang, W.; Chen, L.; Wong-Ng, W. Adv. Funct. Mater. 2010, 20, 755
19. Kawaji, H.; Horie, H.; Yamanaka, S.; Ishikawa, M. Phys. Rev. Lett. 1995, 74, 1427
20. Yamanaka, S.; Enishi, E.; Fukuoka, H.; Yasukawa, M. Inorg. Chem. 2000, 39, 56
21. von Schnering, H. G.; Menke, H. Angew. Chem., Int. Ed. Engl. 1972, 11, 43
22. Zaikina, J.; Kovnir, K. A.; Haarmann, F.; Schnelle, W.; Burkhardt, U.; Borrmann, H.; Schwarz, U.; Grin, Y.; Shevelkov, A. V. Chem.-Eur. J. 2008, 14, 5414
23. Dünner, J.; Mewis, A. Z. Anorg. Allg. Chem. 1995, 621, 191
24. Liu, Y.; Wu, L.-M.; Du, S.-W.; Corbett, J. D.; Chen, L. Angew. Chem., Int. Ed. 2009, 48, 5305
25. Xia, S.-Q.; Bobev, S. J. Am. Chem. Soc. 2007, 129, 10011
26. Xia, S.-Q.; Bobev, S. J. Am. Chem. Soc. 2007, 129, 4049
27. Saparov, B.; Xia, S.-Q.; Bobev, S. Inorg. Chem. 2008, 47, 11237
28. Saparov, B.; He, H.; Zhang, X.; Greene, R.; Bobev, S. Dalton Trans. 2010, 39, 1063
29. He, H.; Stearrett, R.; Nowak, E. R.; Bobev, S. Inorg. Chem. 2010, 49, 7935
30. He, H.; Tyson, C.; Bobev, S. Inorg. Chem. 2011, 50, 8375
31. Toberer, E. S.; Zevalkink, A.; Snyder, J. G. J. Mater. Chem. 2011, 21, 15843
32. Beekman, M.; Nolas, G. S. Phys. B 2006, 383, 111
33. Villars, P.; Calvert, L. D., Eds.; Pearson's Handbook of Crystallographic Data for Intermetallic Phases, 2 nd ed.; American Society for Metals: Materials Park, OH, 1991.
34. SMART; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 2003.
35. SAINT NT, Version 6.45; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 2003.
36. Sheldrick, G. M. SADABS; University of Göttingen: Göttingen, Germany, 2003.
37. Sheldrick, G. M. SHELXTL; University of Göttingen: Göttingen, Germany, 2001.
38. Wood, C.; Zoltan, D.; Stapfer, G. Rev. Sci. Instrum. 1985, 56, 719
39. Li, L.-H.; Chen, L.; Li, J.-Q.; Wu, L.-M. Chem. Mater. 2010, 22, 4007
40. Bentien, A.; Nishibori, E.; Paschen, S.; Iversen, B. B. Phys. Rev. B 2005, 71, 144107
41. Alleno, E.; Maillet, G.; Rouleau, O.; Leroy, E.; Godart, C.; Carrillo-Cabrera, W.; Simon, P.; Grin, Y. Chem. Mater. 2009, 21, 1485
42. Kroener, R.; Peters, K.; von Schnering, H. G.; Nesper, R. Z. Kristallogr. 1998, 213, 667
43. Tanaka, T.; Onimaru, T.; Suekuni, K.; Mano, S.; Fukuoka, H.; Yamanaka, S.; Takabatake, T. Phys. Rev. B. 2010, 81, 165110
44. Kauzlarich, S. M., Ed.; Chemistry, Structure, and Bonding of Zintl Phases and Ions; Wiley-VCH: New York, 1996.
45. Blake, N. P.; Bryan, D.; Latturner, S.; Mollnitz, L.; Stucky, G. D.; Metiu, H. J. Chem. Phys. 2001, 114, 10063
46. Pauling, L. The Nature of the Chemical Bond, 3 rd ed.; Cornell University Press: Ithaca, NY, 1960.
47. Kahlert, H.; Schuster, H.-U. Z. Naturforsch. 1976, 31b, 1538
48. Saparov, B.; Bobev, S. Inorg. Chem. 2010, 49, 5173
49. Jung, W.; Lörincz, J.; Ramlau, R.; Borrmann, H.; Prots, Y.; Haarmann, F.; Schnelle, W.; Burkhardt, U.; Baitinger, M.; Grin, Y. Angew. Chem., Int. Ed. 2007, 46, 6725
50. Shatruk, M. M.; Kovnir, K. A.; Shevelkov, A. V.; Presniakov, I. A.; Popovkin, B. A. Inorg. Chem. 1999, 38, 3455
51. Toberer, E. S.; May, A. F.; Snyder, J. G. Chem. Mater. 2010, 22, 624
52. May, A. F.; Toberer, E. S.; Saramat, A.; Snyder, J. G. Phys. Rev. B 2009, 80, 125205
53. Huo, D.; Sasakawa, T.; Muro, Y.; Takabatake, T. Appl. Phys. Lett. 2003, 82, 2640
54. Zheng, W.-Z.; Wang, P.; Wu, L.-M.; Chen, L. Inorg. Chem. 2010, 49, 5890
55. Qiu, P. F.; Yang, J.; Liu, R. H.; Shi, X.; Huang, X. Y.; Snyder, G. J.; Zhang, W.; Chen, L. D. J. Appl. Phys. 2011, 109, 063713