Thermodynamics of manganese oxides: Effects of particle size and hydration on oxidation-reduction equilibria among hausmannite, bixbyite, and pyrolusite

American Mineralogist

Volumn 97, Issue 8-9, 2012, Pages 1291-1298

  Birkner, Nancy ^a   Navrotsky, Alexandra ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Calorimetry; Manganese oxides; Nanomaterials; Phase equilibria; Surface energy; Surface hydration

Indexed keywords

CALORIMETERS; CALORIMETRY; HYDRATION; INTERFACIAL ENERGY; IODINE COMPOUNDS; MANGANESE OXIDE; NANOSTRUCTURED MATERIALS; OXIDES; PARTICLE SIZE; PHASE EQUILIBRIA; PHOSPHORUS COMPOUNDS; SULFUR COMPOUNDS; URANIUM COMPOUNDS;

HAUSMANNITES; HIGH TEMPERATURE OXIDE MELT SOLUTION CALORIMETRY; OXIDATION REDUCTION; PHASE CHANGE; SPINEL PHASE; SURFACE ENTHALPIES; SURFACE HYDRATION; WATER ADSORPTION;

NITROGEN COMPOUNDS;

ADSORPTION; CALORIMETRY; DESORPTION; EXPERIMENTAL MINERALOGY; HIGH TEMPERATURE; HYDRATION; MANGANESE OXIDE; OXIDATION; PARTICLE SIZE; PHASE EQUILIBRIUM; REDUCTION; SPINEL; SURFACE ENERGY; THERMODYNAMICS;

EID: 84866692859     PISSN: 0003004X     EISSN: 19453027     Source Type: Journal    
DOI: 10.2138/am.2012.3982     Document Type: Article

References (45)

1. Boerio-Goates, J., Li, G., Li, L., Walker, T.F., Parry, T., and Woodfield, B.F. (2006) Surface water and the origin of the positive excess specific heat for 7 nm rutile and anatase nanoparticles. Nano Letters, 6, 750-754.
2. Broecker, W.S. and Liu, T. (2001) Rock varnish: Recorder of desert wetness? GSA Today, 11, 4-10.
3. Brunauer, S., Emmett, P.H., and Teller. E. (1938) Adsorption of gases in multimolecular layers. Journal of the American Chemical Society, 60, 309.
4. Castro, R.H.R. and Wang, B. (2011) The hidden effect of interface energies in the polymorphic stability of nanocrystalline titanium dioxide. Journal of the American Ceramic Society, 94, 918-924.
5. Castro, R., Ushakov, S., Gengembre, L., Gouvea, D., and Navrotsky, A. (2006) Surface energy and thermodynamic stability of γ-alumina: Effect of dopants and water. Chemistry of Materials, 18, 1867-1872.
6. Chorover, J., Kretzschmar, R., Garcia-Pichel, F., and Sparks, D.L. (2007) The Critical zone: Where rock meets life: soil biogeochemical processes within the critical zone. Elements, 3, 321-326.
7. FactSage 5.4.1, Therm Factor (2006) CRCT and GTT-Technologies: Montreal, Canada, and Aachen, Germany 2006.
8. Fortin, D. (2004) Geochemistry: Enhanced: What biogenic minerals tell us. Science, 303, 1618-1619.
9. Foster, A.L., Gordon, E.B. Jr., and Parks, G.A. (2003) X-ray absorption fine structure study of As(V) and Se(IV) sorption complexes on hydrous Mn oxides. Geochimica et Cosmochimica Acta, 67, 11, 1937-1953.
10. Fritsch, S. and Navrotsky, A. (1996) Thermodynamic properties of manganese oxides. Journal of the American Ceramic Society, 79, 1761-1768.
11. Fritsch, S., Post, J.E., and Navrotsky, A. (1997) Energetics of low-temperature polymorphs of manganese dioxide and oxyhydroxide. Geochimica et Cosmochimica Acta, 61, 2613-2616.
12. Fritsch, S., Post, J.E., Suib, S.L., and Navrotsky, A. (1998) Thermochemistry of framework and layer manganese dioxide related phases. Chemistry of Materials, 10, 474-479.
13. Guillemet-Fritsch, S., Navrotsky, A., Tailhades, P., Coradin, H., and Wang, M. (2005) Thermochemistry of iron manganese oxide spinels. Journal of Solid State Chemistry, 178, 106-113.
14. Hazen, R.M. and Sverjensky, D.A. (2010) Mineral surfaces, geochemical complexities, and the origins of life. Cold Spring Harbor Perspectives in Biology, 2, a002162.
15. Huebner, J.S. and Sato, M. (1970) The oxygen fugacity-temperature relationships of manganese oxide and nickel oxide buffers. American Mineralogist, 55, 934-952.
16. Kennedy, C., Smith, D.S., and Warren, L.A. (2004) Surface chemistry and relative Ni sorptive capacities of synthetic hydrous Mn oxyhydroxides under variable wetting and drying regimes. Geochimica et Cosmochimica Acta, 68, 3, 443-454.
17. Kirillov, S.A., Aleksandrova, V.S., Lisnycha, T.V., Dzanashvili, D.I., Khainakov, S.A., Garcia, J.R., Visloguzova, N.M., and Pendelyuk, O.I. (2009) Oxidation of synthetic hausmannite (Mn3O4) to manganite (MnOOH). Journal of Molecular Structure, 928, 89-94.
18. Laberty, C., Suib, S.L., and Navrotsky, A. (2000) Effect of framework and layer substitution in manganese dioxide related phases on the energetics. Chemistry of Materials, 12, 1660-1665.
19. Levchenko, A.A., Li, G., Boerio-Goates, J., Woodfield, B.F., and Navrotsky, A. (2006) TiO2 stability landscape: Polymorphism, surface energy, and bound water energetics. Chemistry of Materials, 18, 6324-6332.
20. Ma, Y., Castro, R.H.R., Zhou, W., and Navrotsky, A. (2011) Surface enthalpy and enthalpy of water adsorption of nanocrystalline tin dioxide. Journal of Materials Research, 26, 848-853.
21. Majzlan, J., Navrotsky, A., and Casey, W. H. (2000) Surface enthalpy of boehmite. Clays and Clay Minerals, 48, 699-707.
22. Majzlan, J., Mazeina, L., and Navrotsky, A. (2007) Enthalpy of water adsorption and surface enthalpy of lepidocrocite (g-FeOOH). Geochimica et Cosmochimica Acta, 71, 615-623.
23. Mazeina, L. and Navrotsky, A. (2007) Enthalpy of water adsorption and surface enthalpy of goethite (α-FeOOH) and hematite (α-Fe2O3). Chemistry of Materials, 19, 825-833.
24. Mazeina, L., Deore, S., and Navrotsky, A. (2006) Energetics of bulk and nano-akaganeite, β-FeOOH: Enthalpy of formation, surface enthalpy, and enthalpy of water adsorption. Chemistry of Materials, 18, 1830-1838.
25. McHale, J.M., Navrotsky, A., and Perrotta, A.J. (1997a) Effects of increased surface area and chemisorbed H2O on the relative stability of nanocrystalline γ-Al2O3 and α-Al2O3. Journal of Physical Chemistry, 101, 603-613.
26. McHale, J.M., Auroux, A., Perrotta, A.J., and Navrotsky, A. (1997b) Surface energies and thermodynamic phase stability in nanocrystalline aluminas. Science, 277, 788-791.
27. McKenzie, R.M. (1971) The synthesis of cryptomelane and some other oxides and hydroxides of manganese. Mineralogical Magazine, 38, 493-502.
28. - (1972) The manganese oxides in soils-A review. Zeitschrift fÜr Pflanzenernährung und Bodenkunde, 131, 221-242.
29. Navrotsky, A. (1997a) Thermochemistry of new, technologically important inorganic materials. Materials Research Society Bulletin, 22, 35-41.
30. - (1997b) Progress and new directions in high-temperature calorimetry revisited. Physics and Chemistry of Minerals, 24, 222-241.
31. - (2001) High-temperature oxide melt calorimetry of oxides and nitrides. Journal of Chemical Thermodynamics, 33, 859-871.
32. - (2011) Nanoscale effects on thermodynamics and phase equilibria in oxide systems. Journal of Chemical Physics and Physical Chemistry, 12, 2207-2215.
33. Navrotsky, A., Mazeina, L., and Majzlan, J. (2008) Size-driven structural and thermodynamic complexity in iron oxides. Science, 319, 1635-1638.
34. Navrotsky, A., Ma, C., Lilova, K., and Birkner, N. (2010) Nanophase transition metal oxides show large thermodynamically driven shifts in oxidation-reduction equilibria. Science, 330, 199-201.
35. Pankratz, L.B. (1982) Thermodynamic properties of elements and oxides. U.S. Bureau of Mines Bulletin, 672, pp. 233-236.
36. Parks, G.A. (1990) Surface energy and adsorption at mineral-water interfaces: An introduction. In M.F. Hochella Jr. and A.F. White, Eds., Mineral-water interface geochemistry, 23, p. 133-175. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia.
37. Pitcher, M.W., Ushakov, S.V., Navrotsky, A., Woodfield, B.F., Li, G., Boerio-Goates, J., and Tissue, B.M. (2005) Energy crossovers in nanocrystalline zirconia. Journal of the American Ceramic Society, 88, 160-167.
38. Ranade, M.R., Navrotsky, A., Zhang, H.Z., Banfield, J.F., Elder, S.H., Zaban, A., Borse, P.H., Kulkarni, S.K., Doran, G.S., and Whitfield, H.J. (2002) Energetics of nanocrystalline TiO2. Proceedings of the National Academy of Sciences, 99, 6476-6481.
39. Robie, R.A. and Hemingway, B.S. (1995) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and at higher temperatures. U.S. Geological Survey Bulletin, 2131, pp. 200-202.
40. Rose, A.H. (1965) Chemical Microbiology. Butterworths, London.
41. Shi, Q., Boerio-Goates, J., Woodfield, K., Rytting, M., Pulsipher, K., Spencer, E.C., Ross, N.L., Navrotsky, A., and Woodfield, B.F. (2012) Heat capacity studies of surface water confined on cassiterite (SnO2) nanoparticles. Journal of Physical Chemistry C, 116(6), 3910-3917.
42. Taylor, R.M., McKenzie, R.M., and Norrish, K. (1964) The mineralogy and chemistry of manganese in some Australian soils. Australian Journal of Soil Research, 2, 235-248.
43. Ushakov, S.V. and Navrotsky, A. (2005) Direct measurements of water adsorption enthalpy on hafnia and zirconia. Applied Physics Letters, 87, 164103.
44. Villalobos, M., Bargar, J., and Sposito, G. (2005) Toxic metals in the environment: The role of surfaces: Trace metal retention on biogenic manganese oxide nanoparticles. Elements, 1, 223-226.
45. Weiner, S. and Dove, P.M. (2003) An overview of biomineralization processes and the problem of the vital effect. In P.M. Dove, J.J. De Yoreo, and S. Weiner, Eds., Biomineralization, 54, p. 1-29. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia.