Determination of biodiesel content in diesel using distillation curves and multivariate calibration

Energy and Fuels

Volumn 26, Issue 9, 2012, Pages 5769-5774

  Aleme, H G ^a   Barbeira, P J S ^a  

^a FEDERAL UNIVERSITY OF MINAS GERAIS   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

CORRELATION COEFFICIENT; DISTILLATION CURVES; LATENT VARIABLE; MULTIVARIATE CALIBRATION; PARTIAL LEAST SQUARES; REGRESSION COEFFICIENT; ROAD TRANSPORTS;

LEAST SQUARES APPROXIMATIONS;

BIODIESEL;

EID: 84866594869     PISSN: 08870624     EISSN: 15205029     Source Type: Journal    
DOI: 10.1021/ef3008757     Document Type: Article

References (19)

1. Knothe, G.; Steidley, K. R. Lubricity of components of biodiesel and petrodiesel. The origin of biodiesel lubricity Energy Fuels 2005, 19, 1192-1200
2. http://www.anp.gov.br (accessed May 11, 2012).
3. Knothe, G.; Gerpen, J. V.; Krahl, J. The Biodiesel Handbook; AOCS Press: Champaign, IL, 2005.
4. Pimentel, M. F.; Ribeiro, G. M. G. S.; da Cruz, R. S.; Stragevitch, L.; Pacheco Filho, J. G. A.; Teixeira, L. S. G. Determination of biodiesel content when blended with mineral diesel fuel using infrared spectroscopy and multivariate calibration Microchem. J. 2006, 82, 201-206
5. BS EN 14078. Liquid petroleum products. Determination of fatty acid methyl ester (FAME) content in middle distillates-Infrared spectrometry method. European Committee for Standardization: Bruxels, DC, 2010.
6. Zagonel, G. F.; Peralta-Zamora, P.; Ramos, L. P. Multivariate monitoring of soybean oil ethanolysis by FTIR Talanta 2004, 63, 1021-1025
7. Oliveira, J. S.; Montalvão, R.; Daher, L.; Suarez, P. A. Z.; Rubim, J. C. Determination of methyl ester contents in biodiesel blends by FTIR-ATR and FTNIR spectroscopies Talanta 2006, 69, 1278-1284
8. Ferrão, M. F.; Viera, M. S.; Pazos, R. E. P.; Fachini, D.; Gerbase, A. E.; Marder, L. Simultaneous determination of quality parameters of biodiesel/diesel blends using HATR-FTIR spectra and PLS, iPLS, or siPLS regressions Fuel 2011, 90, 701-706
9. 1H NMR and Multivariate Calibration for the Prediction of Biodiesel Concentration in Diesel Blends J. Am. Oil Chem. Soc. 2009, 86, 581-585
10. 1H NMR and Chemometrics Talanta 2009, 78, 660-664
11. Pierce, K. M.; Schale, S. P.; Le, T. M.; Larson, J. C. An advanced analytical chemistry experiment using gas chromatography-mass spectrometry, MATLAB, and chemometrics to predict biodiesel blend percent composition J. Chem. Educ. 2011, 88, 806-810
12. Standard test method for distillation of petroleum products at atmospheric pressure, ASTM Standard D 86-11. Book of Standards; American Society for Testing and Materials: West Conshohocken, PA, 2011.
13. Kennard, R. W.; Stone, L. A. Computer aided design of experiments Technometrics 1969, 11, 137-148
14. Massart, D. L.; Vandeginste, B. G. M.; Buydens, L. M. C.; Jong, S.; Lewi, P. J.; Smeyers-Verbeke, J. Handbook of Chemometrics and Qualimetrics. Part B, 1st ed.; Elsevier Publishing: Amsterdam, 1998.
15. Cramer, J. A.; Kramer, K. E.; Johnson, K. J.; Morris, R. E.; Rose-Pehrsson, S. L. Automated wavelength selection for spectroscopic fuel models by symmetrically contracting repeated unmoving window partial least squares Chemom. Intell. Lab. Syst. 2008, 92, 13-21
16. Windom, B. C.; Bruno, T. J. Improvements in the measurement of distillation curves. 5. Reduced pressure advanced distillation curve method Ind. Eng. Chem. Res. 2011, 50, 1115-1126
17. Aleme, H. G.; Corgozinho, C. N. C.; Barbeira, P. J. S. Diesel oil discrimination by origin and type using physicochemical properties and multivariate analysis Fuel 2010, 89, 3151-3156
18. Wakeling, I. N.; Morris, J. J. A test of significance for partial least squares regression J. Chemom. 1993, 7, 291-304
19. Accuracy (trueness and precision) on measurement methods and results. Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method, ISO/IEC 5725-2; International Organization for Standardization: Geneva, Switzerland, 2002.